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Breakthrough for Organic Electrochemistry Using a Narrow Reaction Field

Research Project

Project/Area Number 20350046
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Synthetic chemistry
Research InstitutionYokohama National University (2010-2011)
Tokyo Institute of Technology (2008-2009)

Principal Investigator

ATOBE Mahito  横浜国立大学, 環境情報研究院, 教授 (90291351)

Project Period (FY) 2008 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥20,150,000 (Direct Cost: ¥15,500,000、Indirect Cost: ¥4,650,000)
Fiscal Year 2011: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2010: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2009: ¥2,340,000 (Direct Cost: ¥1,800,000、Indirect Cost: ¥540,000)
Fiscal Year 2008: ¥13,130,000 (Direct Cost: ¥10,100,000、Indirect Cost: ¥3,030,000)
Keywords有機電解合成 / マイクロリアクター / 陽極置換反応 / カップリング反応 / 反応場 / 環境調和型反応 / デラセミ化反応
Research Abstract

Microreactor is usually defined as a miniaturized chemical reaction devise composed of specially fabricated channel(s). One of the most typical characteristic feature of microreactor is extremely large surface-to-volume ratio compared to a classical batch type reactor. Hence, microreactor provides ideal circumstances for heterogeneous reactions such as organic electrochemical reaction. With these backgrounds in mind, this work focuses on practical applications of an electrochemical microreactor to electroorganic synthesis. In addition, this work aims to propose novel systems which are realized only by using the electrochemical microreactor.

Report

(6 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (49 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (21 results) (of which Peer Reviewed: 21 results) Presentation (19 results) Book (3 results) Remarks (6 results)

  • [Journal Article] In Situ Electro generation of o-Benzoquinone and High Yield Reaction with Benzenethiols in a Micro flow System2012

    • Author(s)
      Tsuneo KASHIWAGI, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Chem. Commun

      Volume: 48 Issue: 22 Pages: 2806-2808

    • DOI

      10.1039/c2cc17979b

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Conversion of Benzylamine to Dibenzylamine Using a Microreactor: Analogous System of Photocatalytic Redox Combined Synthesis2011

    • Author(s)
      Fumihiro AMEMIYA, Tsuneo KASHIWAGI, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Chemistry Letters

      Volume: 40 Issue: 6 Pages: 606-608

    • DOI

      10.1246/cl.2011.606

    • NAID

      130004426241

    • ISSN
      0366-7022, 1348-0715
    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Product Selectivity Control Induced by Using Liquid-Liquid Parallel Laminar Flow in a Microreactor2011

    • Author(s)
      Fumihiro AMEMIYA, Hideyuki MATSUMOTO, Keishi FUSE, Tsuneo KASHIWAGI, Chiaki KURODA, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Org. Biomol. Chem

      Volume: 9 Issue: 11 Pages: 4256-4265

    • DOI

      10.1039/c1ob05174a

    • Related Report
      2011 Annual Research Report 2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemo selective Reaction System Using a Two Inlet Micro-flow Reactor : Application to Carbonyl Allylation2010

    • Author(s)
      Fumihiro AMEMIYA, Keishi FUSE, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Chem. Commun

      Volume: 46 Issue: 16 Pages: 2730-2732

    • DOI

      10.1039/b926943f

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] P. C. BULMAN-PAGE and F. MARKEN, Liquid| Liquid Biphasic Electrochemistry in Ultra-turrax Dispersed Acetonitrile| Aqueous Electrolyte Systems2010

    • Author(s)
      J. D. WATKINS, Fumihiro AMEMIYA, Mahito ATOBE
    • Journal Title

      Electrochim. Acta

      Volume: 55 Issue: 28 Pages: 8808-8808

    • DOI

      10.1016/j.electacta.2010.07.104

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemoselective Reaction System Using a Two Inlets Micro-flow Reactor : Application to Reductive Carbonyl Allylation2010

    • Author(s)
      Fumihiro AMEMIYA, Keishi FUSE, Toshio FUCHIGAMI, Mahito ATOBE,
    • Journal Title

      Chem.Commun. 46

      Pages: 2730-2732

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Liquid | Liquid Biphasic Electrochemistry in Ultra-turrax Dispersed Acetonitrile | Aqueous Electrolyte Systems,2010

    • Author(s)
      John D.WATKINS, Fumihiro AMEMIYA, Mahito ATOBE, Philip C.BULMAN-PAGE, Frank MARKEN
    • Journal Title

      Electrochim.Acta 55

      Pages: 8808-8814

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Chemoselective Reaction System Using a Two Inlet Micro-flow Reactor : Application to Carbonyl Allylation2010

    • Author(s)
      F.Amemiya, K.Fuse, T.Fuchigami, M.Atobe
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 2730-2732

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electrochemical Reaction of Water-insoluble Organic Droplets in Aqueous Electrolytes Using Acoustic Emulsification2010

    • Author(s)
      M.Atobe, S.Ikari.K.Nakabayashi, F.Amemiya, T.Fuchigami
    • Journal Title

      Langmuir

      Volume: 26 Pages: 9111-9115

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bipolar Patterning of Conducting Polymers by Electrochemical Doping and Reaction2010

    • Author(s)
      S.Inagi, Y.Ishiguro, M.Atobe, T.FuchiQami
    • Journal Title

      Angew.Chem., lnt.Ed.

      Volume: 49 Pages: 10136-10139

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective Hydrogenation by Polymer-encapsulated Platinum Nanoparticles Prepared by an Easy Single-Step Sonochemical Synthesis2010

    • Author(s)
      Mahito Atobe, Mayuko Okamoto, Toshio Fuchigami, Jong-Eun Park
    • Journal Title

      Ultrasonics Sonochemistry 17

      Pages: 26-29

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization and Ion Transport Studies on Polypyrrole Membranes Prepared Electrochemically in Subcritical and Supercritical Fluids2010

    • Author(s)
      Mahito Atobe, Shinya Iizuka, Ryuta Kobayakawa, Toshio Fuchigami
    • Journal Title

      Journal of the Electrochemical Society 157

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A New Approach to Size-Controlled Synthesis of Conducting Polymer Microspheres Using Pulsed Sonoelectrochemical Polymerization2009

    • Author(s)
      Mahito ATOBE, Kengo ISHIKAWA, Ryosuke ASAMI, Toshio FUCHIGAMI,
    • Journal Title

      Angew.Chem.Int.Ed. 48

      Pages: 6069-6072

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] A New Approach to Size-Controlled Synthesis of Conducting Polymer Microspheres Using Pulsed Sonoelectrochemical Polymerization2009

    • Author(s)
      Mahito Atobe, Kengo Ishikawa, Ryosuke Asami Toshio Fuchigami
    • Journal Title

      Angewandte Chemie International Edition 48

      Pages: 6069-6072

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-supported Paired Electrosynthesis Using a Micro-flow Reactor without Intentionally Added Electrolyte2008

    • Author(s)
      Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      J. Electrochem. Soc

      Volume: 155 Issue: 11 Pages: 162-165

    • DOI

      10.1149/1.2975823

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Novel Electrosynthetic System for Anodic Substitution Reactions Using Parallel Laminar Flow in a Micro-Flow Reactor2008

    • Author(s)
      Daisuke HORII, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Chem. Eur. J

      Volume: 14 Issue: 33 Pages: 10382-10387

    • DOI

      10.1002/chem.200801511

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Novel Electrosynthetic System for Anodic Substitution Reactions Using Parallel Laminar Flow in a Micro-Flow Reactor,2008

    • Author(s)
      Daisuke HORII, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Chem.Eur.J. 14

      Pages: 10382-10387

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Self-supported Paired Electrosynthesis Using a Micro-flow Reactor without Intentionally Added Electrolyte2008

    • Author(s)
      Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      J.Electrochem.Soc 155

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] A Novel Electro synthetic System for Anodic Substitution Reactions Using Parallel Laminar Flow in a Micro-Flow Reactor2008

    • Author(s)
      Daisuke HORII, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Chemistry A European Journal 14

      Pages: 10382-10387

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanistic Study on Electrochemical Deposition of Conjugated Polymers in Centrifugal Fields2008

    • Author(s)
      Atsushi MUROTANI, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Journal of Physical Chemistry B 112

      Pages: 9311-9317

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Development of an Anodic Substitution Reaction System Using Acoustic Emulsification2008

    • Author(s)
      Ryosuke ASAMI, Toshio FUCHIGAMI, Mahito ATOBE
    • Journal Title

      Chemistry Communication

      Pages: 244-246

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Redox Combined Reactions Using Electrochemical Microreactor2011

    • Author(s)
      跡部真人
    • Organizer
      10th International Symposium on Organic Reactions (ISOR 10)
    • Place of Presentation
      横浜(Invited)
    • Year and Date
      2011-10-22
    • Related Report
      2011 Annual Research Report
  • [Presentation] Development of Redox Combined Reaction System Using Electrochemical Microreactor2011

    • Author(s)
      Tsuneo KASHIWAGI, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
    • Organizer
      The Seventh International Symposium on Integrated Synthesis(ISIS-7)
    • Place of Presentation
      Kobe, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Development of Analogous System of Photo catalytic Redox Combined Reaction Using Electrochemical Microreactor2011

    • Author(s)
      Tsuneo KASHIWAGI, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Shigeru NISHIYAMA, Mahito ATOBE
    • Organizer
      2nd Japanese-German Organic Electrochemistry Symposium
    • Place of Presentation
      Niigata, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] 超音波場、遠心場、超臨界流体ならびにイオン液体を反応場とする導電性高分子材料の電解合成2010

    • Author(s)
      跡部真人
    • Organizer
      サイエンス & テクノロジーセミナー
    • Place of Presentation
      東京
    • Year and Date
      2010-12-09
    • Related Report
      2011 Final Research Report
  • [Presentation] Electro synthetic Processes Using Unique Fields and Methods2010

    • Author(s)
      Mahito ATOBE
    • Organizer
      The 1st German-Japanese Symposium on Electrosynthesis
    • Place of Presentation
      Bonn, Germany
    • Year and Date
      2010-10-02
    • Related Report
      2011 Final Research Report
  • [Presentation] Electrosynthetic Processes Using Unique Fields and Methods2010

    • Author(s)
      Mahito ATOBE
    • Organizer
      1st German-Japanese Symposium on Electrosynthesis.
    • Place of Presentation
      Bonn, Germany.
    • Year and Date
      2010-10-02
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] A Novel Electrosynthetic System Using Parallel Laminar Flow in a Micro-Flow Reactor2010

    • Author(s)
      Mahito ATOBE, Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI
    • Organizer
      The 61st Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Nice, France
    • Year and Date
      2010-09-30
    • Related Report
      2011 Final Research Report
  • [Presentation] A Novel Electrosynthetic System Using Parallel Laminar Flow in a Micro-Flow Reactor2010

    • Author(s)
      Mahito ATOBE, Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI,
    • Organizer
      The 61st Annual Meet.of Inter.Soc.Electrochem.,
    • Place of Presentation
      Nice, France.
    • Year and Date
      2010-09-30
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] A Novel Electrosynthetic System Using Pazallel Lazninaz Flow in a Micro-FlowReactor2010

    • Author(s)
      M.Atobe, F.Amemiya, D.Horii, T.Fuchigami
    • Organizer
      The 61st Annual Meeting of International Society of Electrochemistry
    • Place of Presentation
      Nice, France
    • Year and Date
      2010-09-30
    • Related Report
      2010 Annual Research Report
  • [Presentation] Environmental-Friendly Emulsion Electrosyntheses Using Acoustic Emulsification2010

    • Author(s)
      Mahito ATOBE, Shintaro IKARI, Fumihiro AMEMIYA, Ryosuke ASAMI, Toshio FUCHIGAMI
    • Organizer
      217th Electrochem.Soc.Meet.
    • Place of Presentation
      Vancouver, Canada.
    • Year and Date
      2010-04-26
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Multi-step Reactions of Quinones Using Electrochemical Microreactor2010

    • Author(s)
      Tsuneo KASHIWAGI, Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies(Pacifichem 2010)
    • Place of Presentation
      Honolulu, HawaiiHawaii, USA
    • Related Report
      2011 Final Research Report
  • [Presentation] 超音波利用による有機電解合成プロセスの制御2009

    • Author(s)
      跡部真人
    • Organizer
      化学工学会関東支部 第40回Continuing Educationシリーズ講習会
    • Place of Presentation
      東京理科大学
    • Year and Date
      2009-11-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] Development of Chemoselective Microflow Reactor : Application to Regioselective Cathodic Carbonyl Allylation,2009

    • Author(s)
      Fumihiro AMEMIYA, Toshio FUCHIGAMI, Mahito ATOBE
    • Organizer
      215th Electrochem.Soc.Meet
    • Place of Presentation
      Viena, Austria.
    • Year and Date
      2009-10-04
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] ユニークな化学反応場を活用する電解合成プロセスおよび材料合成プロセス2009

    • Author(s)
      跡部真人
    • Organizer
      化学技術戦略推進機構講演会
    • Place of Presentation
      東京
    • Year and Date
      2009-06-01
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロリアクターを活用する電解合成反応のブレークスルー2009

    • Author(s)
      跡部真人
    • Organizer
      4大学ナノ・マイクロファブリケーションコンソーシアム拠点形成シンポジウム
    • Place of Presentation
      川崎
    • Year and Date
      2009-03-06
    • Related Report
      2011 Final Research Report
  • [Presentation] マイクロリアクターを活用する電解合成プロセスのブレークスルー2009

    • Author(s)
      跡部真人
    • Organizer
      近畿化学協会合成部会フロー・マイクロ合成研究会第20回公開講演会-東京講演会
    • Place of Presentation
      東京
    • Year and Date
      2009-01-16
    • Related Report
      2011 Final Research Report
  • [Presentation] Development of a Self-Supported Paired Electrosynthetic System using a Micro-flow Reactor2008

    • Author(s)
      Fumihiro AMEMIYA, Daisuke HORII, Toshio FUCHIGAMI, Mahito ATOBE
    • Organizer
      214th Electrochem.Soc.Meet.
    • Place of Presentation
      Honolulu, USA.
    • Year and Date
      2008-10-13
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Development of Electrosynthetic Processes Using Acoustic Emulsification2008

    • Author(s)
      Mahito ATOBE
    • Organizer
      11th Meeting of the European Society of Sonochemistry
    • Place of Presentation
      La Grande Motte, France
    • Year and Date
      2008-06-03
    • Related Report
      2008 Annual Research Report
  • [Presentation] Development of an Electro synthetic System for Anodic Substitution Reactions Using Parallel Laminar Flow in a Micro-Flow Reactor2008

    • Author(s)
      Mahito ATOBE
    • Organizer
      2008 International Symposium on Organic Reactions
    • Place of Presentation
      Chiai
    • Related Report
      2011 Final Research Report
  • [Book] みみずく書房2009

    • Author(s)
      跡部真人、逢坂哲弥、加納健司、桑畑進、立間徹、門間聰之、
    • Publisher
      で理解する電気化学測定法
    • Related Report
      2010 Self-evaluation Report
  • [Book] カーク・オスマー化学技術・環境ハンドブック(イオン液体(第10章))(第1巻)2009

    • Author(s)
      跡部真人
    • Publisher
      丸善
    • Related Report
      2010 Self-evaluation Report
  • [Book] Q & Aで理解する電気化学測定法2009

    • Author(s)
      跡部真人, 逢坂哲弥, 加納健司, 桑畑進, 立間徹, 門間聰之
    • Total Pages
      208
    • Publisher
      みみずく書房
    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.atobe-lab.ynu.ac.jp

    • Related Report
      2011 Final Research Report
  • [Remarks]

    • URL

      http://www.atobe-lab.ynu.ac.jp

    • Related Report
      2011 Annual Research Report
  • [Remarks] 研究室ホームページ

    • URL

      http://www.atobe-lab.ynu.ac.jp

    • Related Report
      2010 Self-evaluation Report
  • [Remarks] Highlights in Chemical Science 誌に論文 が紹介 (Highlights in Chemical Science, April 2010, Volume 7, Issue 4) Chemoselective Reaction System Using a Two Inlet Micro-flow Reactor : Application to Carbonyl Allylation Amemiya, F. ; Fuse, K .; Fuchigami, T. ; Atobe, M.Chem.Commun.2010, 46, 2730-2732.

    • Related Report
      2010 Self-evaluation Report
  • [Remarks]

    • URL

      http://www.atobe-lab.ynu.ac.jp

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.echem.titech.ac.jp/~atobe/index.html

    • Related Report
      2009 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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