• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of Nonvolatile FET Memory with Helical Polymer

Research Project

Project/Area Number 20350085
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionChiba University

Principal Investigator

KOBAYASHI Norihisa  Chiba University, 大学院・融合科学研究科, 教授 (50195799)

Co-Investigator(Kenkyū-buntansha) UEMURA Sei  産業技術総合研究所, フレキシブルエレクトロニクス研究センター, 研究員 (50392593)
KAMATA Toshihide  産業技術総合研究所, フレキシブルエレクトロニクス研究センター, センター長 (80356815)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥19,110,000 (Direct Cost: ¥14,700,000、Indirect Cost: ¥4,410,000)
Fiscal Year 2010: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2009: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2008: ¥11,440,000 (Direct Cost: ¥8,800,000、Indirect Cost: ¥2,640,000)
Keywords有機電子材料・素子 / FETメモリ / らせん高分子 / ナノ材料 / 生体材料 / ポリペプチド
Research Abstract

Memory devices were fabricated with polypeptide and DNA as a memory material which have helical secondary structure. In the case of polypeptide, it was revealed that the helical tertiary structure can be increased by optimizing the intermolecular interaction. When the helical tertiary structure was much incorporated into the film, the memory device showed driving at lower electric field than that in the absence of the structure. Since the structure can be increased by molecular alignment processes, the device fabricated with thick film (4μm) by the process was driven at same voltage to that of thin film (700nm) prepared by other process. As the results, the yield rate of the device was improved from 50~70 % to 100% due to decrease in pinhole. In the case of DNA, complexing DNA with surfactant was carried out in order to remove the ion. In the OTFT fabricated with DNA-surfactant complex, high on/off ratio was obtained because of decrease in the off-current. Further, when PMMA was layered on the DNA-surfactant layer, pentacene deposited on the PMMA surface as a semiconductor layer showed large grain and high crystallinity. As the results, 104 of on/off ratio at 10V and 1000 hours of the retention time were achieved due to improve the on-current.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (53 results)

All 2010 2009 2008 Other

All Journal Article (14 results) (of which Peer Reviewed: 7 results) Presentation (25 results) Book (9 results) Remarks (5 results)

  • [Journal Article] Color-tunable Multilayer OLED Composed of DNA Complex and Tris(8-hydroxyquinolinato)aluminum2010

    • Author(s)
      中村一希,石川貴之,西岡大輔,牛窪孝洋,小林範久
    • Journal Title

      Appl.Phys.Lett. vol.97

      Pages: 193301-193303

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Color-tunable Multilayer OLED Composed of DNA Complex , Tris(8-hydroxyquinolinato) aluminum2010

    • Author(s)
      N.Kobayashi, 他4名
    • Journal Title

      Applied Physics Letter

      Volume: 97 Pages: 193301-193303

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] エレクトロクロミックディスプレイ2010

    • Author(s)
      小林範久
    • Journal Title

      表面技術

      Volume: 61 Pages: 483-487

    • NAID

      10026872242

    • Related Report
      2010 Annual Research Report
  • [Journal Article] カルバゾールペンダントポリペプチド液晶の構造と電荷輸送性2009

    • Author(s)
      小林範久
    • Journal Title

      鉱山 vol.669

      Pages: 21-29

    • Related Report
      2010 Final Research Report
  • [Journal Article] Memory Mechanism of Printable Ferroelectric TFT Memory with Tertiary Structured Polypeptide as a Dielectric Layer2009

    • Author(s)
      長谷川雅俊,植村聖,鎌田俊英,小林範久
    • Journal Title

      Synth.Met. vol.159

      Pages: 961-964

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Memory Mechanism of Printable Ferroelectric TFT Memory with tertiary Structured Polypeptide as a Dielectric Layer2009

    • Author(s)
      H.Hasegawa
    • Journal Title

      Synthetic Metals 159

      Pages: 961-964

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Properties of Conjugated Polymers Containing 3, 9- and 2, 9-Linked Carbazole Units in the Main Chain2009

    • Author(s)
      K.Tamura
    • Journal Title

      J.Polym.Sci.Part A Polym.Chem. 47

      Pages: 3506-3517

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phthalate-derivative/TiO_2 Modified Electrode for Electrochromic Application2009

    • Author(s)
      S.Tanaka
    • Journal Title

      Solar Energy Materials and Solar Cells 93

      Pages: 2098-2101

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Memory Mechanism of Printable Ferroelectric TFT Memory with Tertiary Structured Po117-peptide as a Dielectric Layer2009

    • Author(s)
      Norihisa KOBAYASHI 他
    • Journal Title

      Synthetic Metals (印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] DNA/導電性高分子高次組織体の構造とEL特性2008

    • Author(s)
      小林範久
    • Journal Title

      未来材料 vol.15

      Pages: 14-21

    • NAID

      40015869927

    • Related Report
      2010 Final Research Report
  • [Journal Article] DNA組織体の電子・光機能材料としての可能性2008

    • Author(s)
      小林範久
    • Journal Title

      Material Stage vol.8

      Pages: 39-42

    • Related Report
      2010 Final Research Report
  • [Journal Article] DNA組織体の電子・光機能材料としての可能性2008

    • Author(s)
      小林範久
    • Journal Title

      Material Stage 8

      Pages: 39-42

    • Related Report
      2008 Annual Research Report
  • [Journal Article] 生体高分子材料を用いたプリンタブル・フレキシブルメモリ素子の作製とその可能性2008

    • Author(s)
      植村聖,鎌田俊英
    • Journal Title

      Material Stage 8

      Pages: 37-38

    • Related Report
      2008 Annual Research Report
  • [Journal Article] 有機トランジスタ型メモリの誘電体層として用いた生体高分仔の高次構造と電気特性との相関2008

    • Author(s)
      植村聖、長谷川雅俊、小林範久、鎌田俊英
    • Journal Title

      信学技報 2008-55

      Pages: 25-29

    • Related Report
      2008 Annual Research Report
  • [Presentation] Relationship Between Morphology and Hysteresis Property of Polyglutamate as a Ferroelectric Layer of Organic Thin Film Transistor Memory2010

    • Author(s)
      植村聖, 猪股傑士, 中村一希, 小林範久, 鎌田俊英
    • Organizer
      2010 International Conference on Flexible and Printed Electronics
    • Place of Presentation
      新竹(台湾)
    • Year and Date
      2010-10-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] 強誘電性ポリペプチドメモリにおけるナノスケールでの膜構造の制御とメモリ素子特性に及ぼす影響2010

    • Author(s)
      植村聖,猪股傑士,福島知央,中村一希,小林範久,鎌田俊英
    • Organizer
      第59会高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] DNA/カチオン性分子複合体を誘電体層に用いた有機TFTメモリの動作安定化2010

    • Author(s)
      植村聖,行本知仁,中村一希,小林範久,鎌田俊英
    • Organizer
      第59会高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Organic Thin Film Transistor Memory Fabricated with DNA Complex as a Gate Dielectric2010

    • Author(s)
      行本知仁,中村一希,小林範久,植村聖,鎌田俊英
    • Organizer
      ICSM 2010
    • Place of Presentation
      京都
    • Year and Date
      2010-07-06
    • Related Report
      2010 Final Research Report
  • [Presentation] Effect of Molecular Alignment at Organic Semiconductor/Polypeptide Interface on Memory Performance of an Organic TFT2010

    • Author(s)
      福島知央,中村一希,小林範久,植村聖,鎌田俊英
    • Organizer
      ICSM 2010
    • Place of Presentation
      京都
    • Year and Date
      2010-07-06
    • Related Report
      2010 Final Research Report
  • [Presentation] Organic Thin Film Transistor Memory Fabricated with DNA Complexasa Gate Dielectric2010

    • Author(s)
      福島知央, 中村一希, 小林範久, 植村聖, 鎌田俊英
    • Organizer
      International Conferenceon Science, Technology of Synthetic Metals 2010
    • Place of Presentation
      京都
    • Year and Date
      2010-07-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Effect of Molecular Alignmentat Organic Semiconductor/Polypeptide Interface on Memory Performance of an Organic TFT2010

    • Author(s)
      行本知仁, 中村一希, 小林範久, 植村聖, 鎌田俊英
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010
    • Place of Presentation
      京都
    • Year and Date
      2010-07-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Influence of the Crystallinity of Polypeptide as a Gate Dielectric on the Hysteresis Behavior of TFT2010

    • Author(s)
      植村聖,猪股傑士,中村一希,小林範久,鎌田俊英
    • Organizer
      ICSM 2010
    • Place of Presentation
      京都
    • Year and Date
      2010-07-05
    • Related Report
      2010 Final Research Report
  • [Presentation] Inuence of the Crystallinity of Polypeptide as a Gate Dielectric on the Hysteresis Behavior of TFT2010

    • Author(s)
      植村聖, 猪股傑士, 中村一希, 小林範久, 鎌田俊英
    • Organizer
      International Conference on Scienceand Technology of Synthetic Metals 2010
    • Place of Presentation
      京都
    • Year and Date
      2010-07-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] DNA/カチオン性分子複合体を誘電体層として用いた有機TFTメモリの構築2010

    • Author(s)
      植村聖,行本知仁,中村一希,小林範久,鎌田俊英
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-26
    • Related Report
      2010 Final Research Report
  • [Presentation] DNA/カチオン性分子複合体を誘電体層として用いた有機TFTメモリの構築2010

    • Author(s)
      行本知仁, 中村一希, 小林範久, 植村聖, 鎌田俊英
    • Organizer
      59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] 強誘電性ポリペプチドTFTメモリにおける誘電体層の分子配向状態がメモリ保持特性に及ぼす影響2010

    • Author(s)
      福島知央,中村一希、小林範久,植村聖,鎌田俊英
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪
    • Year and Date
      2010-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Influence of Substitution Group of the Side Chain of Polypeptide on the Morphology and Its Hysteresis Property as a Ferroelectric Memory Device2009

    • Author(s)
      猪股傑士,中村一希,小林範久,植村聖,鎌田俊英
    • Organizer
      SSDM2009
    • Place of Presentation
      仙台
    • Year and Date
      2009-10-07
    • Related Report
      2010 Final Research Report
  • [Presentation] Influence of Substitution Group of the Side Chain of Polypeptide on the Morphology and its Hysteresis Property as a Ferroelectric Memory Device2009

    • Author(s)
      T.Inomata
    • Organizer
      2009 International Conference on Solid State Devices and Materials
    • Place of Presentation
      仙台(日本)
    • Year and Date
      2009-10-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリペプチド/有機半導体積層膜の強誘電挙動がTFTメモリ特性に及ぼす影響2009

    • Author(s)
      猪股傑士,植村聖,小林範久,鎌田俊英
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Stretching of(DNA/Functional Molecules)Complex between Electrodes Toward DNA Molecular Wire2009

    • Author(s)
      N.Kobayashi
    • Organizer
      SPIE2009
    • Place of Presentation
      San Diego(USA)
    • Year and Date
      2009-08-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリペプチドを用いたTFTメモリの特性に及ぼす側鎖置換基の影響2009

    • Author(s)
      植村聖,猪股傑士,小林範久,鎌田俊英
    • Organizer
      第56回応用物理学関係連合講演会
    • Place of Presentation
      つくば
    • Year and Date
      2009-04-01
    • Related Report
      2010 Final Research Report
  • [Presentation] DNA組織体を用いた有機薄膜トランジスタの構築2009

    • Author(s)
      行本知仁,長谷川雅俊,小林範久,植村聖,鎌田俊英
    • Organizer
      日本化学会第89回春季年会
    • Place of Presentation
      千葉県
    • Year and Date
      2009-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 有機トランジスタ型メモリの誘電体層として用いた生体高分子の高次構造と電気特性との相関2008

    • Author(s)
      植村聖,長谷川雅俊,小林範久,鎌田俊英
    • Organizer
      有機エレクトロニクス研究会
    • Place of Presentation
      東京都
    • Year and Date
      2008-10-31
    • Related Report
      2010 Final Research Report
  • [Presentation] Memory mechanism of printable ferroelectric TFT memory with tertiary structured polypeptide as a dielectric layer2008

    • Author(s)
      長谷川雅俊,小林範久,植村聖,鎌田俊英
    • Organizer
      18th IKETANI CONFERENCE International Conference on Control of Super-Hierarchical Structures and Innovative Functions of Next-Generation Conjugated Polymers
    • Place of Presentation
      兵庫県
    • Year and Date
      2008-10-21
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリペプチド誘電体膜の3次構造制御による有機TFTメモリ特性の向上2008

    • Author(s)
      長谷川雅俊,小林範久,植村聖,鎌田俊英
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪府
    • Year and Date
      2008-09-26
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリペプチド膜を用いた有機TFTメモリのヒステリシス挙動に及ぼすポリペプチド3次構造2008

    • Author(s)
      長谷川雅俊,小林範久,植村聖,鎌田俊英
    • Organizer
      第57回高分子年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-29
    • Related Report
      2010 Final Research Report
  • [Presentation] Development of flexible devices using printable organic semiconductors2008

    • Author(s)
      Toshihide Kamata 他
    • Organizer
      1st International Forum of Printed Active Display
    • Place of Presentation
      Seoul, Korea
    • Year and Date
      2008-01-05
    • Related Report
      2008 Annual Research Report
  • [Presentation] Molecular structure and EL application of highly ordered structure DNA/Ru(bpy)32+ complex2008

    • Author(s)
      Norihisa KOBAYASHI 他
    • Organizer
      SPIE Optics+Photonics 2008
    • Place of Presentation
      San Diego,USA
    • Related Report
      2008 Annual Research Report
  • [Presentation] Memory mechanism of printable ferroelectric TFT memory with terthary structured polypeptide as a dielectric layer2008

    • Author(s)
      Norihisa KOBAYASHI 他
    • Organizer
      18th Iketani conference, International Conference on Control of Super-Hierarchical Structures and Innovative Functions of Next-Generation Coniueated Polymers
    • Place of Presentation
      Awaji, Japan
    • Related Report
      2008 Annual Research Report
  • [Book] 有機半導体デバイス-基礎から最先端材料・デバイスまで-(エレクトロクロミズムとメモリ&非発光型表示素子)2010

    • Author(s)
      小林範久
    • Total Pages
      538
    • Publisher
      オーム社
    • Related Report
      2010 Final Research Report
  • [Book] 有機半導体デバイス-基礎から最先端材料・デバイスまで-(印刷有機メモリ)2010

    • Author(s)
      植村聖, 他
    • Total Pages
      538
    • Publisher
      オーム社
    • Related Report
      2010 Final Research Report
  • [Book] 各種透明フレキシブル基板材料の開発・特性と高性能化(透明フィルム基板への成膜技術)2010

    • Author(s)
      植村聖, 他
    • Total Pages
      14
    • Publisher
      情報機構
    • Related Report
      2010 Final Research Report
  • [Book] 誘起半導体デバイスー基礎から最先端材料・デバイスまで一エレクトロクロミズムとメモリ&非発光型表示素子2010

    • Author(s)
      小林範久
    • Total Pages
      538
    • Publisher
      オーム社
    • Related Report
      2010 Annual Research Report
  • [Book] 有機半導体デバイス基礎から最先端材料・デバイスまで・印刷有機メモリ2010

    • Author(s)
      植村聖, 他
    • Total Pages
      520
    • Publisher
      オーム社
    • Related Report
      2010 Annual Research Report
  • [Book] 月刊『機能材料』(フレキシブルデバイス-オール有機ハイブリッドフィルムエレクトロニクスへの展望-)2009

    • Author(s)
      植村聖, 他
    • Total Pages
      6
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Final Research Report
  • [Book] 次世代共役ポリマーの超階層制御と革新機能(階層制御されたDNA/共役ポリマー高次組織体の構築と光電機能)2009

    • Author(s)
      小林範久
    • Total Pages
      445
    • Publisher
      シーエムシー出版
    • Related Report
      2010 Final Research Report
  • [Book] 次世代共役ポリマーの超階層制御と革新機能2009

    • Author(s)
      小林範久(分担)
    • Total Pages
      445
    • Publisher
      シーエムシー出版
    • Related Report
      2009 Annual Research Report
  • [Book] 有機半導体デバイス -基礎から最先端デバイスまで-2009

    • Author(s)
      植村聖(分担)
    • Publisher
      オーム社出版部(印刷中)
    • Related Report
      2009 Annual Research Report
  • [Remarks] 平成22年度文部科学大臣表彰科学技術賞,文部科学大臣,鎌田俊英,植村聖, 他,2010/04/13

    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://photo-m.tp.chiba-u.jp/i-poly/

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi