Free-Standing Films Based on Polymer Nanoassembly for Functional Interface

• Project/Area Number: 20350100
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Polymer/Textile materials
• Research Institution: Tohoku University
• Principal Investigator: MITSUISHI Masaya Tohoku University, 多元物質科学研究所, 准教授 (70333903)
• Co-Investigator(Kenkyū-buntansha): MIYASHITA Tokuji 東北大学, 多元物質科学研究所, 教授 (40124630)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥19,240,000 (Direct Cost: ¥14,800,000、Indirect Cost: ¥4,440,000); Fiscal Year 2010: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000); Fiscal Year 2009: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000); Fiscal Year 2008: ¥15,210,000 (Direct Cost: ¥11,700,000、Indirect Cost: ¥3,510,000)
• Keywords: 超薄膜 / ナノ材料

Research Abstract

Free-standing nanofilms consisting of polymer Langmuir-Blodgett films were prepared. Incorporation of crosslinkable groups in polymer LB films allows us to prepare free-standing film with the minimum thickness of 10nm. It was found that the stretching ratio reached 7 times larger than that of bulk films.

Research Products

• [Journal Article] Fabrication of fluorinated polymer nanosheets using the Langmuir-Blodgett technique : characterization of their surface properties and applications (2010)
  • Author(s): M.Aminuzzaman, M.Mitsuishi, T.Miyashita
  • Journal Title: Polym.Int. 59 Pages: 583-596
  • Peer Reviewed
• [Journal Article] Surface modification of a flexible polyimide film using a reactive fluorinated polymer nanosheet (2010)
  • Author(s): M.Aminuzzaman, M.Mitsuishi, T.Miyashita
  • Journal Title: Thin Solid Films 519 Pages: 974-977
  • Peer Reviewed
• [Journal Article] Fabrication of fluorinated polymer nanosheets using the Langmuir-Blodgett technique : characterization of their surface properties and applications (2010)
  • Author(s): M.Aminuzzaman, M.Mitsuishi, T.Miyashita
  • Journal Title: Polymer International Volume: 59 Pages: 583-596
  • Peer Reviewed
• [Journal Article] Surface modification of a flexible polyimide film using a reactive fluorin ated polymer nanosheet (2010)
  • Author(s): M.Aminuzzaman, M.Mitsuishi, T.Mivashita
  • Journal Title: Thin Solid Films Volume: 519 Pages: 974-977
  • Peer Reviewed
• [Journal Article] Molecular orientation of nonlinear optical polymer nanosheets on silica nanoparticle monolayer studied by optical waveguide spectroscopy (2009)
  • Author(s): M.Ishifuji, T.Suzuki, M.Mitsuishi, T.Miyashita
  • Journal Title: Thin Solid Films 518 Pages: 457-461
  • Peer Reviewed
• [Journal Article] Photofunctional thin film devices composed of polymer nanosheet assemblies (2009)
  • Author(s): M.Mitsuishi, J.Matsui, T.Miyashita
  • Journal Title: J.Mater.Chem. 19 Pages: 325-329
  • Peer Reviewed
• [Journal Article] Temperature Imaging for Thermal Fluid Flow in Microchannels with Luminescent Polymer Nanosheets (2009)
  • Author(s): M.Mitsuishi, M.Mihashi, M.Aminuzzaman, S.Kikuchi, T.Miyashita
  • Journal Title: J.Nanosci.Nanotechnol. 9 Pages: 90-96
  • Peer Reviewed
• [Journal Article] Molecular orientation of nonlinear optical polymer nanosheets on silica nanoparticle monolayer studied by optical waveguide spectroscopy (2009)
  • Author(s): Miki Ishifuji
  • Journal Title: Thin Solid Films 518 Pages: 457-461
  • Peer Reviewed
• [Journal Article] Photofunctional thin film devices composed of polymer nanosheet assemblies (2009)
  • Author(s): Mitsuishi
  • Journal Title: Journal of Materials Chemistry 19 Pages: 325-329
  • Peer Reviewed
• [Journal Article] Temperature Imaging for Thermal Fluid Flow in Microchannels with Luminescent Polymer Nanosheets (2009)
  • Author(s): Mitsuishi
  • Journal Title: Journal of Nanoscience and Nanotechnology 9 Pages: 90-96
  • Peer Reviewed
• [Presentation] Photo-Induced SiO_2 Film Using Silsesquioxane Copolymer Nanos heet Assembly (2010)
  • Author(s): T.Ikenuma, T.Suzuki, Y.Kim, M.Mitsuishi, T.Miyashita
  • Organizer: JSPS/NPF 4th Joint Seminar
  • Place of Presentation: 米沢
  • Year and Date: 2010-11-11
• [Presentation] 高分子ナノシートを前駆体とした光酸化SiO_2薄膜の構築 (2010)
  • Author(s): 池沼達也, 鈴木健朗, 三ツ石方也, 宮下徳治
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 札幌
  • Year and Date: 2010-09-15
• [Presentation] SiO_2 Ultrathin Film Formation using Silsesquioxane Copolymer Nanosheet Assembly (2010)
  • Author(s): 宮下徳治, 池沼達也, 三ツ石方也
  • Organizer: IIMM2010
  • Place of Presentation: England
  • Year and Date: 2010-09-01
• [Presentation] シルセスキオキサンナノシートを利用した光酸化SiO_2薄膜の作製 (2010)
  • Author(s): 池沼達也, 鈴木健朗, 三ツ石方也, 宮下徳治
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2010-05-27
• [Presentation] シルセスキオキサンナノシートを利用した光酸化Sio2薄膜の作製 (2010)
  • Author(s): 池沼達也, 鈴木健朗, 三ツ石方也, 宮下徳治
  • Organizer: 第59回高分子学会年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2010-05-26
• [Presentation] Photo-induced SiO_2 Network Formation Using Silsesquioxane Copolymer Nanosheet Assembly (2009)
  • Author(s): T.Ikenuma, T.Suzuki, Y.Kim, M.Mitsushi, T.Miyashita
  • Organizer: JSPS-ACP第1回合同セミナー
  • Place of Presentation: Korea
  • Year and Date: 2009-12-11
• [Presentation] シルセスキオキサンナノシートを利用したSiO_2ネットワークの構築 (2009)
  • Author(s): 池沼達也, 鈴木健朗, 三ツ石方也, 宮下徳治
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 神戸
  • Year and Date: 2009-09-16
• [Presentation] 高分子ナノシートをテンプレートに用いた無機ナノ粒子の精密集積 (2009)
  • Author(s): 鈴木健朗
  • Organizer: 第58回高分子討論会
  • Place of Presentation: 熊本
  • Year and Date: 2009-09-16
• [Presentation] Antireflection and Superhydrophilic Films by Silica Nanoparticle Assembly Using Polymer Nanosheet (2009)
  • Author(s): T.Suzuki, M.Ishifuji, M.Mitsushi, T.Miyashita
  • Organizer: KJF2009
  • Place of Presentation: Korea
  • Year and Date: 2009-08-23
• [Presentation] Photoinduced SiO_2 Ultrathin Film Using Polymer Nanosheet Assembly (2009)
  • Author(s): M.Mitsushi, Y.Kim, F.Zhao, A.Watanabe, T.Miyashita
  • Organizer: KJF2009
  • Place of Presentation: Korea
  • Year and Date: 2009-08-23
• [Presentation] 高分子ナノ集積体を利用した自己支持性ナノ薄膜の作製 (2009)
  • Author(s): 三ツ石方也, 宮下徳治
  • Organizer: 電気通信研究所共同プロジェクト研究会「ナノ・バイオの融合による新規バイオデバイスに関する研究」第13回情報バイオトロニクス研究会
  • Place of Presentation: 仙台
  • Year and Date: 2009-06-19
• [Presentation] 高分子ナノシートを用いた機能界面の構築 (2009)
  • Author(s): 三ツ石方也, 鈴木健朗, 石藤美紀, Kim Yeji, 宮下徳治
  • Organizer: 新産業創造物質基盤技術研究センター平成20年成果報告会
  • Place of Presentation: 大阪
  • Year and Date: 2009-03-13
• [Presentation] 高分子ナノシートとシリカナノ粒子の精密集積による機能表面の作製 (2008)
  • Author(s): 鈴木健朗, 石藤美紀, 三ツ石方也, 宮下徳治
  • Organizer: 第8回東北大学多元物質科学研究所研究発表会
  • Place of Presentation: 仙台
  • Year and Date: 2008-12-11
• [Presentation] 架橋性高分子ナノシートによる自己支持性ナノ薄膜の物性評価 (2008)
  • Author(s): 平地圭, 遠藤洋史, 三ツ石方也, 宮下徳治
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-24
• [Presentation] 高分子ナノシート/シリカナノ粒子積層体による超親水表面の作製 (2008)
  • Author(s): 鈴木健朗, 石藤美紀, 三ツ石方也, 宮下徳治
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-09-24
• [Presentation] Free-standing Polymer Nanosheet Assembly Via Langmuir-Blodgett Technique (2008)
  • Author(s): 三ツ石方也, 平地圭, 遠藤洋史, 宮下徳治
  • Organizer: MAM08
  • Place of Presentation: Germany, Dusseldorf
  • Year and Date: 2008-09-07
• [Presentation] 高分子ナノシートを用いた自己支持性ナノ薄膜 (2008)
  • Author(s): 平地圭
  • Organizer: 第57回高分子年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2008-05-30
• [Presentation] 高分子ナノシートを用いた自己支持性ナノ薄膜 (2008)
  • Author(s): 平地圭, 遠藤洋史, 三ツ石方也, 宮下徳治
  • Organizer: 第57回高分子学会年次大会
  • Place of Presentation: 横浜
  • Year and Date: 2008-05-28
• [Book] 現代界面コロイド科学の事典(高分子ナノシート自己支持性膜) (2010)
  • Author(s): 宮下徳治
  • Publisher: 丸善
• [Book] 超分子サイエンス&ナノテクノロジー(高分子ナノシート) (2009)
  • Author(s): 三ツ石方也, 宮下徳治
  • Publisher: NTS出版
• [Book] 超分子サイエンス&ナノテクノロジー (2009)
  • Author(s): 三ツ石方也
  • Total Pages: 8
  • Publisher: NTS出版
• [Remarks] ホームページ等
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