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Designing the Co-continuous Morphology of Multi-component Polymers and Application to Dispersion of Carbon Nanotubes

Research Project

Project/Area Number 20350107
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionKyoto Institute of Technology

Principal Investigator

MIYATA Takaaki  Kyoto Institute of Technology, 工芸科学研究科, 教授 (50188827)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2010: ¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2009: ¥6,890,000 (Direct Cost: ¥5,300,000、Indirect Cost: ¥1,590,000)
Fiscal Year 2008: ¥8,060,000 (Direct Cost: ¥6,200,000、Indirect Cost: ¥1,860,000)
Keywords高分子混合系 / 共連続構造 / ナノチューブ / 高分子ネットワーク / 電気伝導性 / 相分離 / 電気伝道性 / 電気伝導の異方性 / ミクロ電気回路 / 3次元ネットワーク
Research Abstract

The main purpose of this study is to generate and control the co-continuous morphologies of binary as well as ternary polymer mixtures by using photochemical reactions. Since photochemical reactions can be temporally and spatially induced by irradiation, we found a method to control spatially and temporally phase separation of polymer mixtures by using the newly developed "Computer-Assisted Irradiation" (CAI) method. Finally, by taking advantages of various co-continuous morphologies generated by irradiation, we were able to generate 3D networks of multi-walled carbon nanotubes in binary and ternary polymer blends, suggesting a new way to produce conducting polymers.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (33 results)

All 2011 2010 2009 2008

All Journal Article (16 results) (of which Peer Reviewed: 15 results) Presentation (10 results) Book (7 results)

  • [Journal Article] Formation and Relaxation of the Elastic Strain Generated by Photocuring in Polymer Blends Monitored by Mach-Zehnder Interferometry2011

    • Author(s)
      D.-T.Van-Pham, K.Sorioka, T.Norisuye, Q.Tran-Cong-Miyata
    • Journal Title

      Polymer 52

      Pages: 739-745

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation and Relaxation of the Elastic Strain Generated by Photo-curing in Polymer Blends Monitored by Mach-Zehnder Interferometry2011

    • Author(s)
      D.-T.Van-Pham, et al.
    • Journal Title

      Polymer

      Volume: 52 Pages: 739-745

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Design and Morphology Control of Polymer Nanocomposites Using Light-Driven Phase Separation Phenomena2010

    • Author(s)
      D.-T Van-Pham, X.-A.Trinh, H.Nakanishi, Q.Tran-Cong-Miyata
    • Journal Title

      Adv.Nat.Sci. : Nanosci.Nanotechnol.(IOP, UK) Vol.1

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Design and Morphology Control of Polymer Nanocomposites Using Light-Driven Phase Separation Phenomena2010

    • Author(s)
      D.-T.Van-Pham, et al.
    • Journal Title

      Advances in Natural Sciences : Nanosci. Nanotech.

      Volume: 01

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Polymer Materials with Spatially Graded Morphologies : Preparation, Characterization and Utilization2010

    • Author(s)
      D.Fujiki, et al.
    • Journal Title

      Advances in Natural Sciences : Nanosci. Nanotech.

      Volume: 01

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Application of New Treatment Methods for "Reading" of the Complex Capacitance : a Quantitative Description of the Aging Phenomenon in Polymer Glasses2010

    • Author(s)
      R.R.Nigmatullin, et al.
    • Journal Title

      Commun Nonlinear Sci Numer Simulat.

      Volume: 15 Pages: 1286-1307

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physical Aging of Photo-Crosslinked Poly(ethyl acrylate) Observed in the Nanometer Scales by Mach-Zehnder Interferometry2009

    • Author(s)
      D.-T, Van-Pham, K.Sorioka, T.Norisuye, Q.Tran-Cong-Miyata
    • Journal Title

      Polym.J. 41

      Pages: 260-265

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Light Scattering Study on the Mode-Selection Process in Reversible Phase Separation of a Photoreactive Polymer Mixture2009

    • Author(s)
      M.Fukuoka, H.Nakanishi, T.Norisuye, Q.Tran-Cong-Miyata
    • Journal Title

      J.Phys.Chem.B 113

      Pages: 14950-14956

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Light-Induced Regularity on the Physical Properties of Multiphase Polymers2009

    • Author(s)
      K.Murata, T.Murata, H.Nakanishi, T.Norisuye, Q.Tran-Cong-Miyata
    • Journal Title

      Macromol.Mater.Eng. 294

      Pages: 163-168

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effects of Light-Induced Regularity on the Physical Properties of Multi-phase Polymers2009

    • Author(s)
      K.Murata, Q, Tran-Cong-Miyata, et.al.
    • Journal Title

      Macromol.Mater.Eng. 294

      Pages: 163-168

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physical Aging of Photo-Crosslinked Poly(ethyl acrylate) Observed in the Nanometer Scales by Mach-Zehnder Interferometry2009

    • Author(s)
      D.-T.Van-Pham, Q.Tran-Cong-Miyata, et al.
    • Journal Title

      Polymer J. 41

      Pages: 260-265

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Light Scattering Study on the Mode-Selection Process in Reversible Phase Separation of a Photoreactive Polymer Mixtures2009

    • Author(s)
      M.Fukuoka, Q, Tran-Cong-Miyata, et al.
    • Journal Title

      J.Phys.Chem.B 113

      Pages: 14950-14956

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      Q.Tran-Cong-Miyata, et al
    • Journal Title

      in "Molecular Nano Dynamics", Vol. 1, Chapter 10(H. Fukumura et al Eds.)("Morphosynthesis in Polymeric Systems Using Photochemical Reactions", Wiley-VCH)

      Pages: 173-185

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Hexagonal Phase Induced by a Reversible Photo-cross-link Reaction in a Polymer Mixture2008

    • Author(s)
      H.Nakanishi, M.Satoh, Q.Tran-Cong-Miyata
    • Journal Title

      Phys.Rev.E Rapid Commun. 77

      Pages: 20801-20801

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Hexagonal Phase Induced by a Reversible Photo-Cross-Link Reaction in a Polymer Mxtuture2008

    • Author(s)
      H. Nakanishi, M. Satoh, Q. Tran-Cong-Miyata
    • Journal Title

      Phys. Rev. E 77

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Physical Aging of Photo-Cross-linked Poly (ethyl acrylate) Observed in the Nanometer Scales by Mach-Zehnder Interferometry2008

    • Author(s)
      D. -T. Van-Pham, K. Soriok, T. Norisuye, Q. Tran-Cong-Miyata
    • Journal Title

      Polymer Journal 41

      Pages: 260-265

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Polymers with Spatially Graded Morphology Generated and Controlled by Light-Induced Phase Separation2010

    • Organizer
      the 5^<th> IWAMSN-2010
    • Place of Presentation
      Ha-Noi (Invited Talk)
    • Related Report
      2010 Final Research Report
  • [Presentation] Recent Findings in Phase Separation of Reacting Polymer Mixtures2010

    • Organizer
      The 4^<th> International Symposium on Polymer Materials Science
    • Place of Presentation
      Bordeaux, France.(Invited Talk)
    • Related Report
      2010 Final Research Report
  • [Presentation] Light-Induced Phase Separation in Polymer Mixtures as a Pattern-Formation Process : Complexity and Fascination2010

    • Organizer
      Non-linear Dynamics and Self-Organization in Chemical Systems
    • Place of Presentation
      Bordeaux, France.(Invited Talk)
    • Related Report
      2010 Final Research Report
  • [Presentation] Polymers with Spatially Graded Continuous Morphology Generated by Phase Separation under Spatially Non-uniform Conditions2010

    • Organizer
      The International Symposium on Polymer Physics (PP-2010)
    • Place of Presentation
      Ji'nan, China.(Invited Talk)
    • Related Report
      2010 Final Research Report
  • [Presentation] Light-induced Phase Separation in Polymer Mixtures as a Pattern-Formation Process : Complexity and Fascination2010

    • Author(s)
      Q.Tran-Cong-Miyata
    • Organizer
      Symposium on Nonlinear Dynamics and Self-Organization in Chemical Systems(Nonlinear Dynamics Days-NLDD 2010)
    • Place of Presentation
      Bordeaux, FRANCE
    • Related Report
      2010 Annual Research Report
  • [Presentation] Co-continuous Morphologies of Polymer Blends : Generation, Design and Practical Applications2009

    • Author(s)
      Q.Tran-Cong-Miyata
    • Organizer
      JSPS Asia and Africa Science Platform Program on Neo-Fiber Technology Seminar No. 5
    • Place of Presentation
      Ha-Noi, Viet-Nam
    • Year and Date
      2009-07-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Co-continuous Morphologies of Polymer Blends : Generation, Design and Application2009

    • Organizer
      The 5^<th> JSPS Seminar on Asia-Africa Science Platform Program on Neo-Fiber Technology
    • Place of Presentation
      Ha-Noi University of Technology, Ha-Noi, Viet-Nam.(Invited Talk)
    • Related Report
      2010 Final Research Report
  • [Presentation] Design and Morphology Control of Polymer Nanocomposites Using Light- Driven Phase Separation Phenomena2008

    • Organizer
      The Asian Workshop on Advanced Materials Science and Technology
    • Place of Presentation
      Nha-Trang, Viet-Nam.(Invited Talk)
    • Related Report
      2010 Final Research Report
  • [Presentation] Competing Interactions and Pattern Selection Driven by Chemical Reactions in Polymer Mixtures2008

    • Organizer
      The 235^<th> American Chemical Society, Division of Polymer Materials Science (PMSE)
    • Place of Presentation
      New Orleans, U.S.A.(Invited Talk)
    • Related Report
      2010 Final Research Report
  • [Presentation] Competing Interactions and Patterns Selection Driven by Chemical Reactions in Polymer Mixtures2008

    • Author(s)
      Q. Tran-Cong-Miyata
    • Organizer
      International Symposium on "Nonlinear Dynamics in Polymeric Systems"
    • Place of Presentation
      アメリカ化学会New Orleans
    • Related Report
      2008 Annual Research Report
  • [Book] Nonlinear Dynamics with Polymers 11 Chapters (J.A.Pojman and Q.Tran-Cong-Miyata 編集)2010

    • Total Pages
      260
    • Publisher
      Wiley-VCH出版
    • Related Report
      2010 Final Research Report
  • [Book] Nonlinear Dynamics with Polymers Chapter 6 ("Reaction-Induced Phase Separation of Polymeric Systems under Stationary Non-equilibrium Conditions")(J.A.Pojman and Q.Tran-Cong-Miyata Eds.)2010

    • Author(s)
      H. Nakanishi, D.Fujiki, D.-T.Van-Pham, Q.Tran-Cong-Miyata
    • Publisher
      Wiley-VCH, Weinheim
    • Related Report
      2010 Final Research Report
  • [Book] "Nonlinear Dynamics with Polymeric Systems" (J.A.Pojman anQ.Tran-Cong-Miyata Eds,), Chapter 6(pp.91-113)2010

    • Author(s)
      H.Nakanishi, et al.
    • Total Pages
      254
    • Publisher
      Wiley-VCH社
    • Related Report
      2010 Annual Research Report
  • [Book] Polymers, Liquids and Colloids in Electric Fields Chapter 6 ("Phase Separation and Morphology of Polymer Mixtures Driven by Light")(Y.Tsori and U.Steiner Eds.)2009

    • Author(s)
      Q.Tran-Cong-Miyata, H. Nakanishi
    • Publisher
      World Scientific, London
    • Related Report
      2010 Final Research Report
  • [Book] Molecular Nano Dynamics Vol.I, Chapter 10 ("Morphosynthesis in Polymeric Systems Using Photochemical Reactions")(H.Fukumura et al.Eds.)2009

    • Author(s)
      H. Nakanishi, T. Norisuye, Q. Tran-Cong-Miyata
    • Publisher
      Wiley-VCH, Weinheim
    • Related Report
      2010 Final Research Report
  • [Book] 自己組織化ハンドブック 第1章「パターン形成」、第6節(「高分子系における自己組織化」)(国武豊喜監修;下村政嗣、山口智彦編集)2009

    • Author(s)
      Q.Tran-Cong-Miyata, 中西英行
    • Publisher
      エヌ・ティー・エス出版社
    • Related Report
      2010 Final Research Report
  • [Book] "Phase Separation and Morphology of Polymer Mixtures Driven by Light" in "Polymers, Liquids and Colloids in Electric Fields", Y. Tsori and Steiner Eds., Chapter 6, pp. 171- 195.2009

    • Author(s)
      Qui Tran-Cong-Miyata, Hideyuki Nakanishi
    • Total Pages
      300
    • Publisher
      World Scientific, Singapore
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2022-01-20  

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