Optically functional devices by holographic photopolymerization in nanoparticle-polymer composites

• Project/Area Number: 20360028
• Research Category: Grant-in-Aid for Scientific Research (B)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Applied optics/Quantum optical engineering
• Research Institution: The University of Electro-Communications
• Principal Investigator: TOMITA Yasuo The University of Electro-Communications, 大学院・情報理工学研究科, 教授 (50242342)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥18,200,000 (Direct Cost: ¥14,000,000、Indirect Cost: ¥4,200,000); Fiscal Year 2010: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000); Fiscal Year 2009: ¥6,370,000 (Direct Cost: ¥4,900,000、Indirect Cost: ¥1,470,000); Fiscal Year 2008: ¥9,620,000 (Direct Cost: ¥7,400,000、Indirect Cost: ¥2,220,000)
• Keywords: 光学素子 / 光学材料 / フォトポリマー / ホログラム / ナノ微粒子

Research Abstract

It was shown that volume holograms recorded in nanoparticle-polymer composites(NPCs)by means of a holographic nanoparticle assembling method possessed high thermal stability. It was also shown that polymerization shrinkage of a volume hologram recorded in an NPC with SiO_2 nanoparticles and thiol-ene monomers can be reduced as low as 0.2%.In addition, volume holographic recording in semiconductor CdSe quantum dot-polymer composites with the diffraction efficiency near100%was demonstrated. It was also shown that a volume hologram recorded in an NPC could serve as a50%-50%beam splitter for a cold neutron beam.

Research Products

• [Journal Article] Neutron-optical gratings from nanoparticle-polymer composites (2011)
  • Author(s): J.Klepp, C.Pruner, M.A.Ellabban, Y.Tomita, H.Lemmel, H.Rauch, M.Fally
  • Journal Title: Nuclear Instruments and Methods in Physics Research A Volume: 634
  • Peer Reviewed
• [Journal Article] Neutron optical beam splitter from holographically structured nanoparticle-polymer composites (2010)
  • Author(s): M Fally, J.Klepp, Y.Tomita, T.Nakamura, C.Pruner, M.A.Ellabban, R.A.Rupp, M.Bichler, I.D.Olenik, J.Kohlbrecher, H.Eckerlebe, H.Lemmel, H.Rauch
  • Journal Title: Physical Review Letters 105
  • Peer Reviewed
• [Journal Article] Order-of-magnitude polymerization-shrinkage suppression of volume gratings recorded in nanoparticle-polymer composites (2010)
  • Author(s): E.Hata, Y.Tomita
  • Journal Title: Optics Letters 35 Pages: 396-398
  • Peer Reviewed
• [Journal Article] Photopolymerization kinetics and volume holographic recording in ZrO_2 nanoparticle- polymer composites at 404nm (2010)
  • Author(s): K.Omura, Y.Tomita
  • Journal Title: Journal of Applied Physics 107
  • Peer Reviewed
• [Journal Article] Neutron optical beam splitter from holographically structured nanoparticle-polymer composites (2010)
  • Author(s): M Fully, J.Klepp, Y.Tomita, et al.
  • Journal Title: Physical Review Letters Volume: 105
  • Peer Reviewed
• [Journal Article] Nonlinear optical responses of nanoparticle-polymer composites incorporating organic(hyperbranched polymer)-metallic nanoparticle complex (2010)
  • Author(s): X.Liu, K.Matsumura, Y.Tomita, K.Yasui, K.Kojima, K.Chikama
  • Journal Title: Journal of Applied Physics Volume: 108
  • Peer Reviewed
• [Journal Article] Photopolymerization kinetics and volume holographic recording in ZrO_2 nanoparticle-polymer composites at 404nm (2010)
  • Author(s): K.Omura, Y.Tomita
  • Journal Title: Journal of Applied Physics 107
  • Peer Reviewed
• [Journal Article] Holographic assembly of semiconductor CdSe quantum dots in polymer for volume Bragg grating structures with diffraction efficiency near 100% (2009)
  • Author(s): X.Liu, Y.Tomita, J.Oshima, K.Chikama, K.Matsubara, T.Nakashima, T.Kawai
  • Journal Title: Applied Physics Letters 95
  • Peer Reviewed
• [Journal Article] Holographic recording sensitivity enhancement of ZrO_2 nanoparticle- polymer composites by hydrogen donor and acceptor agents (2009)
  • Author(s): T.Nakamura, J.Nozaki, Y.Tomita, K.Ohmori, M.Hidaka
  • Journal Title: Journal of Optics A : Pure and Applied Optics 11(invited paper)
  • Peer Reviewed
• [Journal Article] Holographic recording sensitivity enhancement of ZrO_2nanoparticle-polymer composites by hydrogen donor and acceptor agents(invited paper) (2009)
  • Author(s): T. Nakamura, J. Nozaki, Y. Tomita, K. Ohmori, M. Hidaka
  • Journal Title: Journal of Optics A : Pure and Applied Optics 11
  • Peer Reviewed
• [Journal Article] Improved thermal stability of volume holograms recorded in nanoparticle-polymer composite films (2008)
  • Author(s): Y Tomita, T.Nakamura, A.Tago
  • Journal Title: Optics Letters 33 Pages: 1750-1752
  • Peer Reviewed
• [Journal Article] Improved thermal stability of volume holograms recorded in nanoparticle-polymer composite films (2008)
  • Author(s): Y Tomita, T. Nakamura, A. Tago
  • Journal Title: Optics Letters 33 Pages: 1750-1752
  • Peer Reviewed
• [Presentation] ホログラフィック応用、非線形光学、中性子光学のための光重合性ナノコンポジットポリマー (2011)
  • Author(s): 富田康生
  • Organizer: 第58回応用物理学関係連合講演会
  • Place of Presentation: 分科内招待講演
  • Year and Date: 2011-03-25
• [Presentation] ホログラフィック応用、非線形光学、中性子光学のための光重合性ナノコンポジットポリマー (2011)
  • Author(s): 富田康生
  • Organizer: 第58回応用物理学関係連合講演会
  • Place of Presentation: 神奈川工科大学(神奈川県)(分科内招待講演)(東日本大震災のため中止)
  • Year and Date: 2011-03-25
• [Presentation] 低重合収縮・高屈折率変調特性を有するナノ微粒子-ポリマーコンポジットIV (2011)
  • Author(s): 羽田英司、富田康生
  • Organizer: 第58回応用物理学関係連合講演会
  • Place of Presentation: 神奈川工科大学(神奈川県)(東日本大震災のため中止)
  • Year and Date: 2011-03-25
• [Presentation] ナノ微粒子-ポリマーコンポジットを用いたホログラフィックページデータ記録 (2011)
  • Author(s): 百瀬啓祐、高山新吾、富田康生
  • Organizer: 第58回応用物理学関係連合講演会
  • Place of Presentation: 神奈川工科大学(神奈川県)(東日本大震災のため中止)
  • Year and Date: 2011-03-24
• [Presentation] 高屈折率変調・低重合収縮・高熱的安定性を有する無機ナノ微粒子-ポリマーコンポジット (2010)
  • Author(s): 羽田英司、富田康生
  • Organizer: 日本光学会年次学術講演会 Optics & Photonics Japan 2010
  • Place of Presentation: 駿河台記念会館(東京都)
  • Year and Date: 2010-11-08
• [Presentation] Polymer-composites and polymers as beam splitters for neutrons (2010)
  • Author(s): M.Fally, J.Klepp, C.Pruner, M.Bichler, I.Drevensek Olenik, Y.Tomita, J.Kohlbrecher, H.Fckerlebe
  • Organizer: 10th Austrian Polymer Meeting and 2nd Joint Austrian-Slovenian Polymer Meeting
  • Place of Presentation: Leoben, Austria
  • Year and Date: 2010-09-09
• [Presentation] 低重合収縮・高屈折率変調特性を有するナノ微粒子-ポリマーコンポジットIII (2010)
  • Author(s): 羽田英司、富田康生
  • Organizer: 第71回応用物理学会学術講演会
  • Place of Presentation: 長崎大学(長崎県)
  • Year and Date: 2010-09-08
• [Presentation] 1D photonic lattice structures fabricated by holographic assembly of semiconductor quantum dots in photopolymer films (2010)
  • Author(s): X.Liu, Y.Tomita, J.Oshima, K.Chikama, T.Nakashima, T.Kawai
  • Organizer: 15th Optoelectronics and Communications Conference(OECC 2010)
  • Place of Presentation: Sapporo, Japan
  • Year and Date: 2010-07-07
• [Presentation] Holographic patterning of semiconductor quantum dots in polymer for constructing photonic lattice structures (2010)
  • Author(s): X.Liu, Y.Tomita, J.Oshima, K.Chikama, T.Nakashima, T.Kawai
  • Organizer: The 2010 Conference on Lasers and Electro-Optics/Quantum Electronics and Laser Science Conference (CLEO/QELS 2010)
  • Place of Presentation: San Jose, California, U.S.A.
  • Year and Date: 2010-05-20
• [Presentation] Holographic patterning of semiconductor quantum dots in polymer for constructing photonic lattice structures (2010)
  • Author(s): X.Liu, Y.Tomita, J.Oshima, K.Chikama, T.Nakashima, T.Kawai
  • Organizer: CLEO/QELS 2010
  • Place of Presentation: San Jose, U.S.A.
  • Year and Date: 2010-05-20
• [Presentation] Low polymerization-shrinkage nanoparticle-polymer composite films based on thiol-ene photopolymerization for holographic data storage (2010)
  • Author(s): Y.Tomita, E.Hata, K.Omura, S.Yasui
  • Organizer: SPIE Photonics Europe
  • Place of Presentation: Brussels, Belgium
  • Year and Date: 2010-04-13
• [Presentation] Z-scan characterization of nonlinear optical effects in polymer films incorporating hyperbranched polymer-metallic nanoparticle complex (2010)
  • Author(s): X.Liu, Y.Tomita, K Yasui, K.Kojima, K.Chikama
  • Organizer: SPIE Photonics Europe
  • Place of Presentation: Brussels, Belgium
  • Year and Date: 2010-04-13
• [Presentation] 低重合収縮・高屈折率変調特性を有するナノ微粒子-ポリマーコンポジットII (2010)
  • Author(s): 羽田英司, 富田康生
  • Organizer: 第57回応用物理学関係連合講演会
  • Place of Presentation: 東海大学
  • Year and Date: 2010-03-17
• [Presentation] チオール・エンモノマーを用いたナノ微粒子-ポリマーコンポジットの青紫色波長領域におけるホログラフィック記録特性 (2010)
  • Author(s): 大村考志, 安井理, 富田康生
  • Organizer: 第57回応用物理学関係連合講演会
  • Place of Presentation: 東海大学
  • Year and Date: 2010-03-17
• [Presentation] High contrast Bragg grating structures fabricated by holographic assembly of semiconductor CdSe quantum dots in polymer (2010)
  • Author(s): X.Liu, Y.Tomita, J.Oshima, K.Chikama, T.Nakashima, T.Kawai
  • Organizer: 第57回応用物理学関係連合講演会
  • Place of Presentation: 東海大学
  • Year and Date: 2010-03-17
• [Presentation] 青紫波長領域におけるナノ微粒子-ポリマーコンポジットのホログラフィック記録特性 (2009)
  • Author(s): 大村孝志, 富田康生
  • Organizer: 第70回応用物理学会学術講演会
  • Place of Presentation: 富山大学
  • Year and Date: 2009-09-08
• [Presentation] 低重合収縮・高屈折率変調特性を有するナノ微粒子-ポリマーコンポジット (2009)
  • Author(s): 羽田英司, 富田康生
  • Organizer: 第70回応用物理学会学術講演会
  • Place of Presentation: 富山大学
  • Year and Date: 2009-09-08
• [Presentation] Z-scan measurement of nonlinear absorption and refraction in nanocomposites doped with hyperbranched polymer-metallic nanoparticle complex (2009)
  • Author(s): X.Liu, Y.Tomita, K.Yasui, K.Kojima
  • Organizer: 第70回応用物理学会学術講演会
  • Place of Presentation: 富山大学
  • Year and Date: 2009-09-08
• [Presentation] Holographic nanoparticle-polymer composites for photonics and neutron optics (2009)
  • Author(s): 富田康生
  • Organizer: The eighth Japan-Finland Joint Symposium on Optics in Engineering (OIE) '09
  • Place of Presentation: Tokyo, Japan, (invited talk)
  • Year and Date: 2009-09-04
• [Presentation] Holographic nanoparticle-polymer composites for photonics and neutron optics (2009)
  • Author(s): 富田康生
  • Organizer: The 8th Japan-Finland Joint Symposium on Optics in Engineering (OIE'09)
  • Place of Presentation: Tokyo, Japan
  • Year and Date: 2009-09-04
• [Presentation] Nonlinear optical properties of hyperbranched polymer-metallic nanoparticle complex in a polymer film and organic solution (2009)
  • Author(s): X.Liu, Y.Tomita, K.Yasui, K.Kojima
  • Organizer: The 8th Japan-Finland Joint Symposium on Optics in Engineering (OIE'09)
  • Place of Presentation: Tokyo, Japan
  • Year and Date: 2009-09-04
• [Presentation] Characterization of hologram multiplexing in nanoparticle-polymer composites (2009)
  • Author(s): S.Koda, E.Hata, Y.Tomita
  • Organizer: SPIE Optics & Photonics 2009 Symposium
  • Place of Presentation: San Diego, U.S.A.
  • Year and Date: 2009-08-05
• [Presentation] Blue-sensitive nanoparticle-polymer composites for volume holographic recording (2009)
  • Author(s): K.Omura, K.Gotoh, Y.Tomita, K.Ohmori, M.Hidaka
  • Organizer: SPIE Optics & Photonics 2009 Symposium
  • Place of Presentation: San Diego, U.S.A.
  • Year and Date: 2009-08-05
• [Presentation] Volume holographic recording in nanoparticle-polymer composites with reduced polymerization shrinkage (2009)
  • Author(s): E.Hata, S.Koda, K.Gotoh, Y.Tomita
  • Organizer: Conference on Lasers and Electro-Optics (CLEO)-Europe
  • Place of Presentation: Munich, Germany
  • Year and Date: 2009-06-18
• [Presentation] Volume holographic recording in nanoparticle-polymer composites with reduced polymerization shrinkage (2009)
  • Author(s): E.Hata, S.Koda, K.Gotoh, Y.Tomita
  • Organizer: CLEO-Europe
  • Place of Presentation: Munich, Germany
  • Year and Date: 2009-06-18
• [Presentation] Photonic nanocomposite media for holographic data storage (2009)
  • Author(s): 富田康生
  • Organizer: IEEE/LEOS Optical Data Storage (ODS) 2009
  • Place of Presentation: Lake Buena Vista, Florida, USA, (invited talk)
  • Year and Date: 2009-05-13
• [Presentation] Photonic nanocomposite media for holographic data storage (2009)
  • Author(s): 富田康生
  • Organizer: Technical Digest of IEEE/LEOS Optical Data Storage 2009 (ODS 2009)
  • Place of Presentation: Lake Buena Vista, USA
  • Year and Date: 2009-05-13
• [Presentation] ZrO_2ナノ微粒子-ポリマーコンポジット中に記録された体積ホログラムの格子間隔依存性 (2009)
  • Author(s): 中村俊博, 富田康生
  • Organizer: 第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-04-01
• [Presentation] ナノ微粒子-ポリマーコンポジットの青紫波長域におけるホログラフィク記録特性 (2009)
  • Author(s): 大村孝志, 富田康生, 大森健太郎, 日高基彦
  • Organizer: 第56回応用物群関係連合講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-04-01
• [Presentation] ナノ微粒子-ポリマーコンポジット中に記録された体積ホログラムの重合収縮低減化 (2009)
  • Author(s): 羽田英司, 中村俊博, 富田康生
  • Organizer: 第56回応用物理学関係連合講演会
  • Place of Presentation: 筑波大学
  • Year and Date: 2009-04-01
• [Presentation] 水素供与体/受容体添加によるZrO_2ナノ微粒子-ポリマーコンポジットのホログラフィック記録特性 (2008)
  • Author(s): 中村俊博, 富田康生, 大森健太郎, 日高基彦
  • Organizer: 第6 9回応用物理学会学術講演会
  • Place of Presentation: 名古屋
  • Year and Date: 2008-09-04
• [Presentation] ナノ微粒子-ポリマーコンポジットフィルムを用いた体積ホログラム多重記録 (2008)
  • Author(s): 香田粗光, 富田康生
  • Organizer: 第6 9回応用物理学会学術講演会
  • Place of Presentation: 名古屋
  • Year and Date: 2008-09-04
• [Presentation] ZrO_2 nanoparticle-polymer composite media for volume holographic recording (2008)
  • Author(s): T. Nakamura, S. Koda, K. Ohmura, Y. Tomita
  • Organizer: Joint International Symposium on Optical Memory and Optical Data Storage 2008 (ISOM/ODS 2008)
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2008-07-15
• [Presentation] ZrO_2 nanoparticle-polymer composite media for volume holographic recording (2008)
  • Author(s): T.Nakamura, S.Koda, K.Ohmura, Y.Tomita
  • Organizer: The Joint International Symposium on Optical Memory and IEEE/LEOS Optical Data Storage (ISOM/ODS) 2008
  • Place of Presentation: Waikoloa, Hawaii, USA
  • Year and Date: 2008-07-14
• [Presentation] On the thermal stability of volume holograms recorded in nanoparticle-polymer composite films (2008)
  • Author(s): Y. Tomita, T. Nakamura, A. Tago
  • Organizer: SPIE International Symposium on Photonics Europe
  • Place of Presentation: Strasbourg, France
  • Year and Date: 2008-04-09
• [Book] Holographic nanoparticlephotopolymer composites (2011)
  • Author(s): Y.Tomita
  • Total Pages: 16
  • Publisher: American Scientific Publishers(in press)
• [Remarks] ホームページ等
  • URL: http://talbot.ee.uec.ac.jp/
• [Patent(Industrial Property Rights)] 半導体微粒子を含む体積ホログラム記録材料組成物 (2009)
  • Inventor(s): 富田康生、大島寿朗
  • Industrial Property Rights Holder: 電気通信大学、日産化学工業(株)
  • Industrial Property Number: 2009-295777
  • Filing Date: 2009-12-25
• [Patent(Industrial Property Rights)] 金属ナノ微粒子-アンモニウム基含有高分子化合物複合体を含有する感光性組成物 (2009)
  • Inventor(s): 富田康生、小島圭介、大土井啓祐
  • Industrial Property Rights Holder: 電気通信大学、日産化学工業(株)
  • Industrial Property Number: 2009-201642
  • Filing Date: 2009-09-01
• [Patent(Industrial Property Rights)] ビニルシクロプロパンを含む感光性組成物 (2009)
  • Inventor(s): 富田康生、中村俊博、広岡明、大森健太郎、大島寿朗
  • Industrial Property Rights Holder: 電気通信大学、日産化学工業(株)
  • Industrial Property Number: 2009-112333
  • Filing Date: 2009-05-01
• [Patent(Industrial Property Rights)] 体積ホログラム記録材料及びホログラム記録媒体 (2009)
  • Inventor(s): 富田康生、羽田英司、小島圭介、大森健太郎
  • Industrial Property Rights Holder: 電気通信大学、日産化学工業(株)
  • Industrial Property Number: 2009-075666
  • Filing Date: 2009-03-26
• [Patent(Industrial Property Rights)] 金属ナノ微粒子-アンモニウム基含有分岐高分子化合物複合体を含有する感光性組成物 (2009)
  • Inventor(s): 富田康生, 小島圭介, 大土井啓祐
  • Industrial Property Rights Holder: 電気通信大学、日産化学工業 (株)
  • Industrial Property Number: 2009-201642
  • Filing Date: 2009-09-01
• [Patent(Industrial Property Rights)] 半導体微粒子を含む体積ホログラム記録材料組成物 (2009)
  • Inventor(s): 富田康生, 大島寿朗
  • Industrial Property Rights Holder: 電気通信大学、日産化学工業 (株)
  • Industrial Property Number: 2009-295777
  • Filing Date: 2009-12-25
• [Patent(Industrial Property Rights)] 体積ホログラム記録材料用組成物及びホログラム記録媒体 (2009)
  • Inventor(s): 富田康生, 他3名
  • Industrial Property Rights Holder: 富田康生, 他3名
  • Industrial Property Number: 2009-075666
  • Filing Date: 2009-03-26