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Development of Production Method of Fine Particle by Continuous Plasma-Induced Cathodic Discharge Electrolysis

Research Project

Project/Area Number 20360345
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Metal making engineering
Research InstitutionDoshisha University

Principal Investigator

ITO Yasuhiko  Doshisha University, 理工学部, 教授 (20026066)

Co-Investigator(Kenkyū-buntansha) WADA Motoi  同志社大学, 生命医科学部, 教授 (30201263)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥14,690,000 (Direct Cost: ¥11,300,000、Indirect Cost: ¥3,390,000)
Fiscal Year 2010: ¥4,290,000 (Direct Cost: ¥3,300,000、Indirect Cost: ¥990,000)
Fiscal Year 2009: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000)
Fiscal Year 2008: ¥6,240,000 (Direct Cost: ¥4,800,000、Indirect Cost: ¥1,440,000)
Keywordsプラズマ誘起電解 / 大気圧プラズマ / 放電電解 / 溶融塩 / 溶融塩電解 / 連続製造システム / 金属ナノ粒子 / 陰極放電
Research Abstract

In this study, plasma-induced cathodic discharge electrolysis using a rotating disk anode was conducted in molten LiCl-KCl-CsCl electrolytes, and Ni nanoparticles with diameters of less than 10 nm were obtained. The obtained particles became smaller and more uniform when rotation speed of the disk anode increased until it reached 2,000 rpm; meanwhile, the size of the obtained particle hardly depended on the rotation speed when it exceeded 2,000 rpm. Regardless of rotation speeds, the electrolysis current (0.1-5.0 A) did not affect the size of the particle. The rotating disk anode-type electrolytic cell, therefore, controls the particle growth by the rotation speed of the disk anode.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (45 results)

All 2011 2010 2009 2008 Other

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (26 results) Remarks (1 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Formation of Co-Pt Intermetallic Compound Nanoparticles by Plasma-Induced Cathodic Discharge Electrolysis in a Chloride Melt2011

    • Author(s)
      M. Tokushige, A. Matsuura, T. Nishikiori, Y. Ito
    • Journal Title

      J.Electrochem.Soc. 158

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Co-Pt Intermetallic Compound Nanoparticles by Plasma-Induced Cathodic Discharge Electrolysis in a Chloride Melt2011

    • Author(s)
      M.Tokushige, A.Matsuura, T.Nishikiori, Y.Ito
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 158

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of FePt Intermetallic Compound Nanoparticles by Plasma-Induced Cathodic Discharge Electrolysis2010

    • Author(s)
      M. Tokushige, T. Nishikiori, M. C. Lafouresse, C. Michioka, K. Yoshimura, Y. Fukunaka, Y. Ito
    • Journal Title

      Electrochimica Acta 55

      Pages: 8154-8159

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Fine Ni Nanoparticle by Plasma-Induced Cathodic Discharge Electrolysis Using Rotating Disk Anode2010

    • Author(s)
      M. Tokushige, T. Nishikiori, Y. Ito
    • Journal Title

      J.Electrochem.Soc. 157

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Plasma-Induced Cathodic Discharge Electrolysis to Form Various Metal/ Alloy Nanoparticles2010

    • Author(s)
      M. Tokushige, T. Nishikiori, Y. Ito
    • Journal Title

      Russ.J.Electrochem. 46

      Pages: 619-626

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Plasma-Induced Cathodic Discharge Electrolysis to Form Various Metal/ Alloy Nanoparticles2010

    • Author(s)
      M.Tokushige, T.Nishikiori, Y.Ito
    • Journal Title

      Russian Journal of Electrochemistry

      Volume: 46 Pages: 619-626

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of Fine Ni Nanoparticle by Plasma-Induced Cathodic Discharge Electrolysis Using Rotating Disk Anode2010

    • Author(s)
      M.Tokushige, T.Nishikiori, Y.Ito
    • Journal Title

      Journal of the Electrochemical Society

      Volume: 157

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of FePt Intermetallic Compound Nanoparticles by Plasma-Induced Cathodic Discharge Electrolysis2010

    • Author(s)
      M.Tokushige, T.Nishikiori, M.C.Lafouresse, C.Michioka, K.Yoshimura, Y.Fukunaka, Y.Ito
    • Journal Title

      Electrochimica Acta

      Volume: 55 Pages: 8154-8159

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Plasma-Induced Cathodic Discharge Electrolysis to Form Various Metal/Alloy Nanoparticles2010

    • Author(s)
      M.Tokushige, T.Nishikiori, Y.Ito
    • Journal Title

      Russian Journal of Electrochemistry (掲載確定)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of FePt intermetallic compound nanoparticle by plasma-induced cathodic discharge electrolysis2010

    • Author(s)
      M.Tokushige, T.Nishikiori, M.C.Lafouresse, C.Michioka, K.Yoshimura, Y.Fukunaka, Y.Ito
    • Journal Title

      Electrochimica Acta Available online

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ni Nanoparticles by Plasma- Induced Cathodic Discharge Electrolysis2009

    • Author(s)
      M. Tokushige, T. Nishikiori, Y. Ito
    • Journal Title

      J.Appl.Electrochem. 39

      Pages: 1665-1670

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Magnetic Nanoparticles (Fe and FePt) by Plasma-Induced Cathodic Discharge Electrolysis2009

    • Author(s)
      M. Tokushige, T. Yamanaka, A. Matsuura, T. Nishikiori, Y. Ito
    • Journal Title

      IEEE Transactions on Plasma Sci. 37

      Pages: 1156-1160

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ni Nanoparticle by Plasma-Induced Cathodic Discharge Electrolysis2009

    • Author(s)
      M.Tokushige, T.Nishikiori, Yasuhiko Ito
    • Journal Title

      Journal of Applied Electrochemistry 39

      Pages: 1665-1670

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Magnetic nanoparticles(Fe and FePt intermetallic compound)by Plasma-Induced Cathodic Discharge Electrolysis2009

    • Author(s)
      M.Tokushige, T.Yamanaka, A.Matsuura, T.Nishikiori, Y.Ito
    • Journal Title

      IEEE Transactions on Plasma Science 37

      Pages: 1156-1160

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Ni Nanoparticle by Plasma-Induced Electrolysis2009

    • Author(s)
      Manabu Tokushige, Tokujiro Nishikiori, Yasuhiko Ito
    • Journal Title

      Journal of Applied Electrochemistry (available online)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Magnetic nanoparticles (Fe and FePt intermetallic compound) by Plasma-Induced Electrolysis2009

    • Author(s)
      Manabu Tokushige, Takashi Yamanaka, Akira Matsuura, Tokujiro Nishikiori, Yasuhiko Ito
    • Journal Title

      Special Issue of the IEEE Transactions on Plasma Science, Plasma-Based Surface Modification and Treatment Technologies 37巻1号

      Pages: 1156-1160

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 溶融塩を活用した電解技術の創出と展開2011

    • Author(s)
      伊藤靖彦
    • Organizer
      電気化学会第78回大会特別講演
    • Place of Presentation
      横浜国立大学(横浜)(紙面開催)
    • Year and Date
      2011-03-30
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] プラズマ誘起電解による金属酸化物粒子からの金属ナノ粒子の形成2010

    • Author(s)
      徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      粉体粉末冶金協会平成22年度秋季大会
    • Place of Presentation
      京都大学(京都)
    • Year and Date
      2010-11-11
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] プラズマ誘起電解によるFePtナノ粒子の形成2010

    • Author(s)
      徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第42回溶融塩化学討論会
    • Place of Presentation
      ロワジールホテル函館(函館)
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] プラズマ誘起電解によるSm-Co合金ナノ粒子の形成2010

    • Author(s)
      本郷裕丈、徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第42回溶融塩化学討論会
    • Place of Presentation
      ロワジールホテル函館(函館)
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 新規な溶融塩電解プロセス~実用化への挑戦~2010

    • Author(s)
      伊藤靖彦
    • Organizer
      第81回電気化学会電解科学技術委員会および第11回R&D研究懇談会
    • Place of Presentation
      カネカ研修センター芦屋荘(芦屋)
    • Year and Date
      2010-05-26
    • Related Report
      2010 Final Research Report
  • [Presentation] 新規な溶融塩電解プロセス~実用化への挑戦~2010

    • Author(s)
      伊藤靖彦
    • Organizer
      第81回電気化学会電解科学技術委員会および 第11回R&D研究懇談会
    • Place of Presentation
      カネカ 研修センター芦屋荘(芦屋)
    • Year and Date
      2010-05-26
    • Related Report
      2010 Annual Research Report
  • [Presentation] プラズマ誘起電解によるZrナノ粒子の作製2009

    • Author(s)
      徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館(京都)
    • Year and Date
      2009-12-04
    • Related Report
      2010 Final Research Report
  • [Presentation] プラズマ誘起電解によるSm-Co合金微粒子の作製2009

    • Author(s)
      本郷裕丈、徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館(京都)
    • Year and Date
      2009-12-04
    • Related Report
      2010 Final Research Report
  • [Presentation] プラズマ誘起電解によるZrナノ粒子の作製2009

    • Author(s)
      徳重学, 錦織徳二郎, 伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館
    • Year and Date
      2009-12-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] プラズマ誘起電解によるSm-Co合金微粒子の作製2009

    • Author(s)
      本郷裕丈, 徳重学, 錦織徳次郎, 伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館
    • Year and Date
      2009-12-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] プラズマ誘起電解による白金コバルト合金微粒子の作製2009

    • Author(s)
      松浦陽, 徳重学, 錦織徳二郎, 伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] プラズマ誘起電解によるTaナノ粒子の作製2009

    • Author(s)
      藤井直也, 徳重学, 錦織徳二郎, 伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] プラズマ誘起電解によるTaナノ粒子の作製2009

    • Author(s)
      藤井直也、徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館(京都)
    • Year and Date
      2009-12-01
    • Related Report
      2010 Final Research Report
  • [Presentation] プラズマ誘起電解による白金コバルト合金微粒子の作製2009

    • Author(s)
      松浦陽、徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第26回プラズマ・核融合学会年会
    • Place of Presentation
      京都市国際交流会館(京都)
    • Year and Date
      2009-12-01
    • Related Report
      2010 Final Research Report
  • [Presentation] 連続的プラズマ誘起電解よる金属ナノ粒子の形成2009

    • Author(s)
      徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第41回溶融塩化学討論会
    • Place of Presentation
      京大会館(京都)
    • Year and Date
      2009-11-19
    • Related Report
      2010 Final Research Report
  • [Presentation] プラズマ誘起電解による金属ナノ粒子の作製工程の連続化2009

    • Author(s)
      徳重学, 錦織徳二郎, 伊藤靖彦
    • Organizer
      第41回溶融塩化学討論会
    • Place of Presentation
      京大会館(京都)
    • Year and Date
      2009-11-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] プラズマ誘起電解を用いたFePt金属間化合物ナノ粒子の作製2009

    • Author(s)
      徳重学、錦織徳二郎、福間浩司、伊藤靖彦
    • Organizer
      粉体粉末冶金協会平成21年度春季大会
    • Place of Presentation
      京都工芸繊維大学(京都)
    • Year and Date
      2009-06-04
    • Related Report
      2010 Final Research Report
  • [Presentation] プラズマ誘起電解による金属間化合物ナノ粒子の作製2009

    • Author(s)
      徳重学, 錦織徳二郎, 福間浩司, 伊藤靖彦
    • Organizer
      粉体粉末冶金協会平成21年度春季大会
    • Place of Presentation
      京都工芸繊維大学(京都)
    • Year and Date
      2009-06-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] プラズマ誘起電解によるレアメタルナノ粒子の作製とそのリサイクルへの展開2008

    • Author(s)
      藤井直也、徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第25回プラズマ・核融合学会年会
    • Place of Presentation
      栃木県総合文化センター(宇都宮)
    • Year and Date
      2008-12-04
    • Related Report
      2010 Final Research Report
  • [Presentation] プラズマ誘起電解を用いたCo-Pt合金ナノ粒子の作製2008

    • Author(s)
      松浦陽、徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第25回プラズマ・核融合学会年会
    • Place of Presentation
      栃木県総合文化センター(宇都宮)
    • Year and Date
      2008-12-04
    • Related Report
      2010 Final Research Report
  • [Presentation] 連続的プラズマ誘起電解による金属ナノ粒子の作製と作製粒子の微細化2008

    • Author(s)
      徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第25回プラズマ・核融合学会年会
    • Place of Presentation
      栃木県総合文化センター(宇都宮)
    • Year and Date
      2008-12-04
    • Related Report
      2010 Final Research Report
  • [Presentation] 連続的プラズマ誘起電解による金属ナノ粒子の作製と作製粒子の微細化2008

    • Author(s)
      徳重学, 錦織徳二郎, 伊藤靖彦
    • Organizer
      第25回プラズマ・核融合学会年会
    • Place of Presentation
      栃木県宇都宮市
    • Year and Date
      2008-12-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] Production of Metal Nanoparticles by Plasma- Induced Cathodic Discharge Electrolysis and Novel Continuous Production System2008

    • Author(s)
      M. Tokushige, T. Nishikiori, Y. Ito
    • Organizer
      2008 Joint Symposium on Molten Salts
    • Place of Presentation
      Nichi-I Gakkan Port Island Center, Kobe
    • Year and Date
      2008-10-23
    • Related Report
      2010 Final Research Report
  • [Presentation] Production of Metal Nanoparticles by Plasma-Induced Cathodic Discharge Electrolysis and Novel Continuous Production System2008

    • Author(s)
      Manabu Tokushige, Tokujiro Nishikiori, Yasuhiko Ito
    • Organizer
      2008 Molten Salts Joint Symposium
    • Place of Presentation
      兵庫県神戸市
    • Year and Date
      2008-10-23
    • Related Report
      2008 Annual Research Report
  • [Presentation] プラズマ誘起電解による金属ナノ粒子の作製2008

    • Author(s)
      徳重学、錦織徳二郎、伊藤靖彦
    • Organizer
      第50回マテリアルズ・テーラリング研究会
    • Place of Presentation
      加藤科学振興会軽井沢研修所(軽井沢)
    • Related Report
      2010 Final Research Report
  • [Presentation] プラズマ誘起電解による金属ナノ粒子の作製2008

    • Author(s)
      徳重学, 錦織徳二郎, 伊藤靖彦
    • Organizer
      第50回マテリアルズ・テーラリング研究会
    • Place of Presentation
      長野県軽井沢市
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ等

    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 金属微粒子の製造方法2010

    • Inventor(s)
      伊藤靖彦、徳重学、錦織徳二郎、辻村浩行
    • Industrial Property Rights Holder
      学校法人同志社・アイ'エムセップ株式会社
    • Industrial Property Number
      2010-246040
    • Filing Date
      2010-11-02
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Patent(Industrial Property Rights)] プラズマ誘起電解による微粒子の製造方法およびその装置2008

    • Inventor(s)
      伊藤靖彦、錦織徳二郎、徳重学
    • Industrial Property Rights Holder
      学校法人同志社・アイ'エムセップ株式会社
    • Patent Publication Number
      2008-106309
    • Filing Date
      2008-05-08
    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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