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Controlling the properties of organic/inorganic nanocomposites by surface design of functional nanoparticles

Research Project

Project/Area Number 20360346
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

KAMIYA Hidehiro  Tokyo University of Agriculture and Technology, 大学院・工学研究院, 教授 (20183783)

Co-Investigator(Kenkyū-buntansha) LENGGORO Wuled  東京農工大学, 大学院・工学研究院, 准教授 (10304403)
IIJIMA Motoyuki  東京農工大学, 大学院・工学研究院, 助教 (70513745)
Co-Investigator(Renkei-kenkyūsha) TSUKADA Mayumi  東京農工大学, 大学院・工学府, 技術専門職員 (70376870)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥18,850,000 (Direct Cost: ¥14,500,000、Indirect Cost: ¥4,350,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2009: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2008: ¥11,700,000 (Direct Cost: ¥9,000,000、Indirect Cost: ¥2,700,000)
Keywordsナノ材料 / 表面・界面物性 / 複合材料・物性
Research Abstract

Toward preparation of polymer based nanocomposite materials with uniformly dispersed nanoparticles, a new surface modification process was developed to prevent the aggregation of functional nanoparticles. Nanoparticles dispersible in various solvents and polymers were successfully prepared by developing new modification protocols, tuning surface chemical structures, and conducting multiple surface modifications. Furthermore, the effect of surface chemical structure of nanoparticles on the properties of nanocomposites has been investigated.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (38 results)

All 2011 2010 2009 2008

All Journal Article (14 results) (of which Peer Reviewed: 14 results) Presentation (22 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Effect of additive ratio of mixed silane alkoxides on reactivity with TiO_2 nanoparticle surface and their stability in organic solvents2011

    • Author(s)
      Motoyuki Iijima、Shun Takenouchi、I.Wuled Lenggoro、Hidehiro Kamiya
    • Journal Title

      Adv.Powder Technol. In press(掲載決定)

    • NAID

      10030477789

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Effect of additive ratio of mixed silane alkoxides on reactivity with TiO_2 nanoparticle surface and their stability in organic solvents2010

    • Author(s)
      Motoyuki lijima, et al.
    • Journal Title

      Advanced Powder Technology

      Volume: In press(In press(掲載決定))

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dispersion behavior and surface interaction control of SiC nanoparticles in aqueous media by using polymeric dispersants2010

    • Author(s)
      Yousuke Nomura, et al.
    • Journal Title

      Ceramic Transactions

      Volume: 219 Pages: 117-122

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Advanced Powder Technology2010

    • Author(s)
      M.Nazli Naim, et al.
    • Journal Title

      Electrical-driven disaggregation of the two-dimensional assembly of colloidal polymer particles under pulse DC charging

      Volume: 21(5) Pages: 534-541

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface modification and characterization for dispersion stability of norganic nanometer-scaled particles in liquid media2010

    • Author(s)
      Hidehiro Kamiya, et al.
    • Journal Title

      Science and Technology of Advanced Materials

      Volume: 11(4) Pages: 44304-44304

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Colloids and Surfaces, A2010

    • Author(s)
      M.Nazli Naim, et al.
    • Journal Title

      Electrophoretic packing structure from aqueous nanoparticle suspension in pulse DC charging

      Volume: 360(1-3) Pages: 13-19

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anionic Surfactant with Hydrophobic and Hydrophilic Chains for Nanoparticle Dispersion and Shape Memory Polymer Nanocomposites2009

    • Author(s)
      Motoyuki Iijima、Murino Kobayakawa、Miwa Yamazaki、Yasuhiro Ohta、Hidehiro Kamiya
    • Journal Title

      J.Am.Chem.Soc. Vol.131、No.45

      Pages: 16324-16343

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface modification of BaTiO_3 particles by silane coupling agents in different solvents and their effect on dielectric properties of BaTiO_3/epoxy composites2009

    • Author(s)
      Motoyuki Iijima、Nobuhiro Sato、I.Wuled Lenggoro、Hidehiro Kamiya
    • Journal Title

      Colloids and Surfaces A Vol.352、No.1-3

      Pages: 88-93

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Tuning the stability of TiO_2 nanoparticles in various solvents by mixed silane alkoxides2009

    • Author(s)
      Motoyuki Iijima、Murino Kobayakawa、Hidehiro Kamiya
    • Journal Title

      J.Colloid and Interface Sci. Vol.337, No.1

      Pages: 61-65

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Surface modification of BaTiO_3 particles by silane coupling agents in different solvents and their effect on dielectric properties of BaTiO_3/epoxy composites2009

    • Author(s)
      Motoyuki Iijima, et al.
    • Journal Title

      Colloid and Surface A 352(1-3)

      Pages: 88-93

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Anionic surfactant with hydrophobic and hydrophilic chains for nanopartitle dispersion and shape memory polymer nanocomposites2009

    • Author(s)
      Motoyuki Iijima, et al.
    • Journal Title

      Journal of the American Chemical Society 131(45)

      Pages: 16342-16343

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface modification for improving the stability of nanoparticles in liquid media2009

    • Author(s)
      Motoyuki Iijima, et al.
    • Journal Title

      KONA Powder and Particle Journal 27

      Pages: 119-129

    • NAID

      130003398482

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Tuning the Stability of TiO_2 Nanopartic1es in Various Solvents by Mixed Silane Alkoxides2009

    • Author(s)
      Motoyuki Iijima, et al.
    • Journal Title

      Journal of Colloid and Interface Science Accepted(掲載決定)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deposition of TiO_2 nanoparticles in surfactant-containing aqueous suspension by a pulsed DC charging-mode electrophoresis2009

    • Author(s)
      M. Nazli Nairn, et al.
    • Journal Title

      Journal of the Ceramic Society of Japan 117(1)

      Pages: 127-132

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] コロイドプローブAFM法による炭素系粒子分散挙動の評価2011

    • Author(s)
      増田翔一, 他2名
    • Organizer
      化学工学会第76年会
    • Place of Presentation
      東京農工大学(中止)化学工学会第76年会要旨集(要旨観覧可能日)
    • Year and Date
      2011-03-24
    • Related Report
      2010 Annual Research Report
  • [Presentation] 湿式ビーズミル処理と表面修飾による高分散性カーボンブラック粒子の調製2011

    • Author(s)
      山崎美和, 他2名
    • Organizer
      化学工学会第76年会
    • Place of Presentation
      東京農工大学(中止)化学工学会第76年会要旨集(要旨観覧可能日)
    • Year and Date
      2011-03-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] Functionalized Polyethyleneimine for controlling the dispersibility of SiCaqueous suspensions2010

    • Author(s)
      野村洋介, 他2名
    • Organizer
      2010 AIChE Annual Meeting
    • Place of Presentation
      Salt Lake City(米国)
    • Year and Date
      2010-11-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Layer-by-1ayer surface modification of functional nanoparticles for non-aqueous dispersions2010

    • Author(s)
      飯島志行, 他1名
    • Organizer
      2010 AIChE Annual Meeting
    • Place of Presentation
      Salt Lake City(米国)
    • Year and Date
      2010-11-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Surface modification of functional nanoparticles using hydrophobic and hydrophilic modifiers for tuning their stability in organic solvents2010

    • Author(s)
      飯島志行, 他1名
    • Organizer
      10^<th> International Symposium on Advanced Organic Photonics and 1^<st> International Symposium on Surer Hybrid Materials
    • Place of Presentation
      Tohoku University 招待講演
    • Year and Date
      2010-10-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] 機能性ナノ粒子の有機溶媒分散のための交互吸着法による表面修飾2010

    • Author(s)
      飯島志行, 他1名
    • Organizer
      化学工学会第42回秋季大会
    • Place of Presentation
      同志社大学(京都府)
    • Year and Date
      2010-09-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] Surface Modification of Carbon and Silicon Carbide Nanoparticles for their Improvement of Dispersion Stability in Liquid Media2010

    • Author(s)
      飯島志行, 他3名
    • Organizer
      World Congress on Particle Technology 6
    • Place of Presentation
      Nuremberg(ドイツ)
    • Year and Date
      2010-04-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] Diels-Alder反応を用いた炭素系ナノ粒子の表面設計2009

    • Author(s)
      飯沼ちひろ、飯島志行、Wuled Lenggoro、神谷秀博
    • Organizer
      粉体工学会2009年度秋期研究発表会
    • Place of Presentation
      ホテルコスモスクエア国際交流センター(大阪府)
    • Year and Date
      2009-10-21
    • Related Report
      2010 Final Research Report
  • [Presentation] Diels-Alder反応を用いた炭素系ナノ粒子の表面設計2009

    • Author(s)
      飯沼ちひろ, 他3名
    • Organizer
      粉体工学会 2009年度秋期研究発表会
    • Place of Presentation
      ホテルコスモスクエア国際交流センター(大阪府)
    • Year and Date
      2009-10-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] 複合的表面処理によるTiO2ナノ粒子の有機溶媒・ポリマー中での分散安定化2009

    • Author(s)
      竹之内峻、飯島志行、神谷秀博
    • Organizer
      化学工学会第41回秋季大会
    • Place of Presentation
      広島大学東広島キャンパス(広島県)
    • Year and Date
      2009-09-16
    • Related Report
      2010 Final Research Report
  • [Presentation] 複合的表面処理によるTiO2ナノ粒子の有機溶媒・ポリマー中での分散安定化2009

    • Author(s)
      竹之内峻, 他2名
    • Organizer
      化学工学会第41回秋期大会
    • Place of Presentation
      広島大学 東広島キャンパス(広島県)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高分子分散剤構造によるSiCナノ粒子の水中分散挙動と表面間相互作用の制御2009

    • Author(s)
      野村洋輔, 他4名
    • Organizer
      日本セラミックス協会第22回秋期シンポジウム
    • Place of Presentation
      愛媛大学(愛媛県)
    • Year and Date
      2009-09-16
    • Related Report
      2009 Annual Research Report
  • [Presentation] 無機ナノ粒子分散ポリマー複合体合成のための粒子界面設計2009

    • Author(s)
      飯島志行, 他3名
    • Organizer
      粉体工学会 第45回夏期シンポジウム
    • Place of Presentation
      浜名湖ロイヤルホテル(静岡県)
    • Year and Date
      2009-08-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] 無機系ナノ粒子の物理的操作と界面設計による分散とPMMA複合体の合成2009

    • Author(s)
      神谷秀博, 他2名
    • Organizer
      粉体工学会 第45回夏期シンポジウム
    • Place of Presentation
      浜名湖ロイヤルホテル(静岡県)
    • Year and Date
      2009-08-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Transparent TiO_2/epoxy composites prepared by using a surfactant with hydrophobic and hydrophilic chains2009

    • Author(s)
      神谷秀博, 他2名
    • Organizer
      13^<th> IACIS International conference on surface science & colloid science/83^<rd> ACS colloid & surfaces science symposium
    • Place of Presentation
      Columbia University(アメリカ合衆国、ニューヨーク)
    • Year and Date
      2009-06-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 有機鎖に親水基と疎水基を有する界面活性剤で修飾した無機ナノ粒子の分散特性2009

    • Author(s)
      飯島志行, 他2名
    • Organizer
      粉体工学会2009年度春期研究発表会
    • Place of Presentation
      総評会館(東京都)
    • Year and Date
      2009-05-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] アニオン性界面活性剤の構造と有機溶媒中でのTiO_2ナノ粒子の分散挙動2009

    • Author(s)
      山崎美和, 他2名
    • Organizer
      化学工学会第74年会
    • Place of Presentation
      横浜国立大学
    • Year and Date
      2009-03-19
    • Related Report
      2008 Annual Research Report
  • [Presentation] 機能性ナノ粒子の有機溶媒、樹脂中への均一分散2008

    • Author(s)
      神谷秀博, 他2名
    • Organizer
      第46回粉体に関する討論会
    • Place of Presentation
      奈良県新公会堂
    • Year and Date
      2008-12-04
    • Related Report
      2008 Annual Research Report
  • [Presentation] アニオン性界面活性剤の構造設計とTiO_2ナノ粒子の有機溶媒への均一分散2008

    • Author(s)
      小早川昔離野, 他3名
    • Organizer
      化学工学会第40回秋季大会
    • Place of Presentation
      東北大学川内北キャンパス
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] BaTiO_3高分子複合体設計のための粒子表面改質2008

    • Author(s)
      飯島志行、佐藤信宏、Wuled Lenggoro、神谷秀博
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場(福岡県)
    • Year and Date
      2008-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] シランアルコキシドを用いたTiO_2ナノ粒子の表面修飾と有機溶媒への均一分散2008

    • Author(s)
      飯島志行, 他2名
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-17
    • Related Report
      2008 Annual Research Report
  • [Presentation] BaTiO_3高分子複合体設計のための粒子表面改質2008

    • Author(s)
      飯島志行, 他3名
    • Organizer
      日本セラミックス協会第21回秋季シンポジウム
    • Place of Presentation
      北九州国際会議場
    • Year and Date
      2008-09-17
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] ナノ粒子体及びその製造方法2009

    • Inventor(s)
      神谷秀博、飯島志行、小早川昔離野、太田泰裕
    • Industrial Property Rights Holder
      神谷秀博、飯島志行、小早川昔離野、太田泰裕
    • Patent Publication Number
      2010-159464
    • Filing Date
      2009-01-08
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] ナノ粒子体およびその製造方法2009

    • Inventor(s)
      神谷秀博, 飯島志行, 小早川昔離野, 太田泰裕
    • Industrial Property Rights Holder
      国立大学法人東京農工大学, 東邦化学工業株式会社
    • Industrial Property Number
      2009-002999
    • Filing Date
      2009-01-08
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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