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Nano-foaming Process Induced by Electromagnetic Wave

Research Project

Project/Area Number 20360348
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Properties in chemical engineering process/Transfer operation/Unit operation
Research InstitutionYokohama National University

Principal Investigator

KURUMADA Kenichi  Yokohama National University, 物質工学科, 教授 (80273473)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥17,290,000 (Direct Cost: ¥13,300,000、Indirect Cost: ¥3,990,000)
Fiscal Year 2010: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2009: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Fiscal Year 2008: ¥8,840,000 (Direct Cost: ¥6,800,000、Indirect Cost: ¥2,040,000)
Keywords流動・伝熱・物質移動操作 / 異相分離 / 粉粒体操作 / 薄膜・微粒子形成操作 / ナノ発泡 / 閉孔構造 / 孔径可変性 / 粉体物性 / 残留水酸基 / 高圧気体種 / in situ観察 / マトリクス剛性 / 体感判別 / ハンドリング動作 / 動力学 / 衝突時インパルス測定 / nanofoaming / instantaneous temperature elevation / rigidity of matrix / deformation stress / pressure difference / closed porosity / densitmetry / polycondensation
Research Abstract

Instantaneous application of heat in hard glassy matrices induced by electromagnetic wave or radiation can trigger the formation of nano-sized balloon structure. The starting hard matrix was prepared by the sol-gel method since that method is advantageous to render a quite slight amount of low-molecular-weight species remain in the hardened matrix. In this process, low-molecular-weight species forms gaseous species that displace the surrounding hard matrix in an isotropic geometry. As a result of that, isotropic spherical voids are ubiquitously yielded. The most marked feature of those structures is that they tend to remain as small as 100 nm at most, which indicates the suppression of the mutual coalescence of those balloon-like structures. An auxiliary work is ongoing to process those materials with the nano-sized spherical voids into fine powder. The features of the obtained powders are preliminarily investigated form those kinematical behavior.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (16 results)

All 2010 2009 2008 Other

All Journal Article (8 results) (of which Peer Reviewed: 8 results) Presentation (7 results) Remarks (1 results)

  • [Journal Article] Fabrication of microporous amorphous silica glass by pyrolysis of phenyl groups intercalated in sol-gel derived phenyl-modified silica glass2010

    • Author(s)
      Yoshihiro Kamimura, Kengo Miyoshi, Ken-ichi Kurumada
    • Journal Title

      Journal of Non-Crystalline Solids vol.356

      Pages: 1842-1847

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Fabrication of microporous amorphous silica glass by pyrolysis of phenyl groups intercalated in sol-gel derived phenyl-modified silica glass2010

    • Author(s)
      Yoshihiro Kamimura, Kengo Miyoshi, Ken-ichi Kurumada
    • Journal Title

      Journal of Non-Crystalline Solids

      Volume: 356 Pages: 1842-1847

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between Polarity of Template Hydrogel and Nanoporous Structure Replicated in Sol-Gel Derived Silica Matrix2009

    • Author(s)
      K.Kurumada, A.Suzuki, S.Baba, E.Otsuka
    • Journal Title

      Journal of Applied Polymer Science vol.114

      Pages: 4085-4090

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Entrapment of Organic Liquid Species in Molecular Scale in Sol-Gel Derived Silica Glass Matrix2009

    • Author(s)
      K.Kurumada, Y.Kamimura, S.Matsumoto
    • Journal Title

      Advanced Powder Technology vol.21

      Pages: 23-27

    • NAID

      10027276069

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Relationship between Polarity of Template Hydrogel and Nanoporous Structure Replicated in Sol-Gel Derived Silica Matrix2009

    • Author(s)
      K.Kurumada, A.Suzuki, S.Baba, E.Otsuka
    • Journal Title

      Journal of Applied Polymer Science 114

      Pages: 4085-4090

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Entrapment of Organic Liquid Species in Molecular Scale in Sol-Gel Derived Silica Glass Matrix2009

    • Author(s)
      K.Kurumada, Y.Kamimura, S.Matsumoto
    • Journal Title

      Advanced Powder Technology 21

      Pages: 23-27

    • NAID

      10027276069

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of Residual Swelling Solvent on Nanopore Formation in Replication of Swollen Hydrogel Network2009

    • Author(s)
      K. Kurumada, A. Suzuki, E. Otsuka, S. Baba, Y, Seto, K. Morita, T. Nakamura
    • Journal Title

      Progress in Colloid and Polymer Science 136(2009年9月刊行予定)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Formation of uniform hydroxyapatite nanocoating triggered by nucleation at carboχylic groups embedded in ethylene/acrylic acid copolymer microspheres2008

    • Author(s)
      Ken-ichi Kurumada, Kenzo Susa, Yuzuru Sugano, Mika Takahashi, Gaofeng Pan
    • Journal Title

      Colloids and Surfaces A : Physicochemical and Engineering Aspects 322

      Pages: 34-39

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Quest of Measurable Signals as Sources of Information for Perception of Particles, Powders and Liquids2010

    • Author(s)
      車田研一
    • Organizer
      40th APHS Seminar in Switzerland
    • Place of Presentation
      ETH Zurich, Switzerland
    • Year and Date
      2010-08-12
    • Related Report
      2010 Final Research Report
  • [Presentation] Quest of Measurable Signals as Sources of Information for Perception of Particles, Powders and Liquids2010

    • Author(s)
      Ken-ichi Kurumada
    • Organizer
      40th APHS Seminar in Switzerland
    • Place of Presentation
      スイス・チューリヒ・スイス連邦工科大学
    • Year and Date
      2010-08-12
    • Related Report
      2010 Annual Research Report
  • [Presentation] 講演1ヒューマン・インダストリアル・センシングへの挑戦~"測定"は本当に必要か?~2010

    • Author(s)
      車田研一
    • Organizer
      第18回化学工学会東北支部若手の会セミナー-化学工学に基づく材料設計とその応用-
    • Place of Presentation
      米沢
    • Year and Date
      2010-06-19
    • Related Report
      2010 Final Research Report
  • [Presentation] 汎用工業材の直感的判別の運動学的現象論2010

    • Author(s)
      車田研一・大谷悠貴
    • Organizer
      社団法人化学工学会第75年会
    • Place of Presentation
      鹿児島大学 (鹿児島市郡元)
    • Year and Date
      2010-03-19
    • Related Report
      2009 Annual Research Report
  • [Presentation] 粘弾性流体の衝突の瞬間の過渡的モルフォロジーと巨視的性質の相関2009

    • Author(s)
      車田研一
    • Organizer
      材料化学システム工学討論会2009(講演番号24)
    • Place of Presentation
      東京
    • Year and Date
      2009-12-06
    • Related Report
      2010 Final Research Report
  • [Presentation] シリカガラスマトリクス内でのナノ発泡現象の要因と発現する構造の特徴2009

    • Author(s)
      幡野純一,車田研一
    • Organizer
      材料化学システム工学討論会2009(講演番号P-2)
    • Place of Presentation
      東京
    • Year and Date
      2009-12-06
    • Related Report
      2010 Final Research Report
  • [Presentation] “Schreckliche Fahigkeit fur Verdauung (great “digestive" capacity)" of Glass2008

    • Author(s)
      K. Kurumada
    • Organizer
      Young Researchers Meeting “ From Single Particles to Functional Particulate Systems - Challenges and Solutions "
    • Place of Presentation
      Institute of Particle Technology, Die Eidgenossische Technlsche Hochschule Zarich, Switzerland
    • Year and Date
      2008-12-20
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ等

    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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