Preparation of High Performance Asymmetric Catalyst Using the Regularity of the Crystalline Inorganic Solid
| Project/Area Number |
20360362
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| Research Category |
Grant-in-Aid for Scientific Research (B)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Catalyst/Resource chemical process
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| Research Institution | Osaka University |
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Principal Investigator |
JITSUKAWA Koichiro Osaka University, 大学院・基礎工学研究科, 教授 (50235793)
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| Co-Investigator(Kenkyū-buntansha) |
MIZUGAKI Tomoo 大阪大学, 大学院・基礎工学研究科, 准教授 (50314406)
満留 敬人 (満留 尊人) 大阪大学, 基礎工学研究科, 助教 (00437360)
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| Co-Investigator(Renkei-kenkyūsha) |
MITSUDOME Takato 大阪大学, 大学院・基礎工学研究科, 助教 (00437360)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥18,980,000 (Direct Cost: ¥14,600,000、Indirect Cost: ¥4,380,000)
Fiscal Year 2010: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2009: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2008: ¥13,650,000 (Direct Cost: ¥10,500,000、Indirect Cost: ¥3,150,000)
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| Keywords | 触媒反応 / 反応場 / 固体触媒 / 不斉反応 / マクロリガンド / 触媒設計 / 有機触媒 / ハイドロタルサイト / アミノ酸 / 環境調和型反応 / ディールスアルダー反応 / モンモリロナイト / 固体化触媒 / 固定化触媒 |
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| Research Abstract |
Newly designed catalyst system was developed for preparation of a practical asymmetry synthesis. For preparation of the high performance asymmetric catalyst, asymmetric sphere formed on the surface of regularity inorganic solids is important. Two kinds of the system were examined based on the characteristic of crystalline solid. One was immobilization of the organic catalyst containing the optically active amines to montmorillonite through the ion exchange ability of the solid support. Another was the coordination of the surface atoms of the solid to the active center, in which the solid acted as a macroligand.
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Report
(4 results)
Research Products
(62 results)
