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DEVELOPMENT OF PRECISE SEPARATION METHOD OF RADIOACTIVE NUCLIDES BY HYBRID MICROCAPSULES

Research Project

Project/Area Number 20360417
Research Category

Grant-in-Aid for Scientific Research (B)

Allocation TypeSingle-year Grants
Section一般
Research Field Nuclear engineering
Research InstitutionTohoku University

Principal Investigator

MIMURA Hitoshi  東北大学, 大学院・工学研究科, 教授 (10091753)

Co-Investigator(Kenkyū-buntansha) WAKUI Yoshito  産業技術総合研究所, 東北センター, 主任研究員 (10358369)
HAYASHI Hiromichi  産業技術総合研究所, 東北センター, 主 任研究員 (20344228)
SATO Nobuaki  東北大学, 多元物質科学研究所, 准教授 (70154078)
KOYAMA Shinichi  日本原子力研究開発機構, 大洗研究開発 センター, 主任研究員 (70421782)
NIIBORI Yuichi  東北大学, 大学院・工学研究科, 教授 (90180562)
若林 利男  東北大学, 大学院・工学研究科, 教授 (10400277)
Project Period (FY) 2008 – 2012
Project Status Completed (Fiscal Year 2012)
Budget Amount *help
¥17,160,000 (Direct Cost: ¥13,200,000、Indirect Cost: ¥3,960,000)
Fiscal Year 2012: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Fiscal Year 2011: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
Fiscal Year 2010: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Fiscal Year 2009: ¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2008: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
Keywordsマイクロカプセル / アルギネート / 精密分離 / 発熱元素 / 白金族元素 / 加水分解 性核種 / アクチノイド核種 / クロマトグラフィ分離 / 核種分離 / イオン交換 / 溶媒抽出 / 模擬高レベル廃液 / 加水分分解性核種 / アクチノイド / モリブデン / アメリシウム / 分離・回収 / 分配係数 / 分離係数 / 加水分解性核種 / セシウム / ストロンチウム / 高レベル廃液 / テクネチウム / レニウム / オキソアニオン
Research Abstract

Nuclide separation properties by highly functional microcapsules were evaluated and compact precise separation process was developed. Microcapsules enclosing AMP, crown compound, insoluble ferrocyanides and extractants (MIDOA, TOA and LIX) were effective for the separation of Cs, Sr, Pd,Tc, Re, and Mo, respectively, and applicability to simulated and real wastes was confirmed.

Report

(7 results)
  • 2012 Annual Research Report   Final Research Report ( PDF )
  • 2011 Annual Research Report
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (34 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (18 results)

  • [Journal Article] Selective separation and recovery of cesium by ammonium tungstophosp hate-alginate microcapsules2011

    • Author(s)
      Hitoshi Mimura, Yan Wu, Wang Yufei, Yuichi Niibori, Isao Yamagishi, Masaki, Ozawa, Takashi Ohnishi, Shinichi Koyama
    • Journal Title

      Journal of Nuclear Engineering and Design

      Volume: 241 Pages: 4750-4757

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Adsorption Properties of Nuclear Rare Metals for Hybrid Microcapsules Enclosing MIDOA Extractant2010

    • Author(s)
      Toshiaki Sugimori, Yan Wu, Hitoshi Mimura, Yuichi Niibori, Yuji Sasaki
    • Journal Title

      Proc. of International Conference of Ion Exchange2010

      Volume: 1PA10

    • Related Report
      2012 Final Research Report
    • Peer Reviewed
  • [Journal Article] Selective Uptake of Palladium from High-Level Liquid Wastes by Hybrid Microcapsules Enclosed with Insoluble Ferrocyanides2010

    • Author(s)
      Hitoshi Mimura, Takashi Sakakibara, Wu Yan, Yuichi Niibori, Shin-ichi Koyama, Takashi Ohnishi
    • Journal Title

      Proceedings of the 13^<th> International Conference on Environmental Remediation & Radioactive Waste Management ICEM2010

      Volume: ICEM2010-40103

    • Related Report
      2012 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Selective separation and recovery of Mo (VI) by hybrid microcapsules containing organic extractants2010

    • Author(s)
      Kaoru Ikeda, Yan Wu, Hitoshi Mimura, Yuichi Niibori, Yoshito Wakui, Masahiko Osaka, Shinichi Koyama, Takashi Ohnishi
    • Journal Title

      Proceedings of HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management 2010 Phoenix, USA

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Adsorption Properties of Nuclear Rare Metals for Hybrid Microcapsules Enclosing MIDOA Extractant2010

    • Author(s)
      Toshiaki Sugimori, Yan Wu, Hitoshi Mimura, Yuichi Niibori, Yuji Sasaki
    • Journal Title

      Proc of International Conference of Ion Exchange 2010

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] I Adsorption Properties of Technetium and Rhenium for Hybrid Microcapsules Enclosing TOA Extractant2010

    • Author(s)
      Hitoshi Mimura, Yan Wu, Yuichi Niibori, Shinichi Koyama, Takashi Ohnishi
    • Journal Title

      Proc.of 17^<th> Pacific Basin Nuclear Conference

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 原子力バックエンドにおけるイオン交換法を主体とした核種の高度分離・回収法の開発2010

    • Author(s)
      三村均
    • Journal Title

      日本イオン交換学会誌 21

      Pages: 2-19

    • NAID

      130000428209

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 「イオン交換と再処理・放射性廃棄物処理」第五回2009

    • Author(s)
      三村均, 山岸功
    • Journal Title

      イオン交換法によるアクチノイドの選択的分離・回収(日本イオン交換学会誌依頼論文) Vol.20

      Pages: 86-97

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Selective Separation of Heat-Generation Nuclide by Silica gels Loading with Ammonium Molybdophosphate-Adv.-ORIENT Cycle Development2009

    • Author(s)
      Yusuke Endo, Yan Wu, Hitoshi Mimura, Yuichi Niibori, Shin-ichi Koyama, Takashi Ohnishi, Hiroshi Obayashi, IsaoYamagishi, Masaki Ozawa
    • Journal Title

      Proceedings of GlOBAL2009, Paris, France

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Adv.-ORIENT Cycle, Its Scientific Progress and the Engineering Feasibility2009

    • Author(s)
      Masaki Ozawa, Tatsuya Suzuki, Shin-ichi Koyama, Isao Yamagishi, Reiko Fujita, Ken Okada, Yoshihiko Tatenuma, Hitoshi Mimura, Yasuhiko Fujii
    • Journal Title

      Proceedings of GlOBAL2009, Paris, France

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] イオン交換法によるオキソ酸イオンの選択的分離・回収2009

    • Author(s)
      三村均, 山岸功
    • Journal Title

      日本イオン交換学会誌 20

      Pages: 23-36

    • NAID

      130003375913

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] イオン交換法によるアクチノイドの選択的分離・回収2009

    • Author(s)
      三村均, 山岸功
    • Journal Title

      日本イオン交換学会誌 20

      Pages: 24-34

    • NAID

      130003375916

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] イオン交換法によるオキソ酸イオンの選択的分離・回収2009

    • Author(s)
      三村均
    • Journal Title

      日本イオン交換学会誌 20

      Pages: 23-36

    • NAID

      130003375913

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] 発熱元素の選択的分離・回収と有効利用2008

    • Author(s)
      三村均
    • Journal Title

      日本イオン交換学会誌 19

      Pages: 127-140

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] イオン交換法による白金族元素の選択的分離・回収2008

    • Author(s)
      三村均
    • Journal Title

      日本イオン交換学会誌 19

      Pages: 179-195

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A new back-end cycle strategy for enhancing separation, transmutation and utilization of materials (Adv.-ORIENT cycle)2008

    • Author(s)
      M. Ozawa
    • Journal Title

      Progress in Nuclear Energy 50

      Pages: 476-482

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Development of Selective Separation Method of Nuclear Rare Metals by Highly Functional Xerogels2012

    • Author(s)
      Hitoshi Mimura, Takuya Kawamura, Rana Syed Masud, Yuichi Niibori, Takashi Ohnishi, Hiroshi Ohbayashi, Shin-ichi Koyama, Hiroshi Sugai
    • Organizer
      New Energy Forum-2012
    • Place of Presentation
      広州、中国
    • Year and Date
      2012-10-19
    • Related Report
      2012 Final Research Report
  • [Presentation] Uptake and recovery of cesium, palladium, rhenium and molybdenum from simulated spent fuel solution by hybrid microcapsules2011

    • Author(s)
      Takashi, Ohnishi, Shin-ichi Koyama, Hitoshi Mimura
    • Organizer
      3^<rd> International Symposium on Application of Chemical and Analytical Technologies in Nuclear Industries (Nu-ACT 2011)
    • Place of Presentation
      Republic of Korea, Daejeon
    • Year and Date
      2011-09-30
    • Related Report
      2011 Annual Research Report
  • [Presentation] 先進オリエントサイクル研究(Phase1)3)レアメタルの分離II(Cs,Sr)2010

    • Author(s)
      三村均、山岸功、小澤正基
    • Organizer
      日本原子力学会2010秋の大会
    • Place of Presentation
      北海道大学、札幌
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Selective separation and recovery of Mo(VI) by hybrid microcapsules containing organic extractants2010

    • Author(s)
      Kaoru Ikeda, Yan Wu, Hitoshi Mimura, Yuichi Niibori, Yoshito Wakui, Masahiko Osaka, Shinichi Koyama, Takashi
    • Organizer
      WM2010 Conference
    • Place of Presentation
      Phoenix, USA
    • Year and Date
      2010-03-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] ハイブリッドマイクロカプセルによるPd(II)の選択的吸着2010

    • Author(s)
      葛巻武範, Rebecca Maksymowich, 三村均, 新堀雄一
    • Organizer
      日本原子力学会2010年春の年会
    • Place of Presentation
      茨城大学
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Selective Uptake of Palladium by Hybrid Microcapsule2010

    • Author(s)
      Takenori Kuzumaki, Rebecca Maksymowich, Hitoshi Mimura, Yuichi Niibori
    • Organizer
      HLW, TRU, LLW/ILW, Mixed, Hazardous Wastes & Environmental Management 2010
    • Place of Presentation
      Phoenix, USA
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] 原子力バックエンドにおけるイオン交換法を主体とした核種の高度分離・回収法の開発2009

    • Author(s)
      三村均
    • Organizer
      第25回日本イオン交換研究発表会
    • Place of Presentation
      秋田大学(日本イオン交換学会学会賞受賞講演)
    • Year and Date
      2009-10-10
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] 原子力バックエンドにおけるイオン交換法を主体とした核種の高度分離・回収法の開発2009

    • Author(s)
      三村均
    • Organizer
      第25回日本イオン交換研究発表会
    • Place of Presentation
      秋田市
    • Year and Date
      2009-10-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] 抽出剤内包マイクロカプセルを用いたオキソ酸イオンのコンパクト分離手法の開発2009

    • Author(s)
      森俊昭, 呉艶, 三村均, 新堀雄一, 佐々木裕二
    • Organizer
      第25回日本イオン交換研究発表会
    • Place of Presentation
      秋田大学
    • Year and Date
      2009-10-09
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Preparation of Ferrocyanide Molybdate and Their Selective Uptake Properties for Palladium and Cesium Ions2008

    • Author(s)
      Yusuke ENDO
    • Organizer
      16^<th> Pacific Basin Nuclear Conference (16 PBNC)
    • Place of Presentation
      青森市
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] Uptake of Strontium (II) in Concentrated Nitric Acid by Microcapsules Enclosed with Decyl-18-Crown-62008

    • Author(s)
      Hitoshi MIMURA
    • Organizer
      16^<th> Pacific Basin Nuclear Conference (16 PBNC)
    • Place of Presentation
      青森市
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] Selective Uptake of Re (VII) by Amine Microcapsules2008

    • Author(s)
      Yan WU
    • Organizer
      16^<th> Pacific Basin Nuclear Conference (16 PBNC)
    • Place of Presentation
      青森市
    • Year and Date
      2008-10-13
    • Related Report
      2008 Annual Research Report
  • [Presentation] Multi-functional reprocessing system toward future nuclear cycle2008

    • Author(s)
      M. Ozawa
    • Organizer
      Tenth information meeting, OECD / NEA
    • Place of Presentation
      水戸市
    • Year and Date
      2008-10-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Selective separation of nuclides by hybrid Microcapsules (1) Separation of heat-generating nuclides (Cs, Sr)2008

    • Author(s)
      Y. Endo
    • Organizer
      Tenth information meeting, OECD / NEA
    • Place of Presentation
      水戸市
    • Year and Date
      2008-10-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Selective separation of nuclides by hybrid Microcapsules (2) Separation of rare metals (Re, Mo)2008

    • Author(s)
      Wu Yan
    • Organizer
      Tenth information meeting, OECD / NEA
    • Place of Presentation
      水戸市
    • Year and Date
      2008-10-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] ハイブリッドマイクロカプセルによる有用核種の選択的分離・回収2008

    • Author(s)
      三村均
    • Organizer
      第58回錯体化学討論会シンポジウム、依頼講演
    • Place of Presentation
      金沢
    • Year and Date
      2008-09-20
    • Related Report
      2012 Final Research Report
  • [Presentation] ハイブリッドマイクロカプセルによる有用核種の選択的分離・回収2008

    • Author(s)
      三村均
    • Organizer
      第58回錯体化学討論会シンポジウム, 依頼講演
    • Place of Presentation
      金沢市
    • Year and Date
      2008-09-20
    • Related Report
      2008 Annual Research Report
  • [Presentation] Development of Selective Separation Method of Nuclear Rare Metals by Highly Functional Xerogels

    • Author(s)
      Hitoshi Mimura, Takuya Kawamura, Rana Syed Masud, Yuichi Niibori,Takashi Ohnishi, Hiroshi Ohbayashi, Shin-ichi Koyama, Hiroshi Sugai
    • Organizer
      New Energy Forum-2012
    • Place of Presentation
      広州(中国)
    • Related Report
      2012 Annual Research Report

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Published: 2008-04-01   Modified: 2019-07-29  

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