Organo-chemical Functionalization of Nano-size Cluster Metal Complexes with Redox-active Ligands
| Project/Area Number |
20510093
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Nanostructural science
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| Research Institution | Saitama University |
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Principal Investigator |
FUJIHARA Takashi Saitama University, 科学分析支援センター, 准教授 (70280914)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
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| Keywords | 構造・機能材料 / ナノ材料 / 錯体化学 / 有機化学 / ナノクラスター |
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| Research Abstract |
The nano-size metal cluster complexes which combined zwitterionic ligands with various kinds of metal ions were newly synthesized. The structure analyses for obtained complexes were carried out. The organo-chemical functionalization for obtained metal cluster complexes were carried out. The obtained functionalized materials were examined the structures, the electrochemical properties, and some spectral properties in solid state and in the solution.
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Report
(4 results)
Research Products
(58 results)
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[Presentation] The First Observation of a Spin-Crossover Phenomenon as a FeII-S6 Type Complexes with a Zwitterionic Ligands, Bis(N,N'-diethylarnino)-carbeniumdithiocarboxylate2010
Author(s)
Sugaya, Tomoaki・Naka, Takashi・Furubayashi, Takao・Isago, Hiroaki・Matsushita, Akiyuki・Fujihara, Takashi・Nagasawa, Akira
Organizer
60th Anniversary Conference on Coordination Chemistry inOsaka, Japan
Place of Presentation
大阪国際交流センター
Year and Date
2010-09-27
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