Relationship between nano-/micro-scale structure changes at crystal surfaces and bulk physical properties

• Project/Area Number: 20510097
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Nanostructural science
• Research Institution: Chuo University
• Principal Investigator: SHINDO Hitoshi 中央大学, 理工学部, 教授 (90245986)
• Co-Investigator(Kenkyū-buntansha): NAKAMURA Kazumasa 中央大学, 理工学部, 助教 (90433870) ; NIKI Kaori 中央大学, 理工学部, 助教 (10548100)
• Project Period (FY): 2008 – 2011
• Project Status: Completed (Fiscal Year 2011)
• Budget Amount: ¥4,160,000 (Direct Cost: ¥3,200,000、Indirect Cost: ¥960,000); Fiscal Year 2011: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000); Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
• Keywords: 結晶工学 / 結晶成長 / 走査プローブ顕微鏡 / トライボロジー / 表面界面物性 / 結晶力学 / 摩擦・摩耗 / 塑性変形 / 滑り / 結晶のモルフォロジー / カルサイト / マグネサイト / 原子間力顕微鏡 / 摩擦・磨耗 / 硫酸塩結晶 / アラゴナイト型結晶 / 塩化ナトリウム / 炭酸鉛 / 方解石 / ガラス状炭素 / 固結現象 / イオン注入

Research Abstract

Effects of atomic/molecular arrangements and charge distributions at crystal surfaces upon frictional properties and crystal morphologies observed in larger scales were clarified. In contrast with nm-scale friction where intuitive interpretation holds, frictional properties in larger scales are different. Above threshold values in mechanical stresses, plastic deformations including slip and cleavage change anisotropies and asymmetries in friction.

Research Products

• [Journal Article] Participation of{100}<011> slip system in sliding friction at(001),(111) and(110) surfaces of fluorite(CaF2) crystal (2012)
  • Author(s): Kaori Niki, Gaku Mochimaru, Hitoshi Shindo
  • Journal Title: Tribology Online Volume: Vol.7, No.2 Pages: 81-86
  • NAID: 130002099848
  • Peer Reviewed
• [Journal Article] Frictional asymmetry and wear pattern formation by slip and cleavage detected at directional r{10-14} face of calcite (2012)
  • Author(s): Kaori Niki, Mai Kobayashi, Hitoshi Shindo
  • Journal Title: Tribology Online Volume: Vol.7, No.1 Pages: 8-12
  • Peer Reviewed
• [Journal Article] Frictional asymmetry and wear pattern formation by slip and cleavage detected at directional r{10-14} face of calcite (CaCO3) (2012)
  • Author(s): Kaori Niki, Mai Kobayashi, Hitoshi Shindo
  • Journal Title: Tribology Online Volume: 7巻 Pages: 8-12
  • NAID: 130002099811
  • Peer Reviewed
• [Journal Article] テンプレート法によるポリメチルメタクリレート(PMMA)ハニカムフィルム形成過程の顕微鏡観察 (2012)
  • Author(s): 二木かおり、佐々木裕、星野修平、村田知栄子、堀杏朱、新藤斎
  • Journal Title: 高分子論文集 Volume: 69巻(掲載決定)(印刷中)
  • NAID: 10030772851
  • Peer Reviewed
• [Journal Article] Participation of {100}<011> slip system in sliding friction at (001), (111) and (110) surfaces of fluorite (CaF2) crystal (2012)
  • Author(s): Kaori Niki, Gaku Mochimaru, Hitoshi Shindo
  • Journal Title: Tribology Online Volume: 7巻(掲載決定)(印刷中)
  • NAID: 130002099848
  • Peer Reviewed
• [Journal Article] Contribution of slip and cleavage in friction and wear at(10-14) surface of magnesite(MgCO3) crystal (2011)
  • Author(s): Kaori Niki, Mai Kobayashi, Hitoshi Shindo
  • Journal Title: Tribology Online Volume: Vol.6, No.7 Pages: 317-322
  • NAID: 130002099737
  • Peer Reviewed
• [Journal Article] Stability of crystal faces of aragonite-type strontianite(SrCO3) and cerussite(PbCO3) compared by AFM observation of facet formation in acid (2011)
  • Author(s): Yusuke Shirota, Kaori Niki, Hitoshi Shindo
  • Journal Title: Journal of Crystal Growth Volume: Vol.324, No.1 Pages: 190-195
  • Peer Reviewed
• [Journal Article] Contribution of Slip and Cleavage in Friction and Wear at (1 0 -1 4) Surface of Magnesite (MgCO₃) Crystal (2011)
  • Author(s): Kaori Niki, Mai Kobayashi, Hitoshi Shindo
  • Journal Title: Tribology Online Volume: 6 Issue: 7 Pages: 317-322
  • DOI: 10.2474/trol.6.317
  • NAID: 130002099737
  • ISSN: 1881-218X, 1881-2198
  • Peer Reviewed
• [Journal Article] Surface oxidation and/or corrosion behavior of glass-like carbon in sulfuric and nitric acids, and in aqueous hydrogen peroxide (2011)
  • Author(s): K.Nakamura, H.Morooka, Y.Tanabe, E.Yasuda, T.Akatsu, H.Shindo
  • Journal Title: Corrosion Science Volume: 53巻 Issue: 12 Pages: 4010-4013
  • DOI: 10.1016/j.corsci.2011.08.004
  • Peer Reviewed
• [Journal Article] Stability of crystal faces of aragonite-type strontianite(SrCO3) and cerussite(PbCO3) compared by AFM observation of facet formation in acid. (2011)
  • Author(s): Y.Shirota, K.Niki, H.Shindo
  • Journal Title: J.Cryst.Growth 印刷中
  • Peer Reviewed
• [Journal Article] Stabilities of crystal faces of anhydrite(CaSO4) compared by AFM observation of facet formation processes in aqueous solutions (2010)
  • Author(s): Hitoshi Shindo, 他5名
  • Journal Title: Journal of Crystal Growth Volume: Vol.312 Pages: 573-579
  • Peer Reviewed
• [Journal Article] Stabilities of crystal faces of anhydrite(CaSO4) compared by AFM observation of facet formation processes in aqueous solutions (2010)
  • Author(s): H.Shindo, T Igarashi, W.Karino, M.Yamanobe-Hada , M.Haga
  • Journal Title: J.Cryst.Growth 312 Pages: 573-579
  • Peer Reviewed
• [Journal Article] Stabilities of crystal faces of anhydrite(CaSO4)compared by AFM observation of facet formation processes in aqueous solutions (2010)
  • Author(s): H.Shindo, T.Igarashi, W.Karino, A.Seo, M.Yamanobe-Hada, M.Haga
  • Journal Title: Journal of Crystal Growth 312 Pages: 573-579
  • Peer Reviewed
• [Journal Article] NaCl結晶間架橋のメカニズムと固結防止剤の作用 (2009)
  • Author(s): 新藤斎, 他4名
  • Journal Title: 日本海水学会誌 Volume: 63巻, 3号 Pages: 183-189
  • NAID: 10024977043
  • Peer Reviewed
• [Journal Article] エタノール溶液中での様々なNaCl結晶表面の原子平坦化のメカニズムおよび3つの低指数面での摩擦測定 (2009)
  • Author(s): 新藤斎、狩野弥、甲田啓
  • Journal Title: 日本海水学会誌 63 Pages: 316-322
  • Peer Reviewed
• [Journal Article] NaCl結晶間架橋のメカニズムと固結防止剤の作用 (2009)
  • Author(s): 峯尾隼人、斎藤結子、大野文子、中村和正、新藤斎
  • Journal Title: 日本海水学会誌 63 Pages: 183-189
  • NAID: 10024977043
  • Peer Reviewed
• [Journal Article] Surface modification behaviors of glass-like carbon by oxygen ion implantation (2009)
  • Author(s): 中村和正, Y.Teranishi, Y.Wada, K.Tano, I.Nakamura, Y.Tanabe, E.Yasuda, T.Akatsu, H.Shindo
  • Journal Title: Nucl.Instr.Methods B 267 Pages: 1642-1644
  • Peer Reviewed
• [Journal Article] エタノール溶液中での様々なNaCl結晶面の原子平坦化のメカニズムおよび3つの低指数面での摩擦測定 (2009)
  • Author(s): 新藤斎・狩野弥・甲田啓
  • Journal Title: 日本海水学会誌 63 Pages: 316-322
  • Peer Reviewed
• [Journal Article] 原子間力顕微鏡による微小サイズでの形状計測と物性評価 (2009)
  • Author(s): 新藤斎
  • Journal Title: 化学と教育 57 Pages: 528-531
  • Peer Reviewed
• [Journal Article] Sueface modification behaviors of glass-like carbon by Oxygen ion implantation (2009)
  • Author(s): K. Nakamura, Y. Teranishi, Y. Wada, K. Tano, I. Naka-mura, Y. Tanabe, E. Yasuda, H. Shindo
  • Journal Title: Nuclear Instruments and Methods B (印刷中)
  • Peer Reviewed
• [Journal Article] NaCl結晶間架橋のメカニズムと固結防止剤の作用 (2009)
  • Author(s): 峯尾隼人, 斎藤結子, 大野文子, 中村和正, 新藤 斎
  • Journal Title: 日本海水学会誌 63(印刷中)
  • NAID: 10024977043
  • Peer Reviewed
• [Presentation] AFM観察によるカルサイト(CaCO3)結晶表面の安定性の比較 (2012)
  • Author(s): 大津陽平、山村亮平、二木かおり、新藤斎
  • Organizer: 日本化学会第92春季年会
  • Place of Presentation: 慶応大学日吉・矢上キャンパス
  • Year and Date: 2012-03-26
• [Presentation] イオン結晶表面におけるマイクロスケールの摩擦・磨耗機構の解明 (2012)
  • Author(s): 二木かおり、小林真依、新藤斎
  • Organizer: 日本物理学会第67回年次大会
  • Place of Presentation: 関西学院大学西宮上ヶ原キャンパス
  • Year and Date: 2012-03-24
• [Presentation] Participation of {100}<011> slip system in sliding friction at (001), (111) And (110) surfaces of fluorite (CaF2) crystal (2011)
  • Author(s): Kaori Niki, Gaku Mochimaru, Hitoshi Shindo
  • Organizer: International Tribology Conference, Hiroshima 2011
  • Place of Presentation: 広島国際会議場
  • Year and Date: 2011-11-02
• [Presentation] Contribution of(0001) slip and{10-14} cleavage in friction and wear at(10-14) surfaces of calcite(CaCO3) and magnesite(MgCO3) crystals (2011)
  • Author(s): Kaori Niki, Mai Kobayashi, Hitoshi Shindo
  • Organizer: International Tribology Conference, 2011
  • Place of Presentation: Hiroshima
  • Year and Date: 2011-10-31
• [Presentation] Contribution of (0001) slip and {10-14} cleavage in friction and wear at (10-14) surfaces of calcite (CaCO3) and magnesite (MgCO3) crystals (2011)
  • Author(s): Kaori Niki, Mai Kobayashi, Hitoshi Shindo
  • Organizer: International Tribology Conference, Hiroshima 2011
  • Place of Presentation: 広島国際会議場
  • Year and Date: 2011-10-31
• [Presentation] イオン結晶表面におけるマイクロスケールの摩擦機構 (2011)
  • Author(s): 二木かおり、小林真依、新藤斎
  • Organizer: 日本物理学会2011年秋季大会
  • Place of Presentation: 富山大学五福キャンパス
  • Year and Date: 2011-09-22
• [Presentation] Conjecturing chemical environment of crystal growth by AFM observation of polyhedral micro-etch pits during dissolution (2011)
  • Author(s): Hitoshi Shindo, Toshinori Igarashi, Yusuke Shirota, Ryohei Yamamura, Kaori Niki
  • Organizer: Japan Geoscience Union Meeting 2011
  • Place of Presentation: Makuhari
  • Year and Date: 2011-05-23
• [Presentation] キラルなNaClO3,NaBrO3結晶の表面構造および不斉自己触媒反応に関わるピリミジン誘導体の吸着構造のAFM観察 (2011)
  • Author(s): 竹下毅、二木かおり、新藤斎
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学(神奈川県)
  • Year and Date: 2011-03-28
• [Presentation] AFMによる酸性エタノール水溶液中での方解石(CaCO3)結晶表面の安定性の比較 (2011)
  • Author(s): 山村亮平、二木かおり、新藤斎
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学(神奈川県)
  • Year and Date: 2011-03-28
• [Presentation] 蛍石(CaF2)結晶の滑り系の研究 (2010)
  • Author(s): 持丸岳、二木かおり、新藤斎
  • Organizer: 第54回日本学術会議材料工学連合講演会
  • Place of Presentation: 京都
  • Year and Date: 2010-10-25
• [Presentation] 蛍石(CaF2)結晶の滑り系の研究 (2010)
  • Author(s): 持丸岳、二木かおり、新藤斎
  • Organizer: 第54回日本学術会議材料工学連合講演会
  • Place of Presentation: ハートピア京都(京都)
  • Year and Date: 2010-10-25
• [Presentation] イオン結晶表面におけるマクロスケールの摩擦機構の研究 (2010)
  • Author(s): 二木かおり、新藤斎
  • Organizer: 日本物理学会平成22年度秋季大会
  • Place of Presentation: 大阪
  • Year and Date: 2010-09-24
• [Presentation] イオン結晶表面におけるマクロスケールの摩擦機構の研究 (2010)
  • Author(s): 二木かおり、新藤斎
  • Organizer: 日本物理学会2010年秋季大会
  • Place of Presentation: 大阪府立大学(大阪府)
  • Year and Date: 2010-09-24
• [Presentation] Stability of crystal faces of aragonite-type carbonate minerals, strontianite(SrCO3) and cerussite(PbCO3), compared by AFM observation of facet formation processes during dissolution in dilute aqueous acetic acid (2010)
  • Author(s): Yusuke Shirota, Kaori Niki, Hitoshi Shindo
  • Organizer: The 16^<th> International Conference on Crystal Growth, 2010
  • Place of Presentation: Beijing
  • Year and Date: 2010-08-09
• [Presentation] Stabilities of crystal faces of aragonite-type carbonate minerals, strontianite (SrCO3) and cerussite (PbCO3), compared by AFM observation of facet formation processes during dissolution in dilute aqueous acetic acid (2010)
  • Author(s): Y.Shirota, K.Niki, H.Shindo
  • Organizer: The 16th Intl.Conf.on Crystal Growth
  • Place of Presentation: 北京
  • Year and Date: 2010-08-09
• [Presentation] Stabilities of crystal faces of aragonite-type carbonate minerals, Strontianite(SrCO3) and cerussite(PbCO3), compared by AFM Observation of facet formation processes during dissolution in dilute Aqueous acetic acid (2010)
  • Author(s): Yusuke Shirota, Kaori Niki, Hitoshi Shindo
  • Organizer: The 16th International Conference on Crystal Growth/The 14th International Conference on Vapor Growth and Epitaxy
  • Place of Presentation: Beijing International Conference Center(北京)
  • Year and Date: 2010-08-09
• [Presentation] Conjecturing chemical environment of crystal growth by AFM observation of polyhedral micro-etch pits during dissolution (2010)
  • Author(s): H.Shindo, T.Igarashi, Y.Shirota, R.Yamamura, K.Niki
  • Organizer: Japan Geoscience Union Meeting 2010
  • Place of Presentation: 浦安(招待講演)
  • Year and Date: 2010-05-23
• [Presentation] Conjecturing chemical environment of crystal growth by AFM observation of polyhedral micro-etch pits during dissolution (2010)
  • Author(s): Hitoshi Shindo, Toshinori Igarashi, Yusuke Shirota, Ryohei Yamamura, Kaori Niki
  • Organizer: Japan Geoscience Union Meeting 2010
  • Place of Presentation: 幕張メッセ(千葉県)(招待講演)
  • Year and Date: 2010-05-23
• [Presentation] キラルなRgS(10-10)表面へのピリミジン誘導体の吸着のAFM観察 (2010)
  • Author(s): 城田雄亮, 二木かおり, 新藤斎, 川崎常臣, 〓合憲三
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪近畿大学
  • Year and Date: 2010-03-27
• [Presentation] AFMによる酢酸-エタノール水溶液中での方解石(CaCO3)結晶表面の安定性の比較 (2010)
  • Author(s): 山村亮平, 二木かおり, 新藤斎
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 大阪近畿大学
  • Year and Date: 2010-03-26
• [Presentation] イオン結晶表面におけるナノ・マクロスケールの摩擦機構の解明 (2010)
  • Author(s): 二木かおり、新藤斎
  • Organizer: 日本物理学会第65回年次大会
  • Place of Presentation: 岡山
  • Year and Date: 2010-03-21
• [Presentation] イオン結晶表面におけるナノ・マクロスケールの摩擦機構の解明 (2010)
  • Author(s): 二木かおり, 新藤斎
  • Organizer: 日本物理学会第65回年次大会
  • Place of Presentation: 岡山 岡山大学
  • Year and Date: 2010-03-21
• [Presentation] 硫酸・硝酸・過酸化水素水によるガラス状炭素の湿式酸化・腐食挙動 (2010)
  • Author(s): 中村和正, 師岡弘樹, 新藤斎, 田邊靖博, 赤津隆, 安田榮一
  • Organizer: 日本セラミックス協会2010年会
  • Place of Presentation: 東京 東京農工大学小金井
• [Presentation] 食塩結晶の固結メカニズムと固結防止剤の作用 (2009)
  • Author(s): 峯尾隼人, 斎藤結子, 大野文子, 中村和正, 新藤斎
  • Organizer: 日本海水学会第60年会技術発表会
  • Place of Presentation: 東京 東京大学山上会館
  • Year and Date: 2009-06-04
• [Presentation] アラゴナイト型炭酸塩結晶表面の安定性の比較 (2008)
  • Author(s): 城田雄亮, 中村和正, 新藤斎
  • Organizer: 第38回結晶成長国内会議
  • Place of Presentation: 仙台
  • Year and Date: 2008-11-06
• [Presentation] Surface modification behavior of glass-like carbon by oxygen implantation (2008)
  • Author(s): K. Nakamura, Y. Teranishi, I. Nakamura, H. Shindo
  • Organizer: 16th International Conference on Ion Beam Modification of Materials, 2008
  • Place of Presentation: Dresden
  • Year and Date: 2008-09-01
• [Presentation] Sueface modification behavior of glass-like carbon by Oxygen implantation (2008)
  • Author(s): K. Nakamura, Y. Teranishi, I. Nakamura, H. Shindo
  • Organizer: 16th International Conference on Ion Beam Modification of Materials
  • Place of Presentation: Dresden, Germany
  • Year and Date: 2008-09-01
• [Presentation] 食塩結晶粒子の固結のメカニズム (2008)
  • Author(s): 峯尾隼人, 斎藤結子, 中村和正, 新藤 斎
  • Organizer: 日本海水学会第59年会研究技術発表会
  • Place of Presentation: 長崎
  • Year and Date: 2008-06-06
• [Presentation] Surface oxidation and/or corrosion behavior of glass-Like carbon in sulfuric and nitric acids, and in Aqueous hydrogen peroxide (2008)
  • Author(s): K. Nakamura, H. Morooka, Y. Teranishi, Y. Tanabe, E. Yasuda, H. Shindo
  • Organizer: Joint Conference of The 2nd Inter-national Conference on the Science and Technology for Advanced Ceramics and The lst International Conference on Science and Technology of Solid Sur-faces and Interface
  • Place of Presentation: 千葉
  • Year and Date: 2008-05-31
• [Remarks]