• Search Research Projects
  • Search Researchers
  • How to Use
  1. Back to previous page

Development of depth profile analysis of nano materials using X-ray energy variable XPS

Research Project

Project/Area Number 20510110
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Nanomaterials/Nanobioscience
Research InstitutionNational Institute for Materials Science

Principal Investigator

YOSHIKAWA Hideki  National Institute for Materials Science, ナノ計測センター, 主幹研究員 (20354409)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
KeywordsXPS / 放射光 / エネルギー可変 / 断層解析 / DDF / 非対称パラメーター / EDF
Research Abstract

Hard X-ray photoemission spectroscopy (HX-XPS) has been developed for the analysis of nano materials using energy-variable hard X-ray at synchrotron radiation facilities. The depth profile analysis by HX-XPS is promising as a quantitative nondestructive depth profile technique. For the further development of this technique, the asymmetry parameter, the emission depth distribution function (EDDF) and energy loss function which govern the HX-XPS spectra should be evaluated quantitatively. This work developed the precise algorism which evaluates these quantities by the combination of the angle-resolved&energy-resolved HX-XPS measurements, Monte Carlo simulation and REELS analysis. As an example, HX-XPS analysis of nano particles, which has core-shell structure (core : Ag, shell: polydiacetylene), has been carried out successfully.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (23 results)

All 2010 2009

All Journal Article (11 results) (of which Peer Reviewed: 11 results) Presentation (12 results)

  • [Journal Article] Characterization of Surface Structure Evolution in Ni_3Al Foil Catalysts by Hard X-ray Photoelectron Spectroscopy2010

    • Author(s)
      Y.Xu, H.Yoshikawa, J.H.Jang,M.Demura, K.Kobayashi, S.Ueda, Y.Yamashita, D.M.Wee, T.Hirano
    • Journal Title

      J.Phys.Chem.C Vol.114

      Pages: 6047-6053

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Energy loss function for Si determined from reflection electron energy loss spectra with factor analysis method2010

    • Author(s)
      H.Jin, H.Yoshikawa, S.Tanuma, S.Tougaard
    • Journal Title

      Surf.Interf.Anal. Vol.42

      Pages: 1076-1081

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of optical constants of Si and SiO_2 from reflection electron energy loss spectra using factor analysis method2010

    • Author(s)
      H.Jin, H.Shinotsuka, H.Yoshikawa, H.Iwai, S.Tanuma, S.Tougaard
    • Journal Title

      Journal of Applied Physics Vol.107

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Energy loss function for Si determined from reflection electron energyloss spectra with factor analysis method2010

    • Author(s)
      Hua Jin, Hideki Yoshikawa, Shigeo Tanuma, Sven Tougaard
    • Journal Title

      Surf.Interf.Anal.

      Volume: 42 Pages: 1076-1081

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Characterization of Surface Structure Evolution in Ni_3Al Foil Catalysts by Hard X-ray Photoelectron Spectroscopy2010

    • Author(s)
      Y.Xu, H.Yoshikawa, J.H.Jang, M.Demura, K.Kobayashi, S.Ueda, Y.Yamashita, D.M.Wee, T.Hirano
    • Journal Title

      J.Phys.Chem.C

      Volume: 114 Pages: 6047-6053

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Measurement of optical constants of Si and SiO_2 from reflection electron energy loss spectra using factor analysis method2010

    • Author(s)
      H.Jin, H.Shinotsuka, H.Yoshikawa, H.Iwai, S.Tanuma, S.Tougaard
    • Journal Title

      Journal of Applied Physics 107

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X-Ray Photoelectron Spectroscopy of Core (Silver)-Shell (Polydiacetylene) Type Hybridized Nanocrystals2009

    • Author(s)
      H.Yoshikawa, A.M.Vlaicu, M.Kimura, A.Masuhara, S.Tanuma, H.Nakanishi, H.Oikawa
    • Journal Title

      e-Journal of Surface Science and Nanotechnology Vol.7

      Pages: 711-714

    • NAID

      130004439172

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of Depth Distribution Function for AR-XPS using Synchrotron Radiation Hard X-ray2009

    • Author(s)
      H.Yoshikawa, H.Tanaka, M.Kimura, T.Ogiwara, T.Kimura, K.Kumagai, S.Tanuma, M.Suzuki, K.Kobayashi
    • Journal Title

      Journal of Surface Analysis Vol.15

      Pages: 254-258

    • NAID

      130007499746

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] X-Ray Photoelectron Spectroscopy of Core (Silver)-Shell (Polydiacetylene) Type Hybridized Nanocrystals2009

    • Author(s)
      H.Yoshikawa, A.M.Vlaicu, M.Kimura, A.Masuhara, S.Tanuma, H.Nakanishi, H.Oikawa
    • Journal Title

      e-Journal of Surface Science and Nanotechnology 7

      Pages: 711-714

    • NAID

      130004439172

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Evaluation of Depth Distribution Function for AR-XPS using Synchrotron Radiation Hard X-ray2009

    • Author(s)
      H. Yoshikawa, H. Tanaka, M. Kimura, T. Ogiwara, T. Kimura, K. Kumagai, S. Tanuma, M. Suzuki, K. Kobayashi
    • Journal Title

      Journal of Surface Analysis 15

      Pages: 254-258

    • NAID

      130007499746

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] X-Ray Photoelectron Spectroscopy of Core (Silver) - Shell (Polydiacetylene) Type Hybridized Nanocrystals2009

    • Author(s)
      H. Yoshikawa, A. M. Vlaicu, M. Kimura, A. Masuhara, S. Tanuma, H. Nakanishi, H. Oikawa
    • Journal Title

      e-Journal of Surface Science and Nanotechnology

    • NAID

      130004439172

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] First principle calculation of the optical constants in a wide energy range for III-V semiconductors2010

    • Author(s)
      H.Shinotsuka, M.Arai, H.Yoshikawa, S.Tanuma
    • Organizer
      5th International Symposium on Practical Surface Analysis
    • Place of Presentation
      韓国
    • Year and Date
      2010-10-05
    • Related Report
      2010 Final Research Report
  • [Presentation] Energy loss functions and optical constants of a few semiconductors determined by factor analysis of reflection electron energy loss spectra2010

    • Author(s)
      H.Yoshikawa, H.Jin, H.Shinotsuka, H.Iwai, M.Arai, S.Tougaard, S.Tanuma
    • Organizer
      5th International Symposium on Practical Surface Analysis
    • Place of Presentation
      韓国
    • Year and Date
      2010-10-05
    • Related Report
      2010 Final Research Report
  • [Presentation] Energy loss functions and optical constants of a few semiconductors determined by factor analysis of reflection electron energy loss spectra2010

    • Author(s)
      H.Yoshikawa, H.Jin, H.Shinotsuka, H.Iwai, M.Arai, S.Tougaard, S.Tanuma
    • Organizer
      5th International Symposium on Practical Surface Analysis
    • Place of Presentation
      Gyeongju(韓国)
    • Year and Date
      2010-10-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] First principle calculation of the optical constants in a wide energy range for III-V semiconductors2010

    • Author(s)
      H.Shinotsuka, M.Arai, H.Yoshikawa, S.Tanuma
    • Organizer
      5th International Symposium on Practical Surface Analysis
    • Place of Presentation
      Gyeongju(韓国)
    • Year and Date
      2010-10-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] Hard X-ray Photoelectron Spectroscopy and XANES Analyses of Core (Silver)-Shell (Polydiacetylene) Type Hybridized Nanocrystals2009

    • Author(s)
      H.Yoshikawa, A.M.Vlaicu, M.Kimura, A.Masuhara, S.Tanuma, H.Nakanishi, H.Oikawa
    • Organizer
      7th International Symposium on Atomic Level Characterizations for New Materials and Devices 2009 (ALC'09)
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2009-12-08
    • Related Report
      2010 Final Research Report
  • [Presentation] Determination of optical constants of Si and SiO_2 from reflection electron energy loss spectra using factor analysis method2009

    • Author(s)
      H.Jin, H.Yoshikawa, H.Iwai, S.Shinotsuka, S.Tanuma, S.Tougaard
    • Organizer
      13th European Conference on Applications of Surface and Interface Analysis (ECASIA'09)
    • Place of Presentation
      TURKEY
    • Year and Date
      2009-10-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Calculation of Emission Depth Distribution Functions for CuO and SiO_2 by the Monte Carlo Simulation and the Quantum Mechanical Scattering Theory2009

    • Author(s)
      H.Shinotsuka, H.Yoshikawa, S.Tanuma, T.Fujikawa
    • Organizer
      13th European Conference on Applications of Surface and Interface Analysis (ECASIA'09)
    • Place of Presentation
      TURKEY
    • Year and Date
      2009-10-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Evaluation of Depth Distribution Function for AR-XPS using Synchrotron Radiation Hard X-ray2009

    • Author(s)
      H.Yoshikawa, H.Tanaka, M.Kimura, T.Ogiwara, T.Kimura, K.Kumagai, S.Tanuma, M.Suzuki, K.Kobayashi
    • Organizer
      International workshop for Surface Analysis and Standardization '09
    • Place of Presentation
      沖縄
    • Year and Date
      2009-03-16
    • Related Report
      2010 Final Research Report
  • [Presentation] Evaluation of Depth Distribution Function for AR-XPS using Synchrotron Radiation Hard X-ray2009

    • Author(s)
      H. Yoshikawa, H. Tanaka, M. Kimura, T. Ogiwara, T. Kimura, K. Kumagai, S. Tanuma, M. Suzuki, K. Kobayashi
    • Organizer
      International workshop for Surface Analysis and Standardization '09
    • Place of Presentation
      沖縄コンベンションセンター、沖縄県宜野湾市
    • Year and Date
      2009-03-16
    • Related Report
      2008 Annual Research Report
  • [Presentation] Hard X-ray Photoelectron Spectroscopy and XANES Analyses of Core (Silver)-Shell (Polydiacetylene) Type Hybridized Nanocrystals2009

    • Author(s)
      H.Yoshikawa, A.M.Vlaicu, M.Kimura, A.Masuhara, S.Tanuma, H.Nakanishi, H.Oikawa
    • Organizer
      7th International Symposium on Atomic Level Characterizations for New Materials and Devices 2009 (ALC'09)
    • Place of Presentation
      The Westin Maui、Hawaii, USA
    • Related Report
      2009 Annual Research Report
  • [Presentation] Calculation of Emission Depth Distribution Functions for CuO and SiO_2 by the Monte Carlo Simulation and the Quantum Mechanical Scattering Theory2009

    • Author(s)
      H.Shinotsuka, H.Yoshikawa, S.Tanuma, T.Fujikawa
    • Organizer
      13th European Conference on Applications of Surface and Interface Analysis (ECASIA'09)
    • Place of Presentation
      Dedeman Hotel & Convention Center, Antalya, TURKEY
    • Related Report
      2009 Annual Research Report
  • [Presentation] Determination of optical constants of Si and SiO_2 from reflection electron energy loss spectra using factor analysis method2009

    • Author(s)
      H.Jin, H.Yoshikawa, H.Iwai, S.Shinotsuka, S.Tanuma, S.Tougaard
    • Organizer
      13th European Conference on Applications of Surface and Interface Analysis (ECASIA'09)
    • Place of Presentation
      Dedeman Hotel & Convention Center, Antalya, TURKEY
    • Related Report
      2009 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

Information User Guide FAQ News Terms of Use Attribution of KAKENHI

Powered by NII kakenhi