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Magnetic Properties of Porous Metal-Organic Hybrid Crystals Absorbing Molecular Gases

Research Project

Project/Area Number 20540336
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Condensed matter physics II
Research InstitutionKyushu Institute of Technology

Principal Investigator

TAKAGI Seishi  Kyushu Institute of Technology, 大学院・工学研究院, 教授 (90112359)

Co-Investigator(Kenkyū-buntansha) DEGUCHI HIROYUKI  九州工業大学, 大学院・工学研究院, 教授 (30192206)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,210,000 (Direct Cost: ¥1,700,000、Indirect Cost: ¥510,000)
Keywords磁性 / 多孔性物質 / 金属有機ハイブリッド化合物結晶 / ガス吸着効 / 分子性ガス吸着 / 多孔性化合物 / 有機無機ハイブリッド化合物 / 磁気的性質 / SQUID磁束計
Research Abstract

Porous metal-organic hybrid compounds have been studied for such as gas absorption and catalysis. In addition, their applications as gas sensors have been demonstrated by use of the change in magnetic or optical properties upon gas absorption and desorption. These experiments have been performed ex-situ. It is necessary to understand the properties in-situ, in particular to follow the performance of the materials continuously. Then we have developed an in-situ apparatus and studied the gas sorption effects on the magnetism of porous metal-organic hybrid compounds.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (21 results)

All 2011 2010 2009 2008 Other

All Journal Article (6 results) (of which Peer Reviewed: 6 results) Presentation (14 results) Remarks (1 results)

  • [Journal Article] Study of the Magnetism of Absorbed Paramagnetic Gases in the Metal-Organic Hybrid Ni_2(H_2O)_4PM.2H_2O2011

    • Author(s)
      Z.Jin, S.Matsumoto, N.Fujimoto, M.Yoshihiro, S.Takagi, M.Mito, H.Deguchi, M.Kurmoo
    • Journal Title

      Polyhedron Specila Issue (To be appeared).

      Pages: 4-4

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Study of the Magnetism of Absorbed Paramagnetic Cased in the Metal-Organic Hybrid Ni_2(H_2O)_4PM.2H_2O2011

    • Author(s)
      Z.Jin
    • Journal Title

      Polyhedron Special Issue

      Volume: (印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties of Segregated Layers Containing M^<II>_3(μ_3-OH)_2 (M=Co or Ni) Diamond Chains Bridged by cic, cis, cis-1, 2, 4, 5-Cyclohexanetetracarboxy-late2010

    • Author(s)
      M.Kurmoo, K.Otsubo, H.Kitagawa, M.Henry, M.Ohba, S.Takagi
    • Journal Title

      Inorg.Chem. 49

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Uniaxial Pressure Effect on the Magnetic Properties of the Metal-Organic Hybrid Compound Co^<II>(H_2O)_6Pyromellitate2010

    • Author(s)
      Shusuke Matsumoto, Kohei Kishizono, Narihisa Fujimoto, Mitsuru Yoshihiro, Masaki Mito, Hiroyuki Deguchi, Seishi Takagi, Mohamedally Kurmoo
    • Journal Title

      J.Phys : Conference Series 200

      Pages: 032043-4

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Magnetic Properties of Segregated Layers Containing M^<II>_3(μ_3-OH)_2 (M=Co or Ni) Diamond Chains Bridged by cic, cis, cis-1,2,4,5-Cyclohexan etertacarboxylate2010

    • Author(s)
      M.Kurmoo
    • Journal Title

      Inorganic Chemistry

      Volume: 49 Pages: 9700-9708

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Uniaxial Pressure Effect on the Magnetic Properties of the Metal-Organic Hybrid Compound Co^<II>(H_2O)_6 pyromellitate2010

    • Author(s)
      S.Matsumoto, K.Kishizono, N.Fujimoto, M.Yoshihiro, M.Mito, H.Deguchi, S.Takagi, M.Kurmoo
    • Journal Title

      J.Phys.: Coference Series 200

      Pages: 32043-32043

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 有機無機ハイブリッド化合物Ni-cis-1,4-chdcの酸素および一酸化窒素吸着効果2010

    • Author(s)
      松本周祐
    • Organizer
      日本物理学会九州支部例会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2010-12-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機無機ハイブリッド化合物Ni-Pyroの酸素および一酸化窒素吸着効果2010

    • Author(s)
      金正淑
    • Organizer
      日本物理学会九州支部例会
    • Place of Presentation
      長崎大学(長崎市)
    • Year and Date
      2010-12-04
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機無機ハイブリッド化合物Ni_3(OH)_2(cis-1,4-chdc)_2(H_2O)_4・2H_2Oの磁性の酸素および一酸化窒素吸着効果2010

    • Author(s)
      松本周祐,金正淑,藤本也久,吉弘満,高木精志,美藤正樹,出口博之,Mohamed Kurmoo
    • Organizer
      第116回日本物理学会九州支部例会
    • Place of Presentation
      長崎:長崎大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 有機無機ハイブリッド化合物Ni_2(H_2O)_2C_<10>H_2O_8・2H_2Oの磁性の酸素および一酸化窒素吸着効果2010

    • Author(s)
      金正淑,松本周祐,藤本也久,吉弘満,高木精志,美藤正樹,出口博之,Mohamed Kurmoo
    • Organizer
      第116回日本物理学会九州支部例会
    • Place of Presentation
      長崎:長崎大学
    • Related Report
      2010 Final Research Report
  • [Presentation] SQUID磁束計を用いたf=14kHまでの交流磁化率測定システムの開発2009

    • Author(s)
      鶴田一樹
    • Organizer
      日本物理学会九州支部講演会
    • Place of Presentation
      宮崎大学(宮崎市)
    • Year and Date
      2009-12-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] メソポーラスシリカSBA-15を利用した酸素分子の高圧下磁気測定2009

    • Author(s)
      鶴田英樹
    • Organizer
      日本物理学会九州支部講演会
    • Place of Presentation
      宮崎大学(宮崎市)
    • Year and Date
      2009-12-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Uniaxial Pressure Effect on the Magnetic Properties of the Metal-Organic Hybrid Compound Co^<II>(H_2O)_6 pyromellitate2009

    • Author(s)
      Shusuke Matsumoto(松本周祐)
    • Organizer
      International Conference on Magnetism(ICM 2009)
    • Place of Presentation
      Karlsruhe(Germany)
    • Year and Date
      2009-07-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] 磁気異方性を示すコバルト-ピロメリット酸化合物単結晶の磁性の一軸加圧効果2009

    • Author(s)
      松本周祐,岸園康平,藤本也久,高木精志,美藤正樹,出口博之,M.Kurmoo
    • Organizer
      日本物理学会第64回年次大会
    • Place of Presentation
      東京:立教大学
    • Related Report
      2010 Final Research Report
  • [Presentation] 磁気異方性を示すコバルト-ピロメリット酸化合物の磁性の一軸加圧効果2008

    • Author(s)
      岸園 康平
    • Organizer
      日本物理学会九州支部講演会
    • Place of Presentation
      福岡工業大学(福岡市)
    • Year and Date
      2008-12-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ni-ピロメリット酸化合物の磁性の脱水・加水効果及び分子性ガス吸着効果2008

    • Author(s)
      上田 竜也
    • Organizer
      日本物理学会九州支部講演会
    • Place of Presentation
      福岡工業大学(福岡市)
    • Year and Date
      2008-12-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ni-シクロヘキサンジカルボン酸化合物の磁性の脱水・加水効果及び分子性ガス吸着効果2008

    • Author(s)
      藤本 也久
    • Organizer
      日本物理学会九州支部講演会
    • Place of Presentation
      福岡工業大学(福岡市)
    • Year and Date
      2008-12-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] 磁気異方性を示すコバルト-ピロメリット酸化合物の磁性の一軸加圧効果2008

    • Author(s)
      岸園康平,藤本也久,松本周祐,高木精志,美藤正樹,出口博之,M.Kurmoo
    • Organizer
      第114回日本物理学会九州支部例会
    • Place of Presentation
      福岡:福岡工業大学
    • Related Report
      2010 Final Research Report
  • [Presentation] Ni-ピロメリット酸化合物の磁性の脱水・加水効果及び分子性ガス吸着効果2008

    • Author(s)
      上田竜也,中隈大就,松本周祐,高木精志,美藤正樹,出口博之,M.Kurmoo
    • Organizer
      第114回日本物理学会九州支部例会
    • Place of Presentation
      福岡:福岡工業大学
    • Related Report
      2010 Final Research Report
  • [Presentation] Ni-シクロヘキサンジカルボン酸化合物の磁性の脱水・加水効果及び分子性ガス吸着効果2008

    • Author(s)
      藤本也久,岸園康平,松本周祐,高木精志,美藤正樹,出口博之,M.Kurmoo
    • Organizer
      第114回日本物理学会九州支部例会
    • Place of Presentation
      福岡:福岡工業大学
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2020-05-15  

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