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Chemical state of trace elements and their chemical behavior during sedimentation and diagenesis: proxy for paleoenvironment

Research Project

Project/Area Number 20540475
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Geochemistry/Astrochemistry
Research InstitutionHiroshima University

Principal Investigator

SHIMIZU Hiroshi  Hiroshima University, 大学院・理学研究科, 名誉教授 (60090544)

Co-Investigator(Kenkyū-buntansha) TAKAHASHI Yoshio  広島大学, 大学院・理学研究科, 教授 (10304396)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Keywords微量元素 / 希土類元素 / 堆積過程 / 続成過程 / 化学状態 / 古環境 / 堆積物 / 堆積・続成過程 / 腐植物質 / 原油 / バクテリア / 化学状態決定 / 古環境指標 / マンガン酸化物 / 海洋環境 / 深海底堆積物 / チャート / Mn酸化物相 / リン酸塩相 / XANES法 / LA-ICP-MS
Research Abstract

Chemical state of trace elements such as rare earth elements (REE) and their chemical behavior during sedimentation and diagenesis were studied, in order to examine trace elements in sediments on the geochemical tracer reflecting their sedimentation environments. It is shown on marine sediments that REE incorporated into Mn oxides during sedimentation were released from Mn oxide dissolution during diagenesis, but the released REE were absorbed to phosphate phase such as apatite during the diagenesis. REE patterns in sedimentary rocks are confirmed to inherit their features as a whole through sedimentation and diagenesis and to be an useful geochemical tool reflecting the depositional environment.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (20 results)

All 2010 2009 2008

All Journal Article (17 results) (of which Peer Reviewed: 17 results) Presentation (3 results)

  • [Journal Article] Abundances of rare earth elements in crude oils and their partitions in water.2010

    • Author(s)
      R.Nakada, Y.Takahashi, G.Zheng, Y.Yamamoto, H.Shimizu
    • Journal Title

      Geochem. J. 44

      Pages: 411-418

    • NAID

      10027719720

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Systematic change in relative stabilities of REE-humic complexes at various metal loading levels.2010

    • Author(s)
      Y.Yamamoto, Y.Takahashi, H.Shimizu
    • Journal Title

      Geochem. J. 44

      Pages: 39-63

    • NAID

      10026142774

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] EXAFS study on the cause of enrichment of heavy REEs on bacteria cell surface.2010

    • Author(s)
      Y.Talahashi, M.Yamamoto, Y.Yamamoto, K.Tanaka
    • Journal Title

      Geochim. Cosmochim. Acta 74

      Pages: 5443-5462

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Abundances of rare earth elements in crude oils and their partitions in water2010

    • Author(s)
      R.Nakada
    • Journal Title

      Geochemical Journal

      Volume: 44 Pages: 411-418

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] EXAFS study on the cause of enrichment of heavy REEs on bacteria cell surface2010

    • Author(s)
      Y.Takahashi
    • Journal Title

      Geochimica et_Cosmochimica Acta

      Volume: 74 Pages: 5443-5462

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Systematic change in relative stabilities of REE-humic complexes at various metal loading levels2010

    • Author(s)
      Y.Yamamoto
    • Journal Title

      Geochemical Journal

      Volume: 44 Pages: 39-63

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Systematic change in relative stabilities of REE-humic complexes at various metal loading levels2010

    • Author(s)
      Y.Yamamoto
    • Journal Title

      Geochemical Journal 44

      Pages: 39-63

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Speciation of iron in humic substances by X-ray absorption fine structure and its effect on the complexation between humic substances and trace metal irons.2009

    • Author(s)
      Y.Yamamoto, Y.Takahashi, H.Shimizu
    • Journal Title

      Chem. Lett. 38

      Pages: 278-279

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of the host phase of rare earth elements in natural carbonate using X-ray absorption near-edge structure.2009

    • Author(s)
      K.Tanaka, Y.Takahashi, H.Shimizu
    • Journal Title

      Geochem. J. 43

      Pages: 143-149

    • NAID

      10026141260

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Determination of the host phase of rare earth elements in natural carbonate using X-ray absorption near-edge structure2009

    • Author(s)
      K.Tanaka
    • Journal Title

      Geochemical Journal 43

      Pages: 143-149

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Speciation of iron in humic substances by X-ray absorption fine structure and its effect on the complexation between humic substances and trace metal irons2009

    • Author(s)
      Y.Yamamoto
    • Journal Title

      Chemistry Letters 38

      Pages: 278-279

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Determination of the host phase of rare earth elements in natural carbonate using X-ray absorption near-edge structure2009

    • Author(s)
      K. Tanaka
    • Journal Title

      Geochemical Journal 43(印刷中)

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Observation of transformation of calcite to gypsum in mineral aerosols by Ca K-edge X-ray absorption near-edge structure (XANES).2008

    • Author(s)
      Y.Takahashi, T.Miyoshi, S.Yabuki, Y.Inada, H.Shimizu
    • Journal Title

      Atmospheric Environment 26

      Pages: 6535-6541

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] High-sensitive measurement of uranium L3-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials.2008

    • Author(s)
      Y.Yamamoto, Y.Takahashi, Y.Knai, Y.Watanabe, T.Uruga, H.Tanida, Y.Terada, H.Shimizu
    • Journal Title

      Applied Geochem. 23

      Pages: 2452-2461

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local structure of Y and Ho in calcite and its relevance to Y fractionation from Ho in partitioning between calcite and aqueous solution.2008

    • Author(s)
      K.Tanaka, Y.Takahashi, H.Shimizu
    • Journal Title

      Chem Geol. 248

      Pages: 104-113

    • NAID

      120000876563

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local structure of Y and Ho in calcite and its relevance to Y fractionation from Ho in partitioning between calcite and aqueous solution2008

    • Author(s)
      K. Tanaka
    • Journal Title

      Chemical Geology 248

      Pages: 104-113

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] High-sensitive measurement of uranium L3-edge X-ray absorption near-edge structure (XANES) for the determination of the oxidation states of uranium in crustal materials2008

    • Author(s)
      Y. Yamamoto
    • Journal Title

      Applied Geochemistry 23

      Pages: 2452-2461

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 原油中の希土類元素(REE)存在度と水-原油間でのREEの分配2010

    • Author(s)
      中田亮一・高橋嘉夫・鄭国東・清水洋
    • Organizer
      日本地球化学会第57回年会
    • Place of Presentation
      立正大学熊谷キャンパス
    • Year and Date
      2010-09-09
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 腐植物質-水酸化鉄共存系における希土類元素の固液分配2008

    • Author(s)
      山本祐平・高橋嘉夫・清水洋
    • Organizer
      日本地球化学会第55回年会
    • Place of Presentation
      東京大学駒場キャンパス
    • Year and Date
      2008-09-19
    • Related Report
      2010 Final Research Report
  • [Presentation] 腐植物質-水酸化鉄共存系における希土類元素の固液分配2008

    • Author(s)
      山本 祐平
    • Organizer
      2008年度日本地球化学会第55回年会
    • Place of Presentation
      東京大学教養学部
    • Year and Date
      2008-09-19
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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