Novel developments in the high-resolution spectroscopic study of reactive transition metal transient species

• Project/Area Number: 20550010
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Physical chemistry
• Research Institution: Shizuoka University
• Principal Investigator: OKABAYASHI Toshiaki Shizuoka University, 創造科学技術大学院, 教授 (70224045)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: 含遷移金属活性種 / 高分解能分光 / ナノクラスター / クラスター

Research Abstract

Fourier transform microwave (FTMW) spectrometer was developed for the high-resolution study of the reactive transition metal transient species. A newly designed laser-ablation system with an electronic discharge was combined with the FTMW spectrometer. Some reactive species were observed with a good S/N ratio. A good prospect is now seen in our current development to extend the high-resolution spectroscopy to more reactive transition metal species like nanoclusters.

Research Products

• [Journal Article] Low-energy vibrations of the group 10 metal monocarbonyl MCO (M = Ni, Pd, and Pt) : Rotational spectroscopy and force field analysis (2011)
  • Author(s): Toshiaki Okabayashi, Takuya Yamamoto, Emi Y.Okabayashi
  • Journal Title: Mitsutoshi Tanimoto, J.Phys.Chem. A 115(10) Pages: 1869-1877
  • Peer Reviewed
• [Journal Article] J.Phys.Chem.A (2011)
  • Author(s): T.Okabayashi, T.Yamamoto, E.Y.Okabayashi, M.Tanimoto
  • Journal Title: Low-energy vibrations of the group 10 metal monocarbonyl MCO (M=Ni, Pd, and Pt) : Rotational spectroscopy and force field analysis Volume: 115 Pages: 1869-1877
  • Peer Reviewed
• [Journal Article] Millimeter- and submillimeter-wave spectroscopy of platinum monocyanide, PtCN (2010)
  • Author(s): Emi Y.Okabayashi, Toshiaki Okabayashi, Takashi Furuya, Mitsutoshi Tanimoto
  • Journal Title: Chem.Phys.Lett. 492(1-3) Pages: 25-29
  • Peer Reviewed
• [Journal Article] Hyperfine resolved Fourier transform microwave and millimeter-wave spectroscopy of the iodomethyl radical, CH_2I (^2B_1) (2010)
  • Author(s): Stephane Bailleux, Patrik Kania, Jan Skrinsky, Toshiaki Okabayashi, Mitsutoshi Tanimoto, Satoshi Matsumoto, Hiroyuki Ozeki
  • Journal Title: J.Phys.Chem. 114(14) Pages: 4776-4784
  • Peer Reviewed
• [Journal Article] Millimeter and submillimeter-wave spectroscopy of platinum monocyanide, PtCN (2010)
  • Author(s): .Y. Okabayashi, T.Okabayashi, T.Furuya, M.Tanimoto
  • Journal Title: Chem. Phys. Lett. Volume: 492 Pages: 25-29
  • Peer Reviewed
• [Journal Article] Hyperfine Resolved Fourier Transform Microwave and Millimeter-Wave Spectroscopy of the Iodomethyl Radical, CH_2I (X^2B_1) (2010)
  • Author(s): S.Bailleux, P.Kania, J.Skrinsky, T.Okabayashi, M.Tanimoto, S.Matsumoto, Hiroyuki Ozeki
  • Journal Title: J.Phys.Chem.A
  • Peer Reviewed
• [Journal Article] Detection of free monomeric silver (I) and gold (I) cyanides, AgCN and AuCN : microwave sectra and molecular structure (2009)
  • Author(s): Toshiaki Okabayashi, Emi Y.Okabayashi, Fumi Koto, Toshimasa Ishida, Mitsutoshi Tanimoto
  • Journal Title: J.Amer.Chem.Soc. 131(33) Pages: 11712-11718
  • Peer Reviewed
• [Journal Article] Detection of free monomeric silver (I) and gold (I) cyanides, AgCN and AuCN : microwave spectra and molecular structure (2009)
  • Author(s): T.Okabayashi, E.Y.Okabayashi, F.Koto, T.Ishida, M.Tanimoto
  • Journal Title: J.Amer.Chem.Soc 131 Pages: 11712-11718
  • Peer Reviewed
• [Journal Article] Microwave spectroscopy of the PBr radical in the X^3Σ- state (2008)
  • Author(s): Toshiaki Okabayashi, Hideaki Kawajiri, Michiaki Umeyama, Chihiro Ide, Sumio Oe, Mitsutoshi Tanimoto
  • Journal Title: J.Chem.Phys. 129(12)
  • Peer Reviewed
• [Journal Article] Microwave spectroscopy of the PBr radical in the X ^3Σ^- state (2008)
  • Author(s): T. Okabayashi, H. Kawajiri, M. Umeyama, C. Ide, S. Oe, M. Tanimoto
  • Journal Title: J. Chem. Phys. 129
  • Peer Reviewed
• [Presentation] A search for interstellar carbon-chain alcohol HC_4OH in the star forming region L1527 (2011)
  • Author(s): Mitsutoshi Araki, Shuro Takano, Hiromichi Yamabe, Naohiro, Koshikawa, Koichi Tsukiyama, Aya Nakane, Toshiaki Okabayashi, Arisa Kunimatsu, Nobuhiko Kuze
  • Organizer: The 66th International Symposium on Molecular Spectroscopy
  • Place of Presentation: WF06, Columbus, Ohio
• [Presentation] 直線炭素鎖アルコールHC4OH:星形成領域L1527と暗黒星雲TMC-1での探査 (2011)
  • Author(s): 荒木光典・高野秀路・工藤沙紀・茅根彩花・梅木博也・山辺裕路・築山光一・中根綾・岡林利明・國松亜利沙・久世信彦
  • Organizer: 第11回分子分光研究会
  • Place of Presentation: 広島市立大学 広島市
• [Presentation] 直線炭素鎖アルコールHC_4OHのマイクロ波分光 (2011)
  • Author(s): 國松亜利沙・田辺沙織・小川智史・久世信彦・中根綾・岡林利明・荒木光典
  • Organizer: 第11回分子分光研究会
  • Place of Presentation: 広島市立大学 広島市
• [Presentation] 一塩化パラジウムPdClのマイクロ波分光 (2011)
  • Author(s): 岡林利明・喜瀬勇太
  • Organizer: 第11回分子分光研究会
  • Place of Presentation: 広島市立大学 広島市
• [Presentation] マイクロ波分光を用いたPdを含む短寿命分子種の研究 (2010)
  • Author(s): 喜瀬勇太・岡林恵美・岡林利明
  • Organizer: 第4回分子科学討論会2010
  • Place of Presentation: 大阪大学(大阪府)
  • Year and Date: 2010-09-16
• [Presentation] CH_2IClのフーリエ変換マイクロ波分光 (2010)
  • Author(s): 酒井翔平・尾関博之・S.Bailleux・岡林利明
  • Organizer: 第4回分子科学討論会2010
  • Place of Presentation: 大阪大学(大阪府)
  • Year and Date: 2010-09-15
• [Presentation] 一フッ化パラジウムPdFのマイクロ波分光 (2010)
  • Author(s): 喜瀬勇太・岡林利明
  • Organizer: 第10回分子分光研究会
  • Place of Presentation: 東京工業大学(東京都)
  • Year and Date: 2010-05-14
• [Presentation] マイクロ波分光を用いたPdを含む短寿命分子種の研究 (2010)
  • Author(s): 喜瀬勇太・岡林恵美・岡林利明
  • Organizer: 第4回分子科学討論会2010 3P014
  • Place of Presentation: 大阪大学豊中キャンパス 大阪府豊中市
• [Presentation] CH_2IClのフーリエ変換マイクロ波スペクトル (2010)
  • Author(s): 酒井翔平, 尾関博之, Stephane Bailleux, 岡林利明
  • Organizer: 第4回分子科学討論会2010 2P013
  • Place of Presentation: 大阪大学豊中キャンパス大阪府豊中市
• [Presentation] 一フッ化パラジウムPdFのマイクロ波分光 (2010)
  • Author(s): 喜瀬勇太・岡林恵美・岡林利明
  • Organizer: 第10回分子分光研究会
  • Place of Presentation: 東京工業大学大岡山キャンパス 東京都目黒区
• [Presentation] 一シアン化パラジウムPdCNのマイクロ波分光 (2009)
  • Author(s): 喜瀬勇太・岡林恵美・岡林利明
  • Organizer: 第9回分子分光研究会
  • Place of Presentation: 富山大学五福キャンパス
  • Year and Date: 2009-05-16
• [Presentation] 一フッ化白金PtFのマイクロ波分光 (2009)
  • Author(s): 岡林利明・蔵原卓・岡林恵美・谷本光敏
  • Organizer: 第9回分子分光研究会
  • Place of Presentation: 富山大学五福キャンパス
  • Year and Date: 2009-05-16
• [Presentation] Fourier transform microwave and millimeter wave spectroscopy of the iodomethyl radical, CH_2I(X^2B_1) (2009)
  • Author(s): S.Bailleux, H.Ozeki, T.Okabayashi, M.Tanimoto, P.Kania
  • Organizer: The 30th International Symposium on Free Radicals
  • Place of Presentation: Savonlinna, Finland
• [Presentation] 一フッ化白金PtFのマイクロ波分光 (2009)
  • Author(s): 岡林利明・蔵原卓・岡林恵美・谷本光敏
  • Organizer: 第9回分子分光研究会
  • Place of Presentation: 富山大学五福キャンパス 富山市
• [Presentation] 一シアン化パラジウムPdCNのマイクロ波分光 (2009)
  • Author(s): 喜瀬勇太・岡林恵美・岡林利明
  • Organizer: 第9回分子分光研究会
  • Place of Presentation: 富山大学五福キャンパス 富山市
• [Presentation] Fourier transform microwave and millimeter wave spectroscopy of the iodomethyl radical, CH_2I (X^2B_1) (2009)
  • Author(s): S.Bailleux, H.Ozeki, 岡林利明, M.Tanimoto, P.Kania
  • Organizer: The 30th International Symposium on Free Radicals
  • Place of Presentation: Savonlinna, Finland
• [Presentation] AgSHのマイクロ波分光 (2008)
  • Author(s): 岡林利明・山本拓也・水口伝一朗・岡林恵美・谷本光敏
  • Organizer: 第2回分子科学討論会(2008 1D14)
  • Place of Presentation: 福岡サンパレス 福岡市
• [Presentation] Detection in the Gas-phase of the Iodomethyl Radical, CH_2I, by Fourier Transform Microwave Spectroscopy Combined with Submillimeter-wave Spectroscopy (2008)
  • Author(s): Hiroyuki Ozeki, Toshiaki Okabayashi, Mitsutoshi Tanimoto, Jan Skrinsky, Patrik Kania, Stephane Bailleux
  • Organizer: The 20th International Conference on High Resolution Molecular Spectroscopy
  • Place of Presentation: Prague, Czech Republic
• [Presentation] AgSのマイクロ波分光 (2008)
  • Author(s): 岡林利明・大矢篤志・山本拓也・水口伝一朗・岡林恵美・谷本光敏
  • Organizer: 第8回分子分光研究会
  • Place of Presentation: 神戸大学六甲キャンパス 神戸市
• [Presentation] AgSのマイクロ波分光 (2008)
  • Author(s): 岡林利明, 大矢篤志, 山本拓也, 水口伝一朗, 岡林恵美, 谷本光敏
  • Organizer: 第8回分子分光研究会
  • Place of Presentation: 神戸大学六甲キャンパス
• [Presentation] Detection in the Gas-phase of the Iodomethyl Radical, CH_2I, by Fourier Transform Microwave Spectroscopy Combined with Subraillimeter-wave Spectroscopy (2008)
  • Author(s): H. Ozeki, T. Okabayashi, M. Tanimoto, T. Skrinsky, P. Kania, S. Bailleux
  • Organizer: The 20th International Conference on High Resolution Molecular Speotroscopy
  • Place of Presentation: チョコ共和国・プラハ
• [Presentation] AgSHのマイクロ波分光 (2008)
  • Author(s): 岡林利明, 山本拓也, 水口伝一朗, 岡林恵美, 谷本光敏
  • Organizer: 第2回分子科学討論会2008
  • Place of Presentation: 福岡サンパレス