Development of Synthetic Method for New Polycyclic Compounds based on Rearrangements of Quinone-fused Epoxy Ketones

• Project/Area Number: 20550040
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic chemistry
• Research Institution: Osaka University
• Principal Investigator: OSHIMA Takumi Osaka University, 工学研究科, 教授 (40107082)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000); Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000); Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000); Fiscal Year 2008: ¥2,990,000 (Direct Cost: ¥2,300,000、Indirect Cost: ¥690,000)
• Keywords: キノン / ホモキノン / エポキシド / 酸触媒 / 転位反応 / 多環状化合物 / 隣接基関与 / 反応速度 / 酸触媒反応 / エポキシケトン / 置換基効果 / 酸触媒反 / ルイス酸

Research Abstract

Highly strained quinone-fused epoxy ketones were synthesized via 1,3-dipolar cycloaddition of diaryldiazomethanes with quinones followed by epoxidation. These compounds underwent the acid-catalyzed epoxide ring cleavage associated with the transannular cyclization of endo-π-aryl group to afford several new polycyclic compounds. This synthetic strategy may be successfully applied for the other small-ring fused quinones in view of building a library of new polycyclic compounds.

Research Products

• [Journal Article] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroids vs Methanofullerene and C_<60> (2010)
  • Author(s): N.Ikuma, Y.Susami, T.Oshima
  • Journal Title: Org.Biomol.Chem. 8 Pages: 1394-1398
  • Peer Reviewed
• [Journal Article] Kinetic Evidence for Dihapto η2 π-Aryl Participation in Acid-Catakyzed Ring Opening of Diarylhomobenzoquinone Epoxides (2010)
  • Author(s): H.Asahara, K.Saito, T.Oshima
  • Journal Title: J.Org.Chem. 75 Pages: 733-740
  • Peer Reviewed
• [Journal Article] A New Approach to Benzofurane Synthesis : Lewis Acid Mediated Cycloaddition of Benzoquinones with Stilbene Oxides (2010)
  • Author(s): K.Kokubo, K.Harada, E.Mochizuk, T.Oshima
  • Journal Title: Tetrahedron Lett. 51 Pages: 955-958
  • Peer Reviewed
• [Journal Article] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroids vs Methanofullerene and C_<60> (2010)
  • Author(s): N.Ikuma
  • Journal Title: Org.Biomol.Chem. 8(印刷中)
  • Peer Reviewed
• [Journal Article] Kinetic Evidence for Dihapto (η2) π-Aryl Participation in Acid-Catalyzed Ring Opening of Diarylhomobenzoquinone Epoxides (2010)
  • Author(s): H.Asahara
  • Journal Title: J.Org.Chem. 75 Pages: 733-740
  • Peer Reviewed
• [Journal Article] A New Approach to Benzofuran Synthesis : Lewis Acid Mediated Cycloaddition of Benzoquinones with Stilbene Oxides (2010)
  • Author(s): K.Kokubo
  • Journal Title: Tetrahedron Lett. 51 Pages: 955-958
  • Peer Reviewed
• [Journal Article] フラーレン類の抗酸化評価および汎用化粧品成分の光分解抑制効果青江央江 (2009)
  • Author(s): 都賀谷京子、後藤忠示、伊藤雅之、小久保研、山名修一、大島巧
  • Journal Title: 日本香粧品学会誌 33 Pages: 149-154
  • Peer Reviewed
• [Journal Article] One-step Synthesis of Water-soluble Fullerenols Bearing Nitrogen-containing Substituents (2009)
  • Author(s): K.Matsubayashi, T.Goto, K.Togaya, K.Kokubo, T.Oshima
  • Journal Title: Fullerenes Nanotubes And Carbon Nanostructures 17 Pages: 440-456
  • Peer Reviewed
• [Journal Article] Antimicrobial Activity of Fullerenes and Their Hydroxylated Derivatives (2009)
  • Author(s): H.Aoshima, K.Kokubo, S.Shirakawa, M.Ito, S.Yamana, T.Oshima
  • Journal Title: Biocontrol Science 14 Pages: 69-72
  • NAID: 10025217636
  • Peer Reviewed
• [Journal Article] フラーレン類の抗酸化能評価および汎用化粧品成分の光分解抑制効果 (2009)
  • Author(s): 青島央江
  • Journal Title: 日本香粧品学会誌 33 Pages: 149-154
  • Peer Reviewed
• [Journal Article] One-step Synthesis of Water-soluble Fullerenols Bearing Nitrogen-containing Substituents (2009)
  • Author(s): K.Matsubahashi
  • Journal Title: Fullerenes Nanotubes And Carbon Nanostructures 17 Pages: 440-456
  • Peer Reviewed
• [Journal Article] Antimicrobial Activity of Fullerenes and Their Hydroxylated Derivatives (2009)
  • Author(s): 青島央江
  • Journal Title: Biocontrol Science 14 Pages: 69-72
  • Peer Reviewed
• [Journal Article] One-Step Synthesis of Water-Soluble Fullerenols bearingNitrogen-Containing Substituents (2009)
  • Author(s): K. Matsubayashi, K. Kokubo, H. Tategaki, S. Kawahama, T. Oshima
  • Journal Title: Fullerrenes, Nanotubes and CarbonNanostructures (In press)
  • Peer Reviewed
• [Journal Article] AlCl_3-Catalyzed Tandem Acetylation of Hydroxylated [60]Fullerene (2008)
  • Author(s): K.Kokubo, S.Tochika, M.Kato, Y.Sol, T.Oshima
  • Journal Title: Org.Lett. 10 Pages: 3335-3338
  • Peer Reviewed
• [Journal Article] Conformational Effects in Acid-Mediated Ring Opening of Epoxides : Prominent Role of the Oxirane Walsh Orbital (2008)
  • Author(s): T.Oshima, H.Asahara, E.Kubo, S.Miyamoto, K.Togaya
  • Journal Title: Org.Lett. 10 Pages: 2413-2416
  • Peer Reviewed
• [Journal Article] Structural Effects on Thermal Rearrangements of Fulleroids to Methanofullerenes. The Prominent Role of Cyclopropyl vs Aryl Substituent (2008)
  • Author(s): H.Kitamura, T.Oshima
  • Journal Title: Org.Lett. 10 Pages: 293-296
  • Peer Reviewed
• [Journal Article] Mechanistic Evidence for Remoto p-Aryl Participation in Acid-Catalyzed Ring Opening of Homobenzoquinone Epoxide (2008)
  • Author(s): T.Oshima, H.Asahara, T.Koizumi, S.Miyamoto
  • Journal Title: Chem.Commun. Pages: 1804-1806
  • Peer Reviewed
• [Journal Article] Facile Synthesis of Highly Water Soluble Fullerenes More Than Half-Covered by Hydroxy Groups (2008)
  • Author(s): K.Kokubo, K.Matsubayashi, H.Tategaki, H.Takada, T.Oshima
  • Journal Title: ACS Nano 2 Pages: 293-296
  • Peer Reviewed
• [Journal Article] Effects of Pin-up Oxygen on [60]Fullerene for Enhanced Antioxidant Activity (2008)
  • Author(s): K.Matsubayashi, T.Goto, K.Togaya, K.Kokubo, T.Oshima
  • Journal Title: Nanoscale Res.Lett. 3 Pages: 237-241
  • Peer Reviewed
• [Journal Article] structural Effects on Thermal Rearrangements of Fulle-roids to Methanofullerenes. The Prominent role of Cyclopropyl vs Aryl Substituent (2008)
  • Author(s): H. Kitamura, T. Oshima
  • Journal Title: Org. Lett. 10 Pages: 293-296
  • Peer Reviewed
• [Journal Article] Facile Synthesis of highly Water Soluble FullerenesMore Than Half-Covered by Hydroxy Groups (2008)
  • Author(s): K. Kokubo, K. Matsubayashi, H. Tategaki, H. Takada, T. Oshima
  • Journal Title: ACS Nano 2 Pages: 327-333
  • Peer Reviewed
• [Journal Article] Mechanistic Evidence for Remote π-Aryl Participation inAcid-catalyzed Eing Opening of Homobenzoquinone Epoxide (2008)
  • Author(s): T. Oshima, H. Asahara, T. Koizumi, S. Miyamoto
  • Journal Title: Chea. Co maun. Pages: 1804-1806
  • Peer Reviewed
• [Journal Article] Conformational Effects in Acid-Mediated Eing Opening ofEpoxides : Prominent Role of the Oxirane Walsh Orbital (2008)
  • Author(s): T. Oshima, H. Asahara, E. Kubo, S. Miyamoto, K. Togaya
  • Journal Title: Org. Lett. 10 Pages: 2413-2416
  • Peer Reviewed
• [Journal Article] AlCl_3-Catalyzed Tandem Acetylation of Hydroarylated[60]Fullerenes (2008)
  • Author(s): K. Kokubo, S. Tochika, M. Kato, Y. Sol, T. Oshima
  • Journal Title: Org. Lett. 15 Pages: 3335-3338
  • Peer Reviewed
• [Journal Article] Effects of Pin-up Oxygen on [60]Fullerene for EnhancedAntioxidant Activity (2008)
  • Author(s): K., Matsubayashi, T. Goto, K. Togaya, K. Kokubo, T. Oshima
  • Journal Title: Nanoscale Res. Lett. 3 Pages: 237-241
  • Peer Reviewed
• [Presentation] フラーレンとその誘導体のDiels-Alder反応における極性・ハロゲン溶媒の効果 (2011)
  • Author(s): 伊熊直彦、三木江翼、アラスト・セイエド・リヤー、小久保研、大島巧
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2011-03-28
• [Presentation] 蛍光標識水酸化フラーレンの合成およびその光物理特性 (2011)
  • Author(s): 小久保研、白川翔吾、伊熊直彦、大島巧
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2011-03-28
• [Presentation] トリアゾリノフラーレンの酸触媒脱窒素反応 (2011)
  • Author(s): 三木江翼、田中伸英、伊熊直彦、小久保研、大島巧
  • Organizer: 日本化学会第91回春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2011-03-28
• [Presentation] 2-メチルマロン酸エステル[60]フラーレン二付加体の位置化学ならびに電子的特性 (2011)
  • Author(s): 小久保研、アラストリヤー、大島巧
  • Organizer: 日本化学会91回春季年会
  • Place of Presentation: 横浜
  • Year and Date: 2011-03-28
• [Presentation] 2-メチルマロン酸エステル[60]フラーレンニ付加体の位置化学ならびに電子的特性 (2011)
  • Author(s): 小久保研
  • Organizer: 第91回日本化学会春季年会
  • Place of Presentation: 横浜市・神奈川大学
  • Year and Date: 2011-03-28
• [Presentation] トリアゾリノフラーレンの酸触媒脱窒素反応 (2011)
  • Author(s): 三木江翼
  • Organizer: 第91回日本化学会春季年会
  • Place of Presentation: 横浜市・神奈川大学
  • Year and Date: 2011-03-28
• [Presentation] 蛍光標識水酸化フラーレンの合成およびその光物理特性 (2011)
  • Author(s): 小久保研
  • Organizer: 第91回日本化学会春季年会
  • Place of Presentation: 横浜市・神奈川大学
  • Year and Date: 2011-03-28
• [Presentation] フラーレンとその誘導体のDiels-Alder反応における極性・ハロゲン溶媒の効果 (2011)
  • Author(s): 伊熊直彦
  • Organizer: 第91回日本化学会春季年会
  • Place of Presentation: 横浜市・神奈川大学
  • Year and Date: 2011-03-28
• [Presentation] モルホリノシクロアルケンとC60フラーレンの熱[2+2]環化付加 (2011)
  • Author(s): 三木江翼、浅原時泰、長尾和明、伊熊直彦、小久保研、大島巧
  • Organizer: 第40回フラーレン・ナノチューブシンポジウム
  • Place of Presentation: 名古屋市
  • Year and Date: 2011-03-09
• [Presentation] マルチアリール化[60]フラーレン誘導体の熱および酸化的安定性 (2011)
  • Author(s): 小久保研、柏原宮人、矢野智美、田中克知、伊熊直彦、大島巧
  • Organizer: 第40回フラーレン・ナノチューブシンポジウム
  • Place of Presentation: 名古屋市
  • Year and Date: 2011-03-09
• [Presentation] マルチアリール化[60]フラーレン誘導体の熱的および酸化的安定性 (2011)
  • Author(s): 小久保研
  • Organizer: 第40回フラーレン・ナノチューブシンポジウム
  • Place of Presentation: 名古屋市・名城大学
  • Year and Date: 2011-03-09
• [Presentation] モルホリノシクロアルケンとC60フラーレンの熱[2+2]環付加 (2011)
  • Author(s): 三木江翼
  • Organizer: 第40回フラーレン・ナノチューブシンポジウム
  • Place of Presentation: 名古屋市・名城大学
  • Year and Date: 2011-03-09
• [Presentation] Synthesis of Highly Soluble Multiarylated [60]Fullerene Derivatives Directed to Resist Materials (2010)
  • Author(s): M.Kashihara, M.Kato, T.Yano, K.Tanaka, K.Kokubo, N.Ikuma, T.Oshima
  • Organizer: PACIFICHEM
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2010-12-17
• [Presentation] Kinetics and Regioselectivity of Fulleroid in Diels-Alder Reaction and mCPBA Oxidation : Influence of Strain at the Bridgehead Olefin (2010)
  • Author(s): N.Ikuma, Y.Susami, K.Kokubo, T.Oshima
  • Organizer: PACIFICHEM
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2010-12-17
• [Presentation] Synthesis of Fullerenols Having Fluorophore Moiety (2010)
  • Author(s): K.Kokubo, S.Shirakawa, I.Morita, N.Ikuma, T.Oshima
  • Organizer: PACIFICHEM
  • Place of Presentation: Hawaii, USA
  • Year and Date: 2010-12-17
• [Presentation] Synthesis of fullerenols having fluorophore moiety (2010)
  • Author(s): K.Kokuba
  • Organizer: PACIFICHEM2010
  • Place of Presentation: ハワイ・ワイキキカンファレンスセンター
  • Year and Date: 2010-12-17
• [Presentation] Kinetics and regioselectivity of fulleroid in Diels-Alder reaction and mCPBA oxidation : influence of strain at the bridgehead olefin (2010)
  • Author(s): N.Ikuma
  • Organizer: PACIFICHEM2010
  • Place of Presentation: ハワイ・ワイキキカンファレンスセンター
  • Year and Date: 2010-12-17
• [Presentation] Synthesis of highly soluble multi-arylated [60] fullerene derivatives directed to resist materials (2010)
  • Author(s): M.Kashihara
  • Organizer: PACIFICHEM2010
  • Place of Presentation: ハワイ・ワイキキカンファレンスセンター
  • Year and Date: 2010-12-17
• [Presentation] フレロイドのmCPBA 酸化反応における橋頭位選択的エステル化 (2010)
  • Author(s): 伊熊直彦、住岡慧子、浅原時泰、小久保研、大島巧
  • Organizer: 第39回フラーレン・ナノチューブシンポジウム
  • Place of Presentation: 京都市
  • Year and Date: 2010-09-05
• [Presentation] フレロイドのmCPBA酸化反応における橋頭位選択的エステル化 (2010)
  • Author(s): 伊熊直彦
  • Organizer: 第39回フラーレン・ナノチューブシンポジウム
  • Place of Presentation: 京都市・京都大学
  • Year and Date: 2010-09-05
• [Presentation] フレロイド、メタノフラーレン及びアザフレロイドと各種ジエンとのDiels-Alder反応における速度論的研究 (2010)
  • Author(s): 田中伸英、伊熊直彦、小久保研、大島巧
  • Organizer: 日本化学会第90回春年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-28
• [Presentation] フレロイドの酸化反応における速度論的研究 (2010)
  • Author(s): 住岡慧子、伊熊直彦、小久保研、大島巧
  • Organizer: 日本化学会第90回春年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-28
• [Presentation] フレロイドの酸化反応における速度論的研究 (2010)
  • Author(s): 住岡慧子
  • Organizer: 日本化学会 第90回春季年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-28
• [Presentation] フレロイド、メタノフラーレン及びアザフレロイドと各種ジエンとの Diels-Alder 反応における速度論的研究 (2010)
  • Author(s): 田中伸英
  • Organizer: 日本化学会 第90回春季年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-28
• [Presentation] 部分塩素化水酸化フラーレンの合成およびそのアレルゲン除去能 (2010)
  • Author(s): 森田一翔、小久保研、野口武、大島巧
  • Organizer: 日本化学会第90回春年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-27
• [Presentation] 部分塩素化水酸化フラーレンの合成およびそのアレルゲン除去能 (2010)
  • Author(s): 森田一翔
  • Organizer: 日本化学会 第90回春季年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-27
• [Presentation] ジアリールホモベンゾキノンエポキシドの酸触媒開環反応におけるη^2タイプπ-Ar基関与に対する速度論的考察 (2010)
  • Author(s): 浅原時泰、斉藤浩太、大島巧
  • Organizer: 日本化学会第90回春年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-26
• [Presentation] ジアリールホモベンゾキノンエポキシドの酸触媒開環反応におけるη2タイプπ-Ar基関与に対する速度論的考察 (2010)
  • Author(s): 浅原時泰
  • Organizer: 日本化学会 第90回春季年会
  • Place of Presentation: 東大阪市
  • Year and Date: 2010-03-26
• [Presentation] 非水溶性低度水酸化フラレノールの簡便合成とそのナノ粒子特性 (2010)
  • Author(s): 小林直記、小久保研、大島巧
  • Organizer: 第38回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 名古屋市
  • Year and Date: 2010-03-04
• [Presentation] 高い電子受容性を有する[60]フラーレン二付加体の合成 (2010)
  • Author(s): アラストS.リヤー、小久保研、Hao Geng、Hsing-Lin Wang、大島巧、Long Y.Chiang
  • Organizer: 第38回フラーレン・ナノチューブ総合シンポジウム
  • Place of Presentation: 名古屋市
  • Year and Date: 2010-03-04
• [Presentation] Synthesis and Structural Analysis of novel [60]Fullerene Bisadducts (2009)
  • Author(s): K.Kokubo, R.S.Arasto, H.Geng, H.-L.Wang, T.Oshima, L.Y.Chiang
  • Organizer: IKOOC-11
  • Place of Presentation: Kyoto
  • Year and Date: 2009-11-12
• [Presentation] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroid (2009)
  • Author(s): N.Ikuma, Y.Susami, K.Kokubo, T.Oshima
  • Organizer: IKOOC-11
  • Place of Presentation: Kyoto
  • Year and Date: 2009-11-12
• [Presentation] Kinetic Evaluation of Fractionalipso/ortho π-Aryl Participation in Acid-Catalyzed Ring-opening of Diarylhomobenzoquinone epoxides (2009)
  • Author(s): H.Asahara, K.Saito, T.Oshima
  • Organizer: IKOOC-11
  • Place of Presentation: Kyoto
  • Year and Date: 2009-11-12
• [Presentation] Kinetic Evaluation of Fractional ipso/ortho p-Aryl Participation in Acid-Catalyzed Ring-Openning of Diarylhomobonzoquinone Epoxides (2009)
  • Author(s): 浅原時泰
  • Organizer: The 11th International KYOTO conference on New Aspests of Organic Chemistry (IKCOC-11)
  • Place of Presentation: 京都市
  • Year and Date: 2009-11-12
• [Presentation] Kinetics and Regioselectivity in Diels-Alder Reaction of Fulleroid (2009)
  • Author(s): N.Ikuma
  • Organizer: The 11th International KYOTO conference on New Aspests of Organic Chemistry (IKCOC-11)
  • Place of Presentation: 京都市
  • Year and Date: 2009-11-12
• [Presentation] Synthesis and Structural Analysis of Novel [60] Fullerene Bisadducts (2009)
  • Author(s): Riyah S.Arastoo
  • Organizer: The 11th International KYOTO conference on New Aspests of Organic Chemistry (IKCOC-11)
  • Place of Presentation: 京都市
  • Year and Date: 2009-11-12
• [Presentation] AlCl_3-catalyzed Tandem Acetylation of Hydroarylated [60]Fullerens (2009)
  • Author(s): K.Kokubo, S.Tochika, M.Kashihara, N.Ikuma, T.Oshima
  • Organizer: IKOOC-11
  • Place of Presentation: Kyoto
  • Year and Date: 2009-11-11
• [Presentation] AlCl_3-Catalyzed Tandem Acetylation of Hydroarylated [60] Fullerenes (2009)
  • Author(s): K.Kokubo
  • Organizer: The 11th International KYOTO conference on New Aspests of Organic Chemistry (IKCOC-11)
  • Place of Presentation: 京都市
  • Year and Date: 2009-11-11
• [Presentation] ジアリールシクロブタン縮環キノンの分子内[2+2]光付加環化反応における置換基効果 (2009)
  • Author(s): 浅原時泰、大久保敬、福住俊一、大島巧
  • Organizer: 2009年光化学討論会
  • Place of Presentation: 桐生市
  • Year and Date: 2009-09-16
• [Presentation] ジアリールホモキノンエポキシドの酸触媒骨格転位反応の速度置換基効果 (2008)
  • Author(s): 斉藤浩太、浅原時泰、大島巧
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 大阪
  • Year and Date: 2008-10-03
• [Presentation] ジアリールホモキノン土ポキシドの酸触媒骨格転位反応の速度置換基効果 (2008)
  • Author(s): 斎藤浩太, 浅原時泰, 大島巧
  • Organizer: 第19回基礎有機化学討論会
  • Place of Presentation: 大阪大学、大阪
  • Year and Date: 2008-10-03
• [Presentation] ヒドロアリール化フラーレン誘導体のFriedel-Craftsアセチル化反応ならびに新規環化反応 (2008)
  • Author(s): 加藤万依, 遠近真矢, 小久保研, 大島 巧
  • Organizer: 第3回三大学連携学生研究会、アトミック・ポリスケールテクノロジー連携研究会
  • Place of Presentation: 東京理科大学、長万部キャンバス、北海道
  • Year and Date: 2008-08-22
• [Presentation] β-カロテン退色法を用いた水溶性フラーレン誘導体の抗酸化能の評価 (2008)
  • Author(s): 都賀谷京子, 小久保 研, アラスト セイェド リヤー, 大島 巧
  • Organizer: 第3回三大学連携学生研究会、アトミック・ポリスケールテクノロジー連携研究会
  • Place of Presentation: 東京理科大学、長万部キャンパス、北海道
  • Year and Date: 2008-08-22
• [Remarks] ホームページ等
  • URL: http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/
• [Remarks] 大島研ウェブページ
  • URL: http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/
• [Remarks] 大島研論文リスト
  • URL: http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/publist.htm
• [Remarks] 大島研ウェブページ
  • URL: http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/
• [Remarks] 大島研論文リスト
  • URL: http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/publist.htm
• [Remarks]
  • URL: http://www.chem.eng.osaka-u.ac.jp/~oshima-lab/