Development of new synthetic reactions utilizing high reactivity of ethenetricarboxylates
Project/Area Number |
20550041
|
Research Category |
Grant-in-Aid for Scientific Research (C)
|
Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
|
Research Institution | Nara University of Education |
Principal Investigator |
YAMAZAKI Shoko Nara University of Education, 教育学部, 教授 (50182481)
|
Project Period (FY) |
2008 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
|
Keywords | 合成反応 / 効率的結合形成 / ルイス酸 / エテントリカルボン酸エステル / アミノアセタール / ピペリジン / ピロリジン / アレン / ケトマロン酸エチル / インデン / 2-アミノベンズアルデヒド / テトラヒドロキノリン / インドール / γ-ラクトン / トリフロロメチル基 / プロパルギルアルコール / シクロブタン / 2-エチニルアニリン / キノリン |
Research Abstract |
New efficient cycloaddition reactions utilizing high reactivity of ethenetricarboxylates has been developed. Lewis acid promoted reaction of ethenetricarboxylates with substituted propargyl alcohols, ethynyl anilines, aminobezaldehydes, aminoacetals, and allenes gave nitrogen or oxygen-containing cyclic and carbocyclic compounds. These reactions represent efficient ways to construct potentially useful compounds.
|
Report
(4 results)
Research Products
(50 results)
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[Journal Article] Lewis Acid Promoted Reactions of Ethenetricarboxylates with Allenes : Synthesis of Indenes and γ-Lactones via Conjugate Addition/Cyclization Reaction.2010
Author(s)
Yamazaki, S., Yamamoto, Y., Fukushima, Y., Takebayashi, M., Ukai, T., Mikata, Y.
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Journal Title
J.Org.Chem. 75
Pages: 5216-5222
Related Report
Peer Reviewed
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[Journal Article] Zinc-Catalyzed Reactions of Ethenetricarboxylates with 2-(Trimethyl-silylethynyl)anilines Leading to Bridged Quinoline Derivatives2009
Author(s)
Yamazaki, S., Morikawa, S., Miyazaki, K., Takebayashi, M., Yamamoto, Y., Morimoto, T., Kakiuchi, K., Mikata, Y.
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Journal Title
Org.Lett. 11
Pages: 2796-2799
Related Report
Peer Reviewed
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[Journal Article] Enantioselective Friedel-Crafts reactions of ethenetricarboxylates and substituted pyrroles and furans and intramolecular reaction of benzene derivatives2009
Author(s)
Yamazaki, S., Kashima, S., Kuriyama, T., Iwata, Y., Morimoto, T., Kakiuchi, K.
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Journal Title
Tetrahedron : Asymmetry 20
Pages: 1224-1234
Related Report
Peer Reviewed
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