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Synthesis and Application of a new type of conjugated heterocycles including a phosphorus ylide

Research Project

Project/Area Number 20550046
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Organic chemistry
Research InstitutionEhime University

Principal Investigator

HAYASHI Minoru  Ehime University, 大学院・理工学研究科, 准教授 (20272403)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
Keywords有機元素化学 / 有機リン / ホスホール / 共役複素環 / 合成化学 / 複素環 / 共役系 / リン
Research Abstract

Selective and versatile synthetic methods for new types of phosphorus(V) ylide-containing conjugated heterocycles have been developed. Various phospholes have been synthesized via the above methods, and their structure-function relationships about UV-Vis spectra were revealed. A functional dye, showing the different colors depend on the outside conditions, has been developed by using the above ylide-phosphole as a new type of chromophore.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (22 results)

All 2011 2010 2009

All Journal Article (5 results) (of which Peer Reviewed: 3 results) Presentation (15 results) Patent(Industrial Property Rights) (2 results)

  • [Journal Article] Bis-3-oxo-λ^5-phosphole : isolati on, structural analyses and synthesis of phosphorus-ylide containing conjugate heterocy-cles2010

    • Author(s)
      Y.Nishimura, Y.Kawamura, Y.Watanabe, M.Hayashi
    • Journal Title

      J.Org.Chem. 75

      Pages: 3875-3877

    • Related Report
      2010 Final Research Report
  • [Journal Article] Bis-3-oxo-λ^5-phosphole : isolation, structural analyses and synthesis of phosphorus-ylide containing conjugate heterocycles2010

    • Author(s)
      Y.Nishimura, Y.Kawamura, Y.Watanabe, M.Hayashi
    • Journal Title

      J.Org.Chem.

      Volume: 75 Pages: 3875-3877

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] シリルホスフィンを利用するリン-炭素結合生成反応2010

    • Author(s)
      林実
    • Journal Title

      有機合成化学協会誌

      Volume: 68 Pages: 614-624

    • NAID

      10026869447

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis-3-oxo-λ^5-phosphole : isolation, structural analyses and synthesis of phosphorus-ylide containing conjugate heterocycles2010

    • Author(s)
      Y.Nishimura, Y.Kawamura, Y.Watanabe, M.Hayashi
    • Journal Title

      J.Org.Chem. 75(in press)

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Organophosphine Syntheses via Activation of the Phosphorus-Silicon Bond of Silylphosphines2009

    • Author(s)
      M.Hayashi
    • Journal Title

      Chem.Rec. 9

      Pages: 236-245

    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] 新規リン含有蛍光性-λ^5-ホスフィニン化合物の合成2011

    • Author(s)
      居藤崇志・渡辺裕・林実
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] シリルポスフィンを利用するリン-炭素結合生成反応の開発と応用2010

    • Author(s)
      林実
    • Organizer
      有機合成化学協会中国四国支部奨励賞受賞講演
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-11-13
    • Related Report
      2010 Final Research Report
  • [Presentation] シリルホスフィンを利用するリン-炭素結合生成反応の開発と応用2010

    • Author(s)
      林実
    • Organizer
      有機合成化学協会中国四国支部奨励賞受賞講演
    • Place of Presentation
      岡山大学
    • Year and Date
      2010-11-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] リンイリド構造を有する新規共役ヘテロ環化合物の合成研究2010

    • Author(s)
      高畑智弘・渡辺裕・林実
    • Organizer
      日本化学会西日本大会2010
    • Place of Presentation
      熊本大学
    • Year and Date
      2010-11-06
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 3-オキソ-λ^5-ホスホールを用いた新規リン含有色素化合物の開発2010

    • Author(s)
      辻本博海・渡辺裕・林実
    • Organizer
      日本化学会西日本大会2010
    • Place of Presentation
      熊本大学
    • Year and Date
      2010-11-06
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] 3分子縮合反応による新規リン含有蛍光化合物の合成2010

    • Author(s)
      居藤崇志・右馬埜梨花・渡辺裕・林実
    • Organizer
      日本化学会西日本大会2010
    • Place of Presentation
      熊本大学
    • Year and Date
      2010-11-06
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Syntheses and structural analyses of 3-oxo-λ^5-phospholes2009

    • Author(s)
      西村康伸, 渡辺裕, 林実
    • Organizer
      IKCOC11
    • Place of Presentation
      Kyoto
    • Year and Date
      2009-11-12
    • Related Report
      2010 Final Research Report
  • [Presentation] Syntheses and structural analyses of 3-oxo-λ^5-phospholes2009

    • Author(s)
      西村康伸, 渡辺裕, 林実
    • Organizer
      IKCOC11
    • Place of Presentation
      リーガロイヤルホテル京都
    • Year and Date
      2009-11-12
    • Related Report
      2009 Annual Research Report
  • [Presentation] 新規リン含有蛍光化合物の合成と構造解析2009

    • Author(s)
      右馬埜梨花・渡辺裕・林実
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-08
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] ホスフィノ酢酸エステルと電子不足アルキンとの環化反応による3-オキソ-λ5-ホスホールの新規合成法2009

    • Author(s)
      辻本博海・西村康伸・右馬埜梨花・山原美穂・渡辺裕・林実
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2010 Final Research Report
  • [Presentation] ホスフィノ酢酸エステルと電子不足アルキンとの環化反応による3-オキソ-λ^5-ホスホールの新規合成法2009

    • Author(s)
      辻本博海・西村康伸・右馬埜梨花・山原美穂・渡辺裕・林実
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学
    • Year and Date
      2009-11-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] 3-オキソホスホール骨格を有する縮環型λ^5-ホスホール類の合成2009

    • Author(s)
      酒井亜美・西村康伸・渡辺裕・林実
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2009-03-28
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] リンイリドの分子内環化反応を用いる2位置換3-オキソ-λ^5-ベンゾホスホール類の合成2009

    • Author(s)
      西村康伸・酒井亜美・右馬埜梨花・渡辺裕・林実
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2009-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] ホスフィノ酢酸エステルとアルキンの付加環化反応による3-オキソ-λ^5-ホスホール類の新規合成法2009

    • Author(s)
      辻本博海・西村康伸・右馬埜梨花・渡辺裕・林実
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2009-03-27
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] リンイリドの分子内環化反応を用いる2位置換3-オキソ-λ^5-ベンソホスホール類の合成2009

    • Author(s)
      西村康伸, 酒井亜美, 右馬埜梨花, 渡辺 裕, 林 実
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学船橋キャンパス
    • Year and Date
      2009-03-27
    • Related Report
      2008 Annual Research Report
  • [Patent(Industrial Property Rights)] 新規な3-オキソ-λ^5-ホスホール型化合物とその製造方法2009

    • Inventor(s)
      林実, 他5名
    • Industrial Property Rights Holder
      愛媛大学
    • Industrial Property Number
      2009-014684
    • Filing Date
      2009-01-26
    • Related Report
      2010 Final Research Report
  • [Patent(Industrial Property Rights)] 特許(優先権主張出願)2009

    • Inventor(s)
      林 実, 他5名
    • Industrial Property Rights Holder
      愛媛大学
    • Industrial Property Number
      2009-014684
    • Filing Date
      2009-01-26
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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