Construction of Highly Conjugated Compounds Based on the Pericyclic Cycloreversion
Project/Area Number |
20550047
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Organic chemistry
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Research Institution | Ehime University |
Principal Investigator |
UNO Hidemitsu Ehime University, 大学院・理工学研究科, 教授 (20168735)
|
Research Collaborator |
YAMADA Hiroko 奈良先端科学技術大学院, 准教授 (20372724)
OKUJIMA Tetsuo 愛媛大学, 大学院・理工学研究科, 准教授 (60359924)
KOBAYASHI Nagao 東北大学, 大学院・理学研究科, 教授 (60124575)
MORI Shigeki 愛媛大学, 総合科学研究支援センター, 助教 (30572028)
KIM DongHo Yonsei University, Korea, Professor
|
Project Period (FY) |
2008 – 2010
|
Project Status |
Completed (Fiscal Year 2010)
|
Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
|
Keywords | 構造有機化学 / 有機電子材料 / ペンタセン / 前駆体塗布法 / ポルフィリン / フロリン / 逆Diels・Alder反応 / OFET / オクタフィリン / フタロシアニン / ポルフィリシ / ヘキサフィリン / 逆Diels-Alder反応 / テトラベンゾポルフィリン |
Research Abstract |
I have explored the methodology for synthesis of highly conjugated compounds applying the pericyclic cycloreversion of the precursors in the final step such as thermal retro-Diels-Alder reaction and photo de-thiocarbonylation. These precursors are easily purified due to high solubility toward common solvents and high stability toward oxidation. The targeted highly conjugated compounds can be obtained in a highly pure form by the thorough purification of the precursors. I have developed this methodology, prepared the π-fused compounds, and then clarified their intrinsic properties.
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Report
(4 results)
Research Products
(158 results)
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[Journal Article] Cyclo[8]isoindoles : Ring-Expanded and Annelated Porphyrinoids2011
Author(s)
T.Okujima, G.Jin, N.Matsumoto, J.Mack, S.Mori, K.Ohara, D.Kuzuhara, C.Ando, N.Ono, H.Yamada, H.Uno, N.Kobayashi
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Journal Title
Angew.Chem.Int.Ed. in press
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[Journal Article] Synthesis, Crystal Structure, and Photodynamics of π-Expanded Porphyrin-Fullerene Dyads Synthesized by Diels-Alder Reaction2010
Author(s)
H.Yamada, K.Ohkubo, D.Kuzuhara, T.Takahashi, A.S.D.Sandanayaka, T.Okujima, K.Ohara, O.Ito, H.Uno, N.Ono, S.Fukuzumi, J.Phys.
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Journal Title
Chem.B 114
Pages: 14717-14728
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[Journal Article] Highly Pure Synthesis, Spectral Assignments, and Two-Photon Properties of Cruciform Porphyrin Pentamers Fused with Benzene Units2010
Author(s)
H.Uoyama, K.S.Kim, K.Kuroki, J.-Y.Shin, T.Nagata, T.Okujima, H.Yamada, N.Ono, D.Kim, H.Uno
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Journal Title
Chem.Eur.J. 16
Pages: 4063-4074
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[Journal Article] Thermal Behabior of Bicyclo[2.2.2]-octadiene-Installed Precursors for 2H-Anthra[2,3-c]pyrroles and Anthra-[2,3-c]thiophene2010
Author(s)
H.Uoyama, C.Chenxin, H.Tahara, Y.Shimizu, H.Hagiwara, Y.Hanasaki, H.Yamada, T.Okujima, H.Uno
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Journal Title
Heterocycles 80
Pages: 1187-1196
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[Journal Article] Synthesis, Crystal Structure, and Photodynamics of π-Expanded Porphyrin-Fullerene Dyads Synthesized by Diels-Alder Reaction2010
Author(s)
H.Yamada, K.Ohkubo, D.Kuzuhara, T.Takahashi, A.S.D.Sandanayaka, T.Okujima, K.Ohara, O.Ito, H.Uno, N.Ono, S.Fukuzumi
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Journal Title
J.Phys.Chem.B
Volume: 114
Pages: 14717-14728
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Peer Reviewed
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[Journal Article] Highly Pure Synthesis, Spectral Assignments, and Two-Photon Properties of Cruciform Porphyrin Pentamers Fused with Benzene Units2010
Author(s)
H.Uoyama, K.S.Kim, K.Kuroki, J.-Y.Shin, T.Nagata, T.Okujima, H.Yamada, N.Ono, D.Kim, H.Uno
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Journal Title
Chem.Eur J.
Volume: 16
Pages: 4063-4074
Related Report
Peer Reviewed
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[Journal Article] Thermal Behabior of Bicyclo[2.2.2]octadiene-Installed Precursors for 2H-Anthra[2,3-c]pyrroles and Anthra[2,3-c]thiophene2010
Author(s)
H.Uoyama, C.Cai, H.Tahara, Y.Shimizu, H.Hagiwara, Y.Hanasaki, H.Yamada, T.Okujima, H.Uno
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Journal Title
Heterocycles
Volume: 80
Pages: 1187-1196
Related Report
Peer Reviewed
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[Journal Article] Thermal Behabior of Bicyclo[2.2.2]octadiene-Installed Precursors for 2H-Anthra[2,3-c]pyrroles and Anthra[2,3-c]thiophene2010
Author(s)
H.Uoyama, C.Chenxin, H.Tahara, Y.Shimizu, H.Hagiwara, Y.Hanasaki, H.Yamada, T.Okujima, H.Uno
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Journal Title
Heterocycles 80
Pages: 1187-1196
Related Report
Peer Reviewed
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[Journal Article] First Synthesis of meso-Chlorinated Tetrabenzoporphyrins2009
Author(s)
S.Ito, L.T.Phong, T.Komatsu, N.Igarashi, S.Otsubo, Y.Sakai, A.Ohno, S.Aramaki, Y.Tanaka, H.Uno, T.Oba, K.Hiratani
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Journal Title
Eur.J.Org.Chem.
Pages: 5373-5382
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[Journal Article] First Synthesis of meso-Chlorinated Tetrabenzoporphyrins2009
Author(s)
S.Ito, L.T.Phong, T.Komatsu, N.Igarashi, S.Otsubo, Y.Sakai, A.Ohno, S.Aramaki, Y.Tanaka, H.Uno, T.Oba, K.Hiratani
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Journal Title
Eur.J.Org.Chem
Pages: 5373-5382
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Peer Reviewed
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[Journal Article] Application of MCD Spectroscopy and TD-DFT to Nonplanar Core-Modified Tetrabenzoporphyrins : Effect of ReducedSymmetry on Nonplanar Porphyrinoids2008
Author(s)
J.Mack, M.Bunya, Y.Shimizu, H.Uoyama, N.Komobuchi, T.Okujima, H.Uno, S.Ito, M.J.Stillman, N.Ono, N.Kobayashi
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Journal Title
Chem.Eur.J. 14
Pages: 5001-5020
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[Presentation] Synthesis of Benzoporphycenes2010
Author(s)
D.Kuzuhara, K.Yano, H.Yamada, T.Okujima, H.Uno
Organizer
6^<th> International Conference on Porphyrins and Phthalocyanines
Place of Presentation
New Mexico, USA
Year and Date
2010-07-08
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[Presentation] 可溶性前駆体からのフタロシアニン類の合成と塗布変換型OFET2010
Author(s)
橋本祐介, 金光男, 吉川侑, 中村純, 酒井良正, 大野玲, 大坪才華, 荒牧晋司, 宇野英満, 山田容子, 小野昇, 奥島鉄雄
Organizer
第57回応用物理学関係連合講演会
Place of Presentation
平塚
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