| Project/Area Number |
20550047
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Ehime University |
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Principal Investigator |
UNO Hidemitsu Ehime University, 大学院・理工学研究科, 教授 (20168735)
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| Research Collaborator |
YAMADA Hiroko 奈良先端科学技術大学院, 准教授 (20372724)
OKUJIMA Tetsuo 愛媛大学, 大学院・理工学研究科, 准教授 (60359924)
KOBAYASHI Nagao 東北大学, 大学院・理学研究科, 教授 (60124575)
MORI Shigeki 愛媛大学, 総合科学研究支援センター, 助教 (30572028)
KIM DongHo Yonsei University, Korea, Professor
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 構造有機化学 / 有機電子材料 / ペンタセン / 前駆体塗布法 / ポルフィリン / フロリン / 逆Diels・Alder反応 / OFET / オクタフィリン / フタロシアニン / ポルフィリシ / ヘキサフィリン / 逆Diels-Alder反応 / テトラベンゾポルフィリン |
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| Research Abstract |
I have explored the methodology for synthesis of highly conjugated compounds applying the pericyclic cycloreversion of the precursors in the final step such as thermal retro-Diels-Alder reaction and photo de-thiocarbonylation. These precursors are easily purified due to high solubility toward common solvents and high stability toward oxidation. The targeted highly conjugated compounds can be obtained in a highly pure form by the thorough purification of the precursors. I have developed this methodology, prepared the π-fused compounds, and then clarified their intrinsic properties.
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