Development of fluorescent organosilicon compounds and utilization as light-emissive materials
| Project/Area Number |
20550049
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Osaka Prefecture University |
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Principal Investigator |
MAEDA Hajime Osaka Prefecture University, 物質化学系, 准教授 (40295720)
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| Co-Investigator(Kenkyū-buntansha) |
SEGI Masahito 金沢大学, 物質化学系, 教授 (90135046)
MIZUNO Kazuhiko 大阪府立大学, 工学研究科, 教授 (10109879)
IKEDA Hiroshi 大阪府立大学, 工学研究科, 准教授 (30211717)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | ケイ素 / シラン / ピレン / ピレノファン / シリルエチニル基 / エキシマー / 吸収 / 蛍光 / 並列構造 / スイッチ分子 / ペリレン / モノマー / ナフタレン / 蛍光量子収率 / 発光材料 / フイルム |
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| Research Abstract |
With the aim to develop novel light-emissive materials, synthesis of fluorescent organosilicon compounds and elucidation of emission mechanism were studied. As a result, aromatic rings and substituents on silicon atoms, and number of arylethynyl groups and acetylene linkages, are important for design of fluorescent organosilicon compounds, and it was demonstrated that fluorescence wavelengths, intensities, and lifetimes can be controlled by their molecular structures. Development of light-emissive molecules whose color of emission changed depending on surrounding environments, development of molecules that exhibit only intramolecular excimer emissions, and preparation of light-emissive PMMA films were also achieved.
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Report
(4 results)
Research Products
(57 results)
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[Journal Article] UV Absorption and Fluorescence Properties of Fused Aromatic Hydrocarbons Having Trimethylsilyl, Trimethylgermyl, and Trimethylstannyl Groups2009
Author(s)
Maeda, H., Ishida, H., Inoue, Y., Merpuge, A., Maeda, T., Mizuno, K.
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Journal Title
Res.Chem.Intermed. 35(8-9)
Pages: 939-948
Related Report
Peer Reviewed
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[Journal Article] Lariat-Crown Ether Based Fluorescence Sensors for Heavy Metal Ions2008
Author(s)
Maeda, H., Tierney, D.L., Mariano, P.S., Banerjee, M., Cho, D.W., Yoon, U.C.
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Journal Title
Tetrahedron 64(22)
Pages: 5268-5278
Related Report
Peer Reviewed
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[Journal Article] Photoinduced Tandem Three-Component Coupling of Propanedinitrile, 2,5-Dimethylhexa-2,4-diene, and Cyanoarenes2008
Author(s)
Ohashi, M., Nakatani, K., Maeda, H., Mizuno, K.
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Journal Title
J.Org.Chem. 73(21)
Pages: 8348-8351
Related Report
Peer Reviewed
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[Presentation] ナフタルイミド-シラン連結系化合物の光誘起電子移動反応によるラリアート型クラウンエーテル類の合成と金属イオン認識センサーとしての利用2008
Author(s)
前多肇, Tierney, D.L., Mariano, P.S., Banerjee, M., Cho, D.W., Yoon, U.C.
Organizer
第32回有機電子移動化学討論会
Place of Presentation
近畿大学本部キャンパス
Related Report
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[Presentation] Fluorescence Properties of Silylethynyl-Substituted Naphthalenes2008
Author(s)
Mizuno K., Maeda H., Minamida K., Fujii T., Yamaji M., Konishi, G., Asai, K.
Organizer
The 15th International Symposium on Organosilicon Chemistry (ISOS XV)
Place of Presentation
Haevichi Hotel & Resort, Jeju, Korea
Related Report
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