Exploration of Purely Organic Mole cular Metal Based on Hydrogen-Bond and Charge-Transfer Interaction
| Project/Area Number |
20550051
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Organic chemistry
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| Research Institution | Fukui University of Technology |
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Principal Investigator |
NAKASUJI Kazuhiro Fukui University of Technology, 工学部, 教授 (60028230)
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| Co-Investigator(Kenkyū-buntansha) |
MORITA Yasushi 大阪大学, 大学院・理学研究科, 准教授 (70230133)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 水素結合 / 電荷移動相互作用 / 分子性金属 / プロトン-電子連動系 / 結晶構造制御 / 電子ドナー分子 / イミダゾール / 核酸塩基 / 電荷移動 / 電子ドナー / プロトン / ドナー |
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| Research Abstract |
In order to explore purely organic molecular metals exhibiting peculiar properties and multiple functions based on the cooperation of hydrogen-bond and charge-transfer interactions, we have designed and synthesized new electron-donor molecules composed of tetrathiafulvalene analogues and hydrogen-bonding groups such as imidazole and nucleobases. These new molecules formed diverse network structures by robust hydrogen-bonds, and achieved highly conducting charge-transfer complexes with organic electron-acceptors molecules.
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Report
(4 results)
Research Products
(46 results)
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[Journal Article]2009
Author(s)
佐藤和信
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Journal Title
Molecular Realizations of Quantum Computing 2007(Kinki University Series on Quantum Computing, Vol.2)(World Scientific)
Pages: 58-162
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