Metal-metal interaction in tri- and penta-nuclear complexes with linearly arranged d8 metal units

Research Project

Project/Area Number	20550053
Research Category	Grant-in-Aid for Scientific Research (C)
Allocation Type	Single-year Grants
Section	一般
Research Field	Inorganic chemistry
Research Institution	Osaka University
Principal Investigator	TSUGE Kiyoshi Osaka University, 大学院・理工学研究部, 教授 (60280583)
Project Period (FY)	2008 – 2010
Project Status	Completed (Fiscal Year 2010)
Budget Amount *help	¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000) Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000) Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000) Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords	金属錯体化学 / 金属間相互作用 / 平面金(III)錯体ユニット / N,N架橋 / Au-N結合 / イミド架橋 / N,S架橋 / d8-d8相互作用 / 平面白金(II)錯体ユニット
Research Abstract	To examine the amplification of metal-metal interaction by formation of multinuclear metal ion array, syntheses of multinuclear complexes and complex ligands which enable the linear arrangement of d^8 metal units were conducted with gold (III) and platinum (II) units. A novel imido bridged gold (III) complex ligand was prepared by the reaction of aminopyrimidine and a planar gold (III) unit with bipyridine.

Report

(4 results)