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Studies on Syntheses of Novel Transition-Metal Nitrido or Imido Complexes and Mechanism of their Nitrogen-Atom Transfer Reactions

Research Project

Project/Area Number 20550064
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic chemistry
Research InstitutionOkayama University

Principal Investigator

SUZUKI Takayoshi  Okayama University, 大学院・自然科学研究科, 准教授 (80249953)

Co-Investigator(Kenkyū-buntansha) TAKAGI Hideo  名古屋大学, 物質科学国際研究センター, 准教授 (70242807)
KOJIMA Masaaki  岡山大学, 大学院・自然科学研究科, 教授 (20022725)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords金属錯体化学 / 窒素原子転移反応 / 窒素原子挿入反応 / 高原子価錯体 / ニトリド錯体 / イミノ錯体 / イミド錯体 / 窒素源子挿入反応
Research Abstract

In this research we have succeeded to synthesize new iridium complexes bearing bidentate organic ligands with an N-atom in their chelate framework, which resulted from N-atom insertion reaction initiated by photolysis of iridium(III)?azido complexes. Also, the investiga- tion of their chemical reactivities toward nucleophiles and/or electrophiles revealed the formation of new N-containing organic compounds, as well as the alkylation of the inserted N-atom followed by the complete transfer of the imino group from the metal center. Furthermore, photolysis of the related azido complexes afforded tetrazolate ligands, which could bridge two metal centers giving homo- and heterodinuclear metal complexes. The systematic investigation of their molecular structures in the solid states and in solution led to guide principles for molecular design of functional materials.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (78 results)

All 2011 2010 2009 2008

All Journal Article (31 results) (of which Peer Reviewed: 31 results) Presentation (47 results)

  • [Journal Article] Orange and Yellow Crystals of Copper(I) Complexes Bearing 8-(Diphenylphosphino)quinoline. A Pair of Distortion Isomers of an Intrinsic Tetrahedral Complex2011

    • Author(s)
      Takayoshi Suzuki, Hiroshi Yamaguchi, Akira Hashimoto, Koichi Nozaki, Mototsugu Doi, Naoya Inazumi, Noriaki Ikeda, Satoshi Kawata, Masaaki Kojima, Hideo D.Takagi
    • Journal Title

      Inorg.Chem. 50

      Pages: 3891-3987

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Orange and Yellow Crystals of Copper(I) Complexes Bearing 8-(Diphenylphosphino)-quinoline.A Pair of Distortion Isomers of an Intrinsic Tetrahedral Complex2011

    • Author(s)
      Takayoshi Suzuki
    • Journal Title

      Inorganic Chemistry

      Volume: 50(印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Polymorphic Platinum(II) Complex : Yellow, Red, and Green Polymorphs and X-ray Crystallography of [Pt(fdpb)Cl][Hfdpb=1,3-Bis(5-trifluoromethyl-2-pyridyl) benzene]2011

    • Author(s)
      Yuta Nishiuchi
    • Journal Title

      European Journal of Inorganic Chemistry

      Volume: 2011(印刷中)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and crystal structures of mononuclear and dinu- clear (pentamethylcyclopentadienyl)iridium-(III) complexes containing 2-mercapto- benzimidazole2010

    • Author(s)
      Mai Kotera, Takayoshi Suzuki
    • Journal Title

      Inorg.Chim.Acta 363

      Pages: 3602-3605

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structures and spin states of mono- and dinuclear iron(II) complexes of imidazole-4-carbalde- hyde azine and its derivatives2010

    • Author(s)
      Yukinari Sunatsuki, Ryohei Kawamoto, Kuni- hiro Fujita, Hisashi Maruyama, Takayoshi Suzuki, Hiroyuki Ishida, Masaaki Kojima, Seiichiro Iijima, Naohide Matsumoto
    • Journal Title

      Coord.Chem.Rev. 254

      Pages: 1871-1881

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, Crystal Structures, and Spectroscopic and Redox Pro- perties of Nickel(II) Complexes Containing Phosphane?(Amine or Quinoline)-Type Hybrid Ligands and a Nickel(I) Complex Bearing 8-(Diphenylphosphanyl)quinoline2010

    • Author(s)
      Akira Hashimoto, Hiroshi Yamaguchi, Taka- yoshi Suzuki, Kazuo Kashiwabara, Masaaki Kojima, Hideo D.Takagi
    • Journal Title

      Eur.J.Inorg.Chem.

      Pages: 39-47

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Homochiral column structure of rac-and Λ-[MIII(tn) 3] P309 (M=Co, Cr ; tn=1,3-diaminopropane ; P309=cyclophosphate(3-)) produced by multiple hydrogen bonds2010

    • Author(s)
      Yukinari Sunatsuki
    • Journal Title

      New Journal of Chemistry

      Volume: 34 Pages: 2777-2784

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Syntheses and crystal structures of mononuclear and dinuclear (pentamethylcyclo-pentadienyl) iridium(III) complexes containing 2-mercaptobenzimidazole2010

    • Author(s)
      Mai Kotera
    • Journal Title

      Inorganica Chimica Acta

      Volume: 363 Pages: 3602-3605

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structures and spin states of mono-and dinuclear iron(II) complexes of imidazole-4-carbaldehyde azine and its derivatives2010

    • Author(s)
      Yukinari Sunatsuki
    • Journal Title

      Coordination Chemistry Review

      Volume: 254 Pages: 1871-1881

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Relative reactivity of phenylboronic acid to phenylboronate ion toward L-lactate and mandelate at physiological pH2010

    • Author(s)
      Eisuke Watanabe
    • Journal Title

      Inorganic Chemistry Communications

      Volume: 13 Pages: 1406-1409

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Luminescence Change by the Solvent of Crystallization, Solvent Reorganization, and Vapochromism of Neutral Dicyanoruthenium(II) Complex in the Solid State2010

    • Author(s)
      Taichi Abe
    • Journal Title

      Inorganic Chemistry

      Volume: 49 Pages: 1794-1800

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation, Crystal Structures, and Spectroscopic and Redox Properties of Nickel(II)Complexes Containing Phosphane-(Amine or Quinoline)-Type Hybrid Ligands and a Nickel(I)Complex Bearing 8-(Diphenylphosphanyl)quinoline2010

    • Author(s)
      Akira Hashimoto
    • Journal Title

      European Journal of Inorganic Chemistry 2010

      Pages: 39-47

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Acid-Catalyzed Oxidation of Carboxymethyl Cellulose. Kinetics and Mechanism of Permanganate Oxidation of Carboxymethyl Cellulose in Acid Perchlorate Solutions2010

    • Author(s)
      Refat M.Hassan
    • Journal Title

      Catalysis Communications 11

      Pages: 611-615

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Novel Counter Anion Effects of Added[Co(NH_3)_6]X_3(X^-=Cl^-, Br^-, I^-, or ClO_4^-)on surface Tension Reduction in Aqueous Solutions of Anionic Surfactants2010

    • Author(s)
      Sieng Sovanna
    • Journal Title

      Chemistry Letters 39

      Pages: 306-307

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mononuclear bis(tridentate)-type and dinuclear triple helicate iron(II) complexes containing 2-ethyl-5-methylimidazole-4-carbaldehyde azine2009

    • Author(s)
      Yukinari Sunatsuki, Ryohei Kawamoto, Kuni- hiro Fujita, Hisashi Maruyama, Takayoshi Suzuki, Hiroyuki Ishida, Masaaki Kojima, Seiichiro Iijima, Naohide Matsumoto
    • Journal Title

      Bull.Chem.Soc.Jpn. 82

      Pages: 1497-1505

    • NAID

      10027170743

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structures and Spin States of Bis(tridentate)-Type Mononuclear and Triple Helicate Dinuclear Iron(II) Complexes of Imidazole-4-carb- aldehyde azine2009

    • Author(s)
      Yukinari Sunatsuki, Ryohei Kawamoto, Kuni- hiro Fujita, Hisashi Maruyama, Takayoshi Suzuki, Hiroyuki Ishida, Masaaki Kojima, Seiichiro Iijima, Naohide Matsumoto
    • Journal Title

      Inorg.Chem. 48

      Pages: 8784-8795

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bis[μ-2- (aminosulfanyl)pyridine(1-)]bis[(η^5-pentamethylcyclopentadienyl)iridium(III)] diiodide2009

    • Author(s)
      Yusuke Sekioka, Takayoshi Suzuki
    • Journal Title

      Acta Cryst., Sect.E 65

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures of (azido)(pentamethylcyclopentadienyl)iridium(III) complexes containing various types of bidentate ligands2009

    • Author(s)
      Takayoshi Suzuki, Mai Kotera, Asuka Taka- yama, Masaaki Kojima
    • Journal Title

      Polyhedron 28

      Pages: 2287-2293

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structures of(azido)(pentamethylcyclopentadienyl)-iridium(III)complexes containing various types of bidentate ligands2009

    • Author(s)
      Takayoshi Suzuki
    • Journal Title

      Polyhedron 28

      Pages: 2287-2293

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bis[μ-2-(aminosulfanyl)pyridine(1-)]bis[(η5-pentamethylcyclopentadienyl)iridium(III)]diiodide2009

    • Author(s)
      Yusuke Sekioka
    • Journal Title

      Acta Crystallography, Section E 65

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Electron transfer reaction of porphyrin and porphycene complexes of Cu(II)and Zn(II)in acetonitrile2009

    • Author(s)
      Kaori Aoki
    • Journal Title

      Dalton Transactions 2009

      Pages: 119-125

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structures and Spin States of Bis(tridentate)-Type Mononuclear and Triple Helicate Dinuclear Iron(II)Complexes of Imidazole-4-carbaldehyde azine2009

    • Author(s)
      Yukinari Sunatsuki
    • Journal Title

      Inorganic Chemistry 48

      Pages: 8784-8795

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mononuclear bis(tridentate)-type and dinuclear triple helicate iron(II)complexes containing 2-ethyl-5-methylimidazole-4-carbaldehyde azine2009

    • Author(s)
      Yukinari Sunatsuki
    • Journal Title

      Bulletin of the Chemical Society of Japan 82

      Pages: 1497-1505

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Surface tension reduction(STR)in aqueous solutions of anionic surfactants with cobalt(III)complexes2009

    • Author(s)
      Sieng Sovanna
    • Journal Title

      Journal of Colloid and Interface Science 332

      Pages: 194-200

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural Versatility of 5-Methyltetra- zolato Complexes of (η^5-Pentamethylcyclo- pentadienyl)iridium(III) Incorporating 2,2'-Bipyridine, N,N-Dimethyldithiocarbamate or 2-Pyridinethiolate Ligands2008

    • Author(s)
      Mai Kotera, Yusuke Sekioka, Takayoshi Su- zuki
    • Journal Title

      Inorg.Chem. 47

      Pages: 3498-3508

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural comparison of (pentamethyl- cyclopentadienyl)iridium(III) azido complexes containing potentially N,S-bidentate N-hetero- cyclic thiolates : 2- or 8-quinolinethiolate and benzimidazole-2-thiolate2008

    • Author(s)
      Mai Kotera, Yusuke Sekioka, Takayoshi Suzuki
    • Journal Title

      Inorg.Chim.Acta 361

      Pages: 1479-1484

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Structural Versatility of 5-Methyltetrazolato Complexes of (η^5-Pentamethylcyolo-pentadienyl)iridium(III)Incorporating 2, 2'-Bipyridine, N, N-Dimethyldithio-carbamate or 2-Pyridinethiolate Ligands2008

    • Author(s)
      Mai Kotera
    • Journal Title

      Inorganic Chemistry 47

      Pages: 3498-3508

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Structural comparison of (pentamethylcyclopentadienyl)iridium(III)azido complexes containing potentially N, S-bidentate N-heterocyclic thiolates : 2- or 8-quinolinethiolate and benzimidazole-2-thiolate2008

    • Author(s)
      Mai Kotera
    • Journal Title

      Inorganica Chimica Acta 361

      Pages: 1479-1484

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Cobalt(III)Complexes of a Tripodal Ligand Containing Three Imidazole Groups : Properties and Structures of Racemic and Optically Active Species2008

    • Author(s)
      Hiroyuki Nakamura
    • Journal Title

      European Journal of Inorganic Chemistry 2008

      Pages: 1258-1267

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis, Structures, and Magnetic Properties of Face-Sharing Heterodinuclear Ni(II)-Ln(III)(Ln =Eu, Gd, Tb, Dy)Complexes2008

    • Author(s)
      Tomoka Yamaguchi
    • Journal Title

      Inorganic Chemistry 47

      Pages: 5736-5745

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mono- and Trinuclear Cu^<11> Complexes with Tripodal Ligands2008

    • Author(s)
      Yukinari Sunatsuki
    • Journal Title

      Bulletin of the Chemical Society of Japan 81

      Pages: 716-725

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Orange and yellow cryst- als of copper(I) complexes bearing 8-diphen- ylphosphinoquinoline.2010

    • Author(s)
      鈴木孝義
    • Organizer
      A pair of distortion isomers of intrinsically tetrahedral complex, 2010 International Chemical Congress of Pacific Basin Societies (pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Final Research Report
  • [Presentation] Crystal structures and isomerization reactions of dinuclear Ir(III)?Rh(III) complexes bridged by 5-methyltetrazolate2010

    • Author(s)
      高山明日香
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis and reaction of ruthenium(II) azido complexes bearing 2- pyridinethiolate2010

    • Author(s)
      Go Nakamura
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Final Research Report
  • [Presentation] 5-メチルテトラゾラト架橋Ir-Rh二核錯体の結晶および溶存構造に与える共存配位子の影響2010

    • Author(s)
      高山明日香
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2010 Final Research Report
  • [Presentation] Novel Structural Modification of 8-(Diphenylphos- phino)quinoline Complexes2010

    • Author(s)
      Takayoshi Suzuki, Hideo D. Takagi
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in OSAKA, Japan
    • Place of Presentation
      Osaka.
    • Related Report
      2010 Final Research Report
  • [Presentation] Reactivities of Iridium- (III) NSC(NR_2)S^<2-> Complexes Generated by Photolysis of Azido-dithiocarbamato Com- plexes2010

    • Author(s)
      有吉慧太, 鈴木孝義
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      八王子
    • Related Report
      2010 Final Research Report
  • [Presentation] Nitrogen Atom Insertion Initiated by Photolysis of Iridium(III) Azido Complexes2010

    • Author(s)
      鈴木孝義
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds
    • Place of Presentation
      Sapporo, Japan.
    • Related Report
      2010 Final Research Report
  • [Presentation] Reactivities of Nitrogen Atom-inserted Products Generated by Photo- lysis of Iridium(III) Azido-dithiocarbamato Complexes2010

    • Author(s)
      有吉慧太
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coor- dination Compounds
    • Place of Presentation
      Sapporo, Japan.
    • Related Report
      2010 Final Research Report
  • [Presentation] Orange and yellow crystals copper(II) complexes bearing 8-diphenylphosphinoquinoline : A pair of disortion isomers of intrinsically tetrahedral complex2010

    • Author(s)
      Takayoshi Suzuki
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (Pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Annual Research Report
  • [Presentation] Reactivities of iridium(III) NSC(NR2)S2-complexes generated by photolysis of azido-dithiocarbamato complexes2010

    • Author(s)
      Keita Ariyoshi
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (Pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Annual Research Report
  • [Presentation] Geometrical isomers of cobalt(III) complexes with unsymmetrical tridentate (hydroxybenzamido) alkylamines2010

    • Author(s)
      Ryoji Mitsuhashi
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (Pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Annual Research Report
  • [Presentation] Crystal structures and isomerization reactions of dinuclear Ir(III)-Rh(III) complexes bridged by 5-methyltetrazolate2010

    • Author(s)
      Asuka Takayama
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (Pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Annual Research Report
  • [Presentation] Synthesis and reaction of ruthenium(II) azido complexes bearing 2-pyridinethiolate2010

    • Author(s)
      Go Nakamura
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (Pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Annual Research Report
  • [Presentation] Structures and magnetic property of seven-coordinate molybdenum(II) complexes containing 1,1,1-tris(dimethylphosphinomethyl)ethane2010

    • Author(s)
      Atsushi Kikuma
    • Organizer
      2010 International Chemical Congress of Pacific Basin Societies (Pacifichem2010)
    • Place of Presentation
      Honolulu, HI, U.S.A.
    • Related Report
      2010 Annual Research Report
  • [Presentation] Geometrical isomers of cobalt(III) complexes with unsymmetrical tridentaten-(alkylamino)salicylamidate ligands2010

    • Author(s)
      Ryoji Mitsuhashi
    • Organizer
      XVIIth International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz, Poland
    • Related Report
      2010 Annual Research Report
  • [Presentation] Preparation, structures, and properties of manganese(II), -(III), and -(IV) complexes with a tripodal ligand2010

    • Author(s)
      Masaaki Kojima
    • Organizer
      XVIIth International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz, Poland
    • Related Report
      2010 Annual Research Report
  • [Presentation] 8-(ジフェニルホスフィノ)キノリンを含む遷移金属錯体の特異な構造2010

    • Author(s)
      鈴木孝義
    • Organizer
      2010年日本化学会西日本大会
    • Place of Presentation
      熊本大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] Novel Structural Modification of 8-(Diphenylphosphino)quinoline Complexes2010

    • Author(s)
      Takayoshi Suzuki
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in OSAKA
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] Geometrical Isomers of Cobalt Complexes with Unsymmetrical Tridentate (Hydroxybenzamido) alkylamines2010

    • Author(s)
      Ryoji Mitsuhashi
    • Organizer
      60th Anniversary Conference on Coordination Chemistry in OSAKA
    • Place of Presentation
      Osaka, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] 5-メチルテトラゾラト架橋Ir-Rh二核錯体の結晶および溶存構造与える共存配位子の影響2010

    • Author(s)
      高山明日香
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2010 Annual Research Report
  • [Presentation] 特異な構造および電子状態の安定化を可能にする三脚状三座ホスフィン配位子を有するMo, W錯体の合成と性質2010

    • Author(s)
      菊間淳志
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2010 Annual Research Report
  • [Presentation] 8-(ジフェニルホスフィノ)キノリンおよびその類縁配位子を含む遷移金属錯体の合成と立体構造2010

    • Author(s)
      中村豪
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2010 Annual Research Report
  • [Presentation] テトラゾラト誘導体を架橋配位子に用いた異種金属二核錯体の合成と性質2010

    • Author(s)
      竹原佑太郎
    • Organizer
      第60回錯体化学討論会
    • Place of Presentation
      大阪
    • Related Report
      2010 Annual Research Report
  • [Presentation] Reactivities of Iridium(III) NSC(NR2)S2-Complexes Generated by Photolysis of Azido-dithiocarbamato Complexes2010

    • Author(s)
      有吉慧太
    • Organizer
      第57回有機金属化学討論会
    • Place of Presentation
      中央大学(八王子)
    • Related Report
      2010 Annual Research Report
  • [Presentation] Unusual Molecular Structures of 8-Diphenylphosphinoquinoline Complexes. Two Novel Examples of Palladium(II) and Copper (I) with Crystal Color Changes2010

    • Author(s)
      Takayoshi Suzuki
    • Organizer
      2nd Okayama University - Copenhagen University collaboration symposium
    • Place of Presentation
      Copenhagen, Denmark
    • Related Report
      2010 Annual Research Report
  • [Presentation] Reactivities of Iridium(III) Complexes Containing N-atom-inserted Ligands, NSC(NR2)S2-and SN=C(NR2)S2-2010

    • Author(s)
      Keita Ariyoshi
    • Organizer
      2nd Okayama University - Copenhagen University collaboration symposium
    • Place of Presentation
      Copenhagen, Denmark
    • Related Report
      2010 Annual Research Report
  • [Presentation] Geometrical Isomers of Cobalt(III) Complexes with Unsymmetrical Tridentate (Hydroxybenzamido) alkylamines2010

    • Author(s)
      Ryoji Mitsuhashi
    • Organizer
      2nd Okayama University - Copenhagen University collaboration symposium
    • Place of Presentation
      Copenhagen, Denmark
    • Related Report
      2010 Annual Research Report
  • [Presentation] Crystal Structures and Isomerization Reactions of Dinuclear Ir-Rh Complexes Bridged by 5-Methyltetrazolate2010

    • Author(s)
      Asuka Takayama
    • Organizer
      2nd Okayama University Copenhagen University collaboration symposium
    • Place of Presentation
      Copenhagen, Denmark
    • Related Report
      2010 Annual Research Report
  • [Presentation] Mononuclear Manganese(II), -(III), and -(IV) Complexes with a Tripodal Ligand2010

    • Author(s)
      Masaaki Kojima
    • Organizer
      2nd Okayama University - Copenhagen University collaboration symposium
    • Place of Presentation
      Copenhagen, Denmark
    • Related Report
      2010 Annual Research Report
  • [Presentation] 5-メチルテトラゾラトが架橋した異種金属二核錯体の特異な異性化反応メカニズム2009

    • Author(s)
      高山明日香
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎
    • Related Report
      2010 Final Research Report
  • [Presentation] 2-シアノエチルホスフィン類を含むCo(III)錯体の構造、性質および反応:テトラゾラト/ホスフィン型キレート錯体の生成2009

    • Author(s)
      木原恵子
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎
    • Related Report
      2010 Final Research Report
  • [Presentation] 8-(ジフェニルホスフィノ)キノリンを含むイリジウム(III)ヒドリド錯体の生成2009

    • Author(s)
      有吉慧太
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      船橋
    • Related Report
      2010 Final Research Report
  • [Presentation] Nitrogen Atom Insertion Initiated by Photolysis of Iridium(III)Azido Complexes2009

    • Author(s)
      Takayoshi Suzuki
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds
    • Place of Presentation
      札幌
    • Related Report
      2009 Annual Research Report
  • [Presentation] Reactivities of Nitrogen Atom-inserted Products Generated by Photolysis of Iridium(III)Azido-dithiocarbamato Complexes2009

    • Author(s)
      Keita Ariyoshi
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds
    • Place of Presentation
      札幌
    • Related Report
      2009 Annual Research Report
  • [Presentation] 2-シアノエチルホスフィン類を含むCo(III)錯体の構造、性質および反応 : テトラゾラト/ホスフィン型キレート錯体の生成2009

    • Author(s)
      木原恵子
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 5-メチルテトラゾラトが架橋した異種金属二核錯体の特異な異性化反応メカニズム2009

    • Author(s)
      高山明日香
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] ジチオカルバマトおよびアジドを含む錯体に光照射により生成したイリジウム(III)NSC(NR_2)S^<2->錯体の反応性2009

    • Author(s)
      有吉慧太
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 非対称型三座アミドまたはシッフ塩基配位子を用いた金属錯体の合成とその構造および性質2009

    • Author(s)
      三橋了爾
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] アミド基を有する直鎖型六座配位子を用いたコバルト(II/III)錯体の合成と性質2009

    • Author(s)
      山根優希
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] 三脚型配位子を用いた単核マンガン(II),(III),(IV)錯体の合成と性質2009

    • Author(s)
      喜島由香菜
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] Novel counter anion effects(CAEs)of added[Co(NH_3)_6]X_3(X^-=Cl^-, Br^-, I^- or ClO_4^-)on surface tension reduction(STR)of aqueous solutions of anionic surfactants2009

    • Author(s)
      S.Sovanna
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学
    • Related Report
      2009 Annual Research Report
  • [Presentation] Structural Versatility of 5-Methyltetrazolato Complexes of (Pentame- thylcyclopentadienyl)iridium(III) Incorpora- ting 2,2'-Bipyridine, N,N-Dimethyldithiocarb- amate, or 2-Pyridinethiolate Ligands2008

    • Author(s)
      鈴木孝義
    • Organizer
      38th International Conference on Coordination Chemistry
    • Place of Presentation
      Jerusalem, Israel.
    • Related Report
      2010 Final Research Report
  • [Presentation] STRUCTURAL VERSATILITY OF 5-METHYLTETRAZOLATO COMPLEXES OF (PENTAMETHYLCYCLOPENTADIENYL)IRIDIUM(III)INCORPORATING 2, 2'-BIPYRIDINE, N, N-DIMETHYLDITHIOCARBAMATE, OR 2-PYRIDINETHIOLATE LIGANDS2008

    • Author(s)
      Takayoshi Suzuki
    • Organizer
      38th International Conference on Coordination Chemistry
    • Place of Presentation
      Jerusalem, Israel
    • Related Report
      2008 Annual Research Report
  • [Presentation] STRUCTURES AND SPIN STATES OF MONO- AND DINUCLEAR IRON(II)COMPLEXES WITH BIS-IMIDAZOLYLIMINE LIGANDS2008

    • Author(s)
      Masaaki Kojima'
    • Organizer
      XVIth International Winter School on Coordination Chemistry
    • Place of Presentation
      Karpacz, Poland
    • Related Report
      2008 Annual Research Report
  • [Presentation] 2-シアノエチル基を有する単座ホスフィンを含むCo(III)錯体の構造と性質2008

    • Author(s)
      木原恵子
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] 種々の二座キレート配位子を含むCp^*Ir^<III>(N_3)錯体(Cp^*= η^5-C_5Me_5)の結晶構造2008

    • Author(s)
      高山明日香
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2008 Annual Research Report
  • [Presentation] 8-ジフェニルホスフィノキノリンを含むCp^*Ir^<III> (Cp^* = η^5-C_5Me_5)ヒドリド錯体の生成2008

    • Author(s)
      有吉慧太
    • Organizer
      第58回錯体化学討論会
    • Place of Presentation
      金沢大学
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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