Synthesis of new functional materials by assembly of lantern-type dinuclear complexes
| Project/Area Number |
20550066
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic chemistry
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| Research Institution | Shimane University |
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Principal Investigator |
HANDA Makoto Shimane University, 総合理工学部, 教授 (70208700)
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| Co-Investigator(Kenkyū-buntansha) |
IKEUE Takahisa 島根大学, 総合理工学部, 准教授 (00379033)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
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| Keywords | 二核錯体 / 集積化 / 磁性 / 液晶 / 置換反応 / ポリマー錯体 / ルテニウム / ロジウム / 機能性化合物 |
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| Research Abstract |
Assembled complexes of lantern-type dinuclear complxes composed of two metal ions and four bidentate ligands such as carboxylate ions were synthesized and characterized. Chlorido and cyanato-bridged polymers of ruthenium (II, III) carboxylate dimers with long alkyl chains have shown intra-dimer antiferromagnetisms and liquid crystalline properties. New types of assembled complexes of the lantern-type dimers were also obtained by using formamidinato and carboxylato ligands for supporting the dinuclear skeletons.
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Report
(4 results)
Research Products
(113 results)
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[Journal Article] Synthesis, Magnetic and Spectral Properties, and Crystal Structure of Mixed-Valence Ruthenium(II,III) 3,4,5-Tributanoxy benzotate, in "Insights into Coordination, Bioinorganic and Applied Inorganic Chemistry," "ed by M.Melnik, J.Sigla, and M.Tatarko2009
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[Presentation] Synthesis, One-dimensional Polymer Complexes of Rhodium(II) Carboxylates and N,N'-Bidentate Ligands2011
Author(s)
Masahiro Mikuriya, Junya Yamamoto, Kazuya Ouchi, Yasutaka Nakanishi, Daisuke Yoshioka, Hidekazu Tanaka, Makoto Handa
Organizer
Second International Conference on Multifunctional, Hybrid & Nanomaterials
Place of Presentation
Strasbourg, France
Year and Date
2011-03-07
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[Presentation] Synthesis, Crystal Structures, and Adsorption Properties of Chain Complexes of Rhodium(II) Acerate and Rhodium(II) Benzoate with N,N'-Bidentate Ligands2010
Author(s)
Masahiro Mikuriya, Junya Yamamoto, Kazuya Ouchi, Yasutaka Nakanishi, Daisuke Yoshioka, Hidekazu Tanaka, Makoto Handa
Organizer
IVth International Conference on Molecular Materials MOLMAT 2010
Place of Presentation
Montpellier, France
Year and Date
2010-07-06
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[Presentation] チオオキザミド金属錯体の合成と性質2008
Author(s)
新田展大, 東浦大二郎, 末次裕太, 池上崇久, 石田英晃, 御厨正博, 半田真
Organizer
2008年日本化学会西日本大会
Place of Presentation
長崎大学(長崎市)
Year and Date
2008-11-15
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