| Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
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| Research Abstract |
Molybdenum(VI)-oxo, -sulfido, and -selenido complexes were prepared. Upon oxidizing oxomolybdenum(IV) complexes electrochemically or chemically in the presence of water, six-coordinate dioxomolybdenum(VI) complexes having one oxo group derived from the water molecule were prepared. Additionally, sulfido-, and selenido-molybdenum(VI) complexes were prepared from its silanolate derivative and the hydrogensulfide or hydrogenselenide. The effects of the terminal sulfido and selenido groups on the atom transfer reactivity and electronic structures were examined.
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