| Project/Area Number |
20550079
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Kochi University |
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Principal Investigator |
UEDA Tadaharu Kochi University, 教育研究部・総合科学系, 准教授 (50294822)
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| Co-Investigator(Kenkyū-buntansha) |
KOTSUKI Hiyoshizo 高知大学, 副学長 (80093954)
YONEMURA Toshiaki 高知大学, 教育研究部総合科学系, 教授 (90240382)
ONDA Ayumu 高知大学, 教育研究部総合科学系, 助教 (80335918)
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| Research Collaborator |
BOND Alan M. モナッシュ大学, 化学科, 教授
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥3,250,000 (Direct Cost: ¥2,500,000、Indirect Cost: ¥750,000)
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| Keywords | 金属サレン錯体 / 有機ハロゲン化物 / 脱ハロゲン化反応 / 電気化学 / シミュレーション / 化学センサー |
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| Research Abstract |
The final purpose of this project is the development of electrochemical determination for halogenated organic compounds, most of which are very toxic. In order to achieve the purpose, we have mainly carried out two types of experiments as follows: 1) Voltammetric behavior of metal complexes with various salen ligands was investigated to elucidate the effect of lithium ion and relationship between ligand type and redox potential. 2) The reaction of electrogenerated metal(I)-salen complexes with halogenated organic compounds was examined with various electrochemical measurements to find out that the light irradiation on the surface of electrode accelerate de-haloganation reaction
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