| Project/Area Number |
20550089
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Analytical chemistry
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| Research Institution | Konan University |
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Principal Investigator |
CHAYAMA Kenji Konan University, 理工学部, 教授 (10188493)
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| Co-Investigator(Renkei-kenkyūsha) |
WATSUKI Satoshi 甲南大学, 理工学部, 准教授 (80373033)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 貴金属イオン / ポリチオエーテル誘導体 / 温度感応性高分子 / 下限臨界共溶温度 / 銀(I)イオン / チオエーテル誘導体 / 溶媒抽出 / モノアザジチオエーテル / 金属イオン捕集 / 錯形成反応 |
|---|
| Research Abstract |
Novel temperature-responsive copolymers of N-isopropylacrylamide and monoaza-poly-thioether derivative, were synthesized for the selective extraction of soft metal ions such as silver (I), copper (I), gold (III) and palladium (II) ion. Metal ion extraction using the copolymer with appropriate counter anions such as picrate ion, nitrate or perchlorate ion was examined. Soft metal ions such as silver (I), copper (I), gold (III) and palladium (II) ion were extracted selectively into the solid polymer phase. The extraction efficiency of a metal ion such as silver ion increased as the increase of the ratio of the monoaza-tetrathioether group to N-isopropylacrylamide group in the polymer. The quantitative extraction of class b metal ions as well as the liquid-liquid extraction of metal ions with monoaza-tetrathioether molecule was performed.
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