Research in novel catalyses using dinuclear allyl and propargyl complexes

• Project/Area Number: 20550091
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Synthetic chemistry
• Research Institution: Shizuoka University
• Principal Investigator: TSUKADA Naofumi Shizuoka University, 理学部, 准教授 (70292240)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
• Keywords: パラジウム / 白金 / 二核錯体 / アリル化合物 / プロパルギル化合物 / プロパルギル化号物 / 触媒反応 / 銅

Research Abstract

Several new allyl palladium and platinum complexes having chelate bridging ligands were synthesized and utilized as catalyst for novel transformation of organic compounds. We found that the dinuclear allyl complexes exhibited different selectivity from mononuclear complexes in the cross-coupling of phenylboric acid and allyl compounds, and developed a novel method for preparation of tetrahydrofuranes from carbonyl compounds and isobutenes having two leaving groups.

Research Products

• [Journal Article] Hydrocarboxylation of unactivated internal alkynes with carboxylic acids catalyzed by dinuclear palladium complexes (2011)
  • Author(s): Naofumi Tsukada, Atsushi Takahashi, Yoshio Inoue
  • Journal Title: Tetrahedron Letters Vol.52, No.2 Pages: 248-250
  • NAID: 120002851899
  • Peer Reviewed
• [Journal Article] Hydrocarboxylation of unactivated internal alkynes with carboxylic acidscatalyzed by dinuclear palladium complexes (2011)
  • Author(s): Naofumi Tsukada, Atsushi Takahashi, Yoshio Inoue
  • Journal Title: Tetrahedron Letters Volume: 52 Pages: 248-250
  • Peer Reviewed
• [Journal Article] Synthesis of dinuclear palladium complexes having two parallel isocyanide ligands, and their application as catalysts to pyrrole formation from tert-butylisocyanide and alkynes (2009)
  • Author(s): Naofumi Tsukada, Makiko Wada, Naoki Takahashi, Yoshio Inoue
  • Journal Title: Journal of Organometallic Chmistry Vol.694, No.9-10 Pages: 1333-1338
  • NAID: 120001794372
  • Peer Reviewed
• [Journal Article] Synthesis of dinuclear palladium complexes having two parallel isocyanide ligands, and their application as catalysts to pyrrole for mation from tert-butylisooyanide and alkynes (2009)
  • Author(s): Naofumi Tsukada, Makiko Wada, Naoki Takahashi, Yoshio Inoue
  • Journal Title: Journal of Organometallie Chemistry 694 Pages: 1333-1338
  • Peer Reviewed
• [Presentation] 薗頭カップリング反応におけるパラジウム銅複核錯体の触媒作用 (2011)
  • Author(s): 大田哲平、塚田直史
  • Organizer: 日本化学会第91春季年会(3PA-183P)
  • Place of Presentation: 神奈川大学横浜キャンパス
  • Year and Date: 2011-03-28
• [Presentation] 新規架橋配位子を用いた銅触媒によるアリールハライドのエーテル化反応 (2011)
  • Author(s): 中恨宇之、塚田直史
  • Organizer: 日本化学会第91春季年会(3PA-187P)
  • Place of Presentation: 神奈川大学横浜キャンパス
  • Year and Date: 2011-03-28
• [Presentation] 薗頭カップリング反応におけるパラジウム銅複核錯体の触媒作用 (2011)
  • Author(s): 大田哲平、塚田直史
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 神奈川大学(神奈川県)
  • Year and Date: 2011-03-28
• [Presentation] パラジウム触媒によるシリルアセチレンとアルキルアセチレンの酸化的カップリング反応 (2010)
  • Author(s): 佐藤俊介、塚田直史
  • Organizer: 日本化学会第90春季年会(3F2-29A)
  • Place of Presentation: 近畿大学東大阪キャンパス
  • Year and Date: 2010-03-28
• [Presentation] 新規架橋配位子による二核π-アリルパラジウム錯体の合成とその触媒作用 (2010)
  • Author(s): 山口優、塚田直史
  • Organizer: 日本化学会第90春季年会(3PA-022P)
  • Place of Presentation: 近畿大学東大阪キャンバス
  • Year and Date: 2010-03-28
• [Presentation] 新規架橋配位子による二核π-アリルパラジウム錯体の合成とその触媒作用 (2010)
  • Author(s): 塚田直史
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学
  • Year and Date: 2010-03-28
• [Presentation] パラジウム銅二核錯体触媒を用いたヨウ化アリールのアミノ化反応 (2009)
  • Author(s): 塚田直史、高橋総子、大西希、松本直樹、井上祥雄
  • Organizer: 第56回有機金属化学討論会(P2A-07)
  • Place of Presentation: 同志社大学今出川キャンパス
  • Year and Date: 2009-09-10
• [Presentation] 銅パラジウムニ核錯体触媒によるアリールハライドのアミノ化反応 (2009)
  • Author(s): 大西希、松本直樹、塚田直史, 井上祥雄
  • Organizer: 日本化学会第89回春季年会(4F1-44A)
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2009-03-30
• [Presentation] 二核パラジウム錯体触媒を用いた末端アルキンによるエンインの環化反応 (2009)
  • Author(s): 青山淑未、塚田直史、井上祥雄
  • Organizer: 日本化学会第89回春季年会(3F1-28A)
  • Place of Presentation: 日本大学理工学部船橋キャンパス
  • Year and Date: 2009-03-29
• [Remarks]
  • URL: http://www.ipc.shizuoka.ac.jp/~sntsuka/