| Project/Area Number |
20550117
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Polymer chemistry
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| Research Institution | Japan Atomic Energy Agency |
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Principal Investigator |
HASEGAWA Shin Japan Atomic Energy Agency, 量子ビーム応用研究部門, 研究員 (60354940)
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| Co-Investigator(Kenkyū-buntansha) |
MAEKAWA Yasunari 独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 研究主幹 (30354939)
榎本 一之 独立行政法人日本原子力研究開発機構, 量子ビーム応用研究部門, 博士研究員 (50465978)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥3,770,000 (Direct Cost: ¥2,900,000、Indirect Cost: ¥870,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
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| Keywords | 機能性高分子 / 放射線 / グラフト重合 / 燃料電池 / 長寿命ラジカル / フッ素モノマー / 電解質膜 / リビングラジカル重合 |
|---|
| Research Abstract |
For synthesis of polymer electrolyte membrane (PEM) that can be applied to fuel cells for mobile electricity in vehicles, as well as a domestic co-generation system, radiation-induced graft polymerization is a convenient method to introduce directly graft chains with proton conductivity into fluorine polymer. A superior durable PEM which introduced fluorine vinyl monomer into polymer films can be obtained by using both long-term radicals by irradiation for graft polymerization and stable radicals for living radical polymerization.
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