| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥2,860,000 (Direct Cost: ¥2,200,000、Indirect Cost: ¥660,000)
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| Research Abstract |
In order to realize strong interaction between conducting electrons and localized spins in molecular conductors mainly based on the TTF system, we have been carrying out the preparation of TTF-ligands which have the coordination sites to paramagnetic metal ions, and the studies of physical properties of the metal complexes based on the TTF-ligands. From TTF-ligands with the Schiff base type coordination sites, we succeeded in the development of molecular system in which electron conduction and magnetic property coexisted, and those with redox properties showing spin-crossover phenomena. On the other hand, pyrazol-type TTF-ligands gave multinuclear metal complexes which showed a single molecular magnet behavior at very low temperature.
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