Chemical Expansion of the Cavities of Fullerenes by Organic Reactions
| Project/Area Number |
20550122
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Nagoya University |
|---|
Principal Investigator |
IWAMATSU Sho-ichi Nagoya University, 環境学研究科, 准教授 (60345866)
|
|---|
| Project Period (FY) |
2008 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
|---|
| Keywords | 分子認識 / 超分子化学 / ナノ材料 / ナノチューブ・フラーレン |
|---|
| Research Abstract |
This research focuses on expansion of the limited cavities of fullerenes by building cylindrical π-electronic walls onto the top of open-cage C_<60> derivatives. Alkylation reactions of methylene hydrogen atoms on the rims of open-cage fullerenes allow to introduce alkyl substituents as potential components for the extension. It has been found that substituents effect on the rates of incorporations/releases of the guests. The reactions of an open-cage C_<60> with hydroxyl amines afford ketoxime derivatives as new starting materials for further transformations.
|
Report
(4 results)
Research Products
(13 results)
