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Spatio-temporally developed phenomena by introducing anisotropy of chemical reaction fields and nonequilibrium conditions

Research Project

Project/Area Number 20550124
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials chemistry
Research InstitutionHiroshima University

Principal Investigator

NAKATA Satoshi  Hiroshima University, 大学院・理学研究科, 教授 (50217741)

Co-Investigator(Kenkyū-buntansha) KITAHATA Hiroyuki  千葉大学, 大学院・理学研究科, 准教授 (20378532)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords非線形 / 界面 / 非平衡 / 自律運動 / 自己組織化 / 時空間発展 / 振動 / 表面張力 / 非綿形 / 時空間発展現象 / 異方性 / 自律系 / 膜
Research Abstract

Our purpose of this research is to clarify the mechanism of spatio-temporally developed phenomena at an immiscible interface under the anisotropic and nonequilibrium conditions. Actually, we investigated a change in the mode of self-motion was investigated for a camphor disk on water upon the addition of sulfate surfactants with alkyl chains of different lengths as a simple autonomous system. With an increase in the concentration of surfactant with a longer alkyl chain, two mode changes (continuous -> intermittent oscillatory -> no motion) were observed. With an increase in the concentration of surfactant with a shorter alkyl chain, four mode changes (continuous -> oscillatory -> continuous -> oscillatory -> no motion) were observed. These two types of mode changes are discussed in relation to the solubility of the surfactant and camphor in the water phase and the surface tension of the surfactant, camphor, and a mixture of surfactant and camphor as the driving force of motion. We also examined (1) the relati ship between mode-switching and synchronization, (2) mode-change depending on the external environment, and (3) rate balance between reaction and diffusion system.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (55 results)

All 2011 2010 2009 2008 Other

All Journal Article (36 results) (of which Peer Reviewed: 36 results) Presentation (11 results) Book (4 results) Remarks (4 results)

  • [Journal Article] Interactions between sex hormones and 1 1,2-di-o-myristoyl-sn-glycero-3-phospho choline monolayer : Characteristics of the liposome, surface area versus surface pressure of the monolayer, and microscopic observation2011

    • Author(s)
      S.Nakata, A.Ikeguchi, T.Shiota, R.Komori, N.Kumazawa, M.Tsutsumi, M.Denda
    • Journal Title

      Bulletin Chemical Society of Japan 84

      Pages: 283-289

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Interactions between sex hormones and a 1,2-di-O-myristoyl-sn-glycero-3-phosphocholine molecular layer : Characteristics of the liposome, Surface area versus surface pressure of the monolayer, and microscopic observation2011

    • Author(s)
      H.Kitahata, K.Kawata, S.Takahashi, M.Nakamura, Y.Sumino, S.Nakata
    • Journal Title

      Bulletin of the Chemical Society of Japan

      Volume: 84(印刷中) Pages: 7-7

    • NAID

      10028046236

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Phase Wave Between Two Oscillators in the Photosensitive Belousov-Zhabotinsky Reaction Depending on the Difference in the Illumination Time2010

    • Author(s)
      S.Nakata, K.Kashima, H.Kitahata, Y.Mori
    • Journal Title

      Journal of Physical Chemistry A 114

      Pages: 9124-9129

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synchronized motion of the water surfaces around two fixed camphor disks2010

    • Author(s)
      H.Kitahata, K.Kawata, S.Takahashi, M.Nakamura, Y.Sumino, S.Nakata
    • Journal Title

      Journal of Colloid and Interface Science 351

      Pages: 299-303

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-motion of a benzoquinone disk coupled with a redox reaction2010

    • Author(s)
      N.J.Suematsu, Y.Miyahara, Y.Matsuda, S.Nakata
    • Journal Title

      Journal of Physical Chemistry C 114

      Pages: 13340-13343

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Collective behavior of inanimate boats2010

    • Author(s)
      N.J.Suematsu, S.Nakata, A.Awazu, H.Nishimori
    • Journal Title

      Phys. Rev. E 81

      Pages: 56210-56210

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mode-switching of the self-motion of a camphor boat depending on the diffusion distance of camphor molecules2010

    • Author(s)
      N.J.Suematsu, Y.Ikura, M.Nagayama, H.Kitahata, N.Kawagishi, M.Murakami, S.Nakata
    • Journal Title

      Journal of Physical Chemistry C 114

      Pages: 9876-9882

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Apex of a V-shaped cut field acts as a pacemaker on an oscillatory system2010

    • Author(s)
      I.N.Motoike, S.Nakata, Y.Iguchi, K.K.Takemura, K.Hayashi, K.Yoshikawa
    • Journal Title

      Chem. Phys. Lett. 490

      Pages: 238-241

    • NAID

      120002224060

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Distinguishing among gases with a semiconductor sensor depending on the frequency modulation of a cyclic temperature2010

    • Author(s)
      S.Nakata, K.Kashima
    • Journal Title

      Electroanalysis 22

      Pages: 1573-1580

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Experimental and theoretical studies on the self-motion of a phenanthroline disk coupled with complex formation2010

    • Author(s)
      K.Iida, N.J.Suematsu, Y.Miyahara, H.Kitahata, M.Nagayama, S.Nakata
    • Journal Title

      Physical Chemistry Chemical Physics 12

      Pages: 1557-1563

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-motion of a camphor disk on an aqueous phase depending on the alkyl chain length of sulfate surfactants2010

    • Author(s)
      S.Nakata, M.Murakami
    • Journal Title

      Langmuir 26

      Pages: 2414-2417

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mathematical analysis of intercellular calcium propagation induced by ATP2010

    • Author(s)
      M.Tsutsumi, H.Kitahata, S.Nakata, Y.Sanno, M.Nagayama, M.Denda
    • Journal Title

      Skin Research Technology 16

      Pages: 146-150

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Phase wave between two oscillators in the photosensitive Belousov-Zhabotinsky reaction depending on the difference in the illumination time2010

    • Author(s)
      S.Nakata, K.Kashima, H.Kitahata, Y.Mori
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 114 Pages: 9124-9129

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Collective behavior of inanimate boats2010

    • Author(s)
      N.J.Suematsu, S.Nakata, A.Awazu, H.Nishimori
    • Journal Title

      Physical Review E

      Volume: 81

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-motion of a benzoquinone disk coupled with a redox reaction2010

    • Author(s)
      N.J.Suematsu, Y Miyahara, Y Matsuda, S.Nakata
    • Journal Title

      The Journal of Physical Chemistry A

      Volume: 114 Pages: 13340-13343

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mode-switching of the self-motion of a camphor boat depending on the diffusion distance of camphor molecules2010

    • Author(s)
      N.J.Suematsu, Y Ikura, M.Nagayama, H.Kitahata, N.Kawagishi, M.Murakami, S.Nakata
    • Journal Title

      The Journal of Physical Chemistry C

      Volume: 114 Pages: 9876-9882

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mathematical analysis of intercellular calcium propagation induced by adenosine triphosphate2010

    • Author(s)
      M.Tsutsumi, H.Kitahata, S.Nakata, Y Sanno, M.Nagayama, M.Denda
    • Journal Title

      Skin Research and Technology

      Volume: 16 Pages: 146-150

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Distinguishing Among Gases with a Semiconductor Sensor Depending on the Frequency Modulation of a Cyclic Temperature2010

    • Author(s)
      S.Nakata, K.Kashima
    • Journal Title

      Electroanalysis

      Volume: 16 Pages: 146-150

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Apex of a V-shaped cut field acts as a pacemaker on an oscillatory system2010

    • Author(s)
      I.N.Motoike, S.Nakata, Y.Iguchi, K.K.Takemura, K.Hayashi, K.Yoshikawa
    • Journal Title

      Chemical Physics Letters

      Volume: 490 Pages: 238-241

    • NAID

      120002224060

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synchronized motion of the water surfaces around two fixed camphor disks2010

    • Author(s)
      H.Kitahata, K.Kawata, S.Takahashi, M.Nakamura, Y.Sumino, S.Nakata
    • Journal Title

      Journal of Colloid and Interface Science

      Volume: 351 Pages: 299-303

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-Motion of a Camphor Disk on an Aqueous Phase Depending on the Alkyl Chain Length of Sulfate Surfactants2010

    • Author(s)
      S.Nakata, M.Murakami
    • Journal Title

      Langmuir 26

      Pages: 2414-2417

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Spontaneous deformation of an oil droplet induced by the cooperative transport of cationic and anionic surfactants through the interface2009

    • Author(s)
      Y.Sumino, H.Kitahata, H.Seto, S.Nakata, K.Yoshikawa
    • Journal Title

      Journal of Physical Chemistry B 113

      Pages: 15709-15714

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oscillation in penetration distance in a train of chemical pulses propagating in an optically-constrained narrowing channel2009

    • Author(s)
      H.Kitahata, K.Fujio, J.Gorecki, S.Nakata, Y.Igarashi, A.Gorecka, K.Yoshikawa
    • Journal Title

      Journal of Physical Chemistry A 113

      Pages: 10405-10409

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Intermittent motion of a camphor float depending on the nature of the float surface on water2009

    • Author(s)
      S.Nakata, N.Kawagishi, M.Murakami, N.J Suematsu, M.Nakamura
    • Journal Title

      Colloids and Surfaces A 349

      Pages: 74-77

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Arnold tongue of electrochemical nonlinear oscillators2009

    • Author(s)
      S.Nakata, K.Miyazaki, S.Izuhara, H.Yamaoka, D.Tanaka
    • Journal Title

      Journal of Physical Chemistry A 113

      Pages: 6876-6879

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] A liquid/liquid interface excited by stimulation with water2009

    • Author(s)
      S.Nakata, K.Ishibashi, K.Kawata, Y.Sumino, S.Nakanishi, K.Sonoda
    • Journal Title

      Journal of Colloid and Interface Science 332

      Pages: 254-257

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Wave Propagation in the Photosensitive Belousov-Zhabotinsky Reaction across an Asymmetric Gap2009

    • Author(s)
      T.Ichino, K.Fujio, M.Matsushita, S.Nakata
    • Journal Title

      Journal of Physical Chemistry A 113

      Pages: 2304-2308

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Bifurcation of self-motion depending on the reaction order2009

    • Author(s)
      M.Nagayama, M.Yadome, M.Murakami, N.Kato, J.Kirisaka, S.Nakata
    • Journal Title

      Physical Chemistry Chemical Physics 11

      Pages: 1085-1090

    • NAID

      120001249805

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Chemical sensing with dynamical nonlinear information2009

    • Author(s)
      S.Nakata, S.Izuhara, K.Masui, M.R.Islam
    • Journal Title

      International Journal of Unconventional Computing 5

      Pages: 39-52

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Arnold Tongue of Electrochemical Nonlinear Oscillators2009

    • Author(s)
      S.Nakata, K.Miyazaki, S.Izuhara, H.Yamaoka, D.Tanaka
    • Journal Title

      The Journal of Physical Chemistry A 113

      Pages: 6876-6879

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Wave Propagation in the Photosensitive Belousov-Zhabotinsky Reaction Across an Asymmetric Gap2009

    • Author(s)
      T.Ichino, K.Fujio, M.Matsushita, S.Nakata
    • Journal Title

      The Journal of Physical Chemistry A 113

      Pages: 2304-2308

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Bifurcation of self-motion depending on the reaction order2009

    • Author(s)
      M. Nagayama, M. Yadome, M. Murakami, N. Kato, J. Kirisaka, S. Nakata
    • Journal Title

      Physical Chemistry Chemical Physics 11

      Pages: 1085-1090

    • NAID

      120001249805

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A liquid/liquid interface excited by stimulation with water2009

    • Author(s)
      S. Nakata, K. Ishibashi, K. Kawata, Y. Sumino, S. Nakanishi, K. Sonoda
    • Journal Title

      Journal of Colloid and Interface Science 332

      Pages: 254-257

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Self-motion of a phenanthroline disk on divalent metalion aqueous solutions coupled with complex formation2008

    • Author(s)
      S.Nakata, Y.Arima
    • Journal Title

      Colloids and Surfaces A 324

      Pages: 222-227

    • NAID

      120001092486

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oscillation of a water surface in contact with a fixed camphor disk2008

    • Author(s)
      H.Kitahata, K.Kawata, Y.Sumino, S.Nakata
    • Journal Title

      Chemical Physics Letters 457

      Pages: 254-258

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Self-motion of a phenanthroline disk on divalent metal ion aqueous solutions coupled with complex formation2008

    • Author(s)
      S. Nakata, Y. Arima
    • Journal Title

      Colloids and Surfaces A 324

      Pages: 222-227

    • NAID

      120001092486

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] ステロイド-リン脂質混合単分子膜における表面圧の特徴的変化2011

    • Author(s)
      塩田考矢・中田聡・熊澤紀之・傳田光洋
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2011-03-28
    • Related Report
      2010 Annual Research Report
  • [Presentation] SDS水相上で自律運動する樟脳船2011

    • Author(s)
      中田聡、末松信彦、松田唯
    • Organizer
      第91日本化学会春季年会2D2-30
    • Place of Presentation
      神奈川大学、横浜
    • Year and Date
      2011-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] 光照射による自律運動モードの制御2011

    • Author(s)
      松田唯・中田聡・末松J.信彦
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] 円形反応場を伝播する化学反応波の集団が形成する疎密波2011

    • Author(s)
      末松J.信彦・佐藤太亮・元池N.育子・中田聡
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] SDS水相上で自律運動する樟脳船2011

    • Author(s)
      中田聡・末松J.信彦・松田唯
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Ru触媒を用いたBZ反応系の光興奮2011

    • Author(s)
      佐藤太亮・中田聡・北畑裕之・末松J.信彦・雨宮隆・森義仁
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      神奈川大学(横浜)
    • Year and Date
      2011-03-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Coupling of reactiondiffusion and self-motion under nonequilibrium conditions2010

    • Author(s)
      中田聡
    • Organizer
      Pacifichem 2010
    • Place of Presentation
      Hawaii, USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Final Research Report
  • [Presentation] 界面活性剤に依存した自律運動のモードスイッチング2010

    • Author(s)
      中田聡、村上舞
    • Organizer
      日本化学会春季年会4E2-13
    • Place of Presentation
      近畿大学、東大阪
    • Year and Date
      2010-03-29
    • Related Report
      2010 Final Research Report
  • [Presentation] 界面活性剤に依存した自律運動のモードスイッチング2010

    • Author(s)
      中田聡, 村上舞
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学 (東大阪)
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] 樟脳浮きの振動運動2009

    • Author(s)
      中田聡、末松信彦、村上舞、川岸奈央
    • Organizer
      日本化学会第89春季年会2E6-49
    • Place of Presentation
      日大理工、船橋
    • Year and Date
      2009-03-28
    • Related Report
      2010 Final Research Report
  • [Presentation] 樟脳浮きの振動運動2009

    • Author(s)
      中田 聡
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(船橋、千葉)
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Book] 生き物のように振る舞う無生物の数理科学2011

    • Author(s)
      中田聡
    • Total Pages
      7
    • Publisher
      数学セミナー8月号
    • Related Report
      2010 Annual Research Report
  • [Book] 自己組織化ハンドブック(反応-拡散-対流の結合による自律系のスイッチング)(NTS、国武豊喜 監修、NTS)2009

    • Author(s)
      中田聡、北畑裕之
    • Related Report
      2010 Final Research Report
  • [Book] よみがえれ!科学者魂(丸善)2009

    • Author(s)
      佐々木聰、雨宮隆、鴨下顕彦、露本伊佐男、中田聡
    • Related Report
      2010 Final Research Report
  • [Book] 「反応―拡散―対流の結合による自律系のスイッチング」、自己組織化ハンドブック2009

    • Author(s)
      中田聡, 北畑裕之
    • Total Pages
      4
    • Publisher
      株式会社エヌ・ティー・エス
    • Related Report
      2009 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://www.mls.sci.hiroshima-u.ac.jp/bukkan/nakata.htm

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.mls.sci.hiroshima-u.ac.jp/bukkan/nakata.htm

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.mls.sci.hiroshima-u.ac.jp/bukkan/index_j.html

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.mls.sci.hiroshima-u.ac.jp/bukkan/index_j.html

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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