Construction of novel organosupramolecular system using properties of nitrogen containing heterocyclic metal complexes
| Project/Area Number |
20550125
|
|---|
| Research Category |
Grant-in-Aid for Scientific Research (C)
|
| Allocation Type | Single-year Grants |
|---|
| Section | 一般 |
|---|
| Research Field |
Functional materials chemistry
|
|---|
| Research Institution | Kyushu University |
|---|
Principal Investigator |
KAWATO Toshio Kyushu University, 大学院・理学研究院, 名誉教授 (40038477)
|
|---|
| Co-Investigator(Kenkyū-buntansha) |
ITO Yoshio 九州大学, 大学院・理学研究院, 准教授 (00221086)
ITOH Kennosuke 信州大学, 工学部, 助教 (40467874)
|
|---|
| Project Period (FY) |
2008 – 2010
|
| Project Status |
Completed (Fiscal Year 2010)
|
| Budget Amount *help |
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
|
|---|
| Keywords | 構造有機化学 / ピラジン / ポルフィリン / フラーレン / 分子認識 / 超分子 / 電子移動システム / ビピリジン / 光電子移動システム |
|---|
| Research Abstract |
Novel supramolecular structures utilizing the characteristic of heteroaromatic compounds such as pyrazine were constructed. At the first stage of the study, a new type of reaction for 2,3,5,6-tetrakis(chloromethyl)pyrazine was developed to yield 2,6-diformyl-substituted pyrazine, which was derived to a new porphyrin compound. Metal complexation of the pyrazine ligand and a 4,4'-bipyridine analogue was successfully achieved. Resultant metal complexes as well as the new ligands were found to trap fullerenes effectively.
|
Report
(4 results)
Research Products
(13 results)
