Solid-state NMR in an Ultra High Magnetic Field and its application to local structure in materials.

• Project/Area Number: 20550132
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Functional materials chemistry
• Research Institution: National Institute for Materials Science
• Principal Investigator: SHIMIZU Tadashi National Institute for Materials Science, ナノ計測センター, グループリーダー (00354366)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000); Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000); Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
• Keywords: NMR / 強磁場 / 多核NMR / 構造解析 / 触媒 / 固体NMR / 四極子核

Research Abstract

The nuclei of more than 60% elements are quadrupolar nuclei which have NMR resolution much poorer than the dipolar NMR. High-magnetic-field is the only way to improve the resolution of solid-state quadrupolar NMR, because the line broadening due to quadrupole effect disappears in a high-magnetic-field. The higher magnetic field we have, the more elements we can study.

Research Products

• [Journal Article] NMR property of sodalite loaded with potassium (2010)
  • Author(s): Mutsuo Igarashi, Takehito Nakano, GOTO Atsushi, HASHI Kenjiro, SHIMIZU Tadash, Atsufumi Hanazawa, Yasuo Nozue
  • Journal Title: Journal of Physics and Chemistry of Solids 71 Pages: 638-641
  • Peer Reviewed
• [Journal Article] Solid-state ^<95>Mo NMR of mixed-valence polyoxomolybdates (V, VI) with localized or delocalized d^1 electrons (2010)
  • Author(s): Takahiro Iijima, Toshihiro Yamase, Masataka Tansho, Tadashi Shimizu, Katsuyuki Nishimura
  • Journal Title: Chemical Physics Letters 487 Pages: 232-236
  • Peer Reviewed
• [Journal Article] 11B-11B two dimensional correlation nuclear magnetic resonance on sodium borosilicate glass (2010)
  • Author(s): Murakami Miwa, SHIMIZU Tadashi, TANSHO Masataka, AKAI Tomoko, YAZAWA Tetsuo
  • Journal Title: CHEMISTRY LETTERS Vol.39, No.1 Pages: 32-33
  • NAID: 10027176371
  • Peer Reviewed
• [Journal Article] ^<10>B and ^<11>B high-resolution NMR studies on boron-doped diamond (2010)
  • Author(s): M.Murakami, et.al.
  • Journal Title: Physics C Volume: 470
  • Peer Reviewed
• [Journal Article] Solid-state 95Mo NMR of mixed-valence polyoxomolybdates (2010)
  • Author(s): T.Iijima, etl.al.
  • Journal Title: Chemical Physics Letters Volume: 487 Pages: 232-236
  • Peer Reviewed
• [Journal Article] NMR Property of sodalite loaded with potassium (2010)
  • Author(s): M.Igarashi, et.al.
  • Journal Title: J.Phys.Chem.Solids Volume: 71 Pages: 638-641
  • Peer Reviewed
• [Journal Article] High-Resolution Solid-State NMR Studies of Natural Abundant 15N Observed in Halogen-Bridged One-Dimensional Complexes, [NiX(chxn)2]X2 and [Pd(chxn)2][PdX2(chxn)2]Y4 (chxn=(1R,2R)-yclohexane ; Y=X (Halogen), NO3, and ClO4) (2009)
  • Author(s): Noriyoshi Kimura, Tadashi Shimizu, Ryuichi Ikeda
  • Journal Title: Bull.Chem.Soc.Jpn. Vol.82, No.6 Pages: 704-708
  • Peer Reviewed
• [Journal Article] Improvement of 1H-2H cross polarization under magic-angle spinning by using amplitude/frequency modulation (2009)
  • Author(s): MURAKAMI Miwa, SHIMIZU Tadashi, TANSHO Masataka, TAKEGOSHI Kiyonori
  • Journal Title: SOLID STATE NUCLEAR MAGNETIC RESONANCE Vol.36, No.4 Pages: 172-176
  • Peer Reviewed
• [Journal Article] Mesoporous Silica/Polymer Composites Utilizing Intelligent Caps onto Mesopore Walls toward Practical Low-Dielectric Materials (2009)
  • Author(s): Shosuke Kiba, Yoshinori Okawauchi, Takeshi Yanagihara, Miwa MURAKAMI, Tadashi Shimizu, Yusuke YAMAUCHI
  • Journal Title: CHEMISTRY-AN ASIAN JOURNAL Vol.4, No 12 Pages: 1798-1801
  • Peer Reviewed
• [Journal Article] 10B/11B1D/2D solid-state high-resolution NMR studies on boron-doped diamond (2009)
  • Author(s): Miwa MURAKAMI, Tadashi Shimizu, Masataka TANSHO, Yoshihiko TAKANO, Satoshi ISHII, Evgeni A.Ekimov, Vladmir Sidorov, Kiyonori TAKEGOSHI
  • Journal Title: DIAMOND AND RELATED MATERIALS Vol.18, No.10 Pages: 1267-1273
  • Peer Reviewed
• [Journal Article] Aerosol-Assisted Synthesis of Mesoporous Organosilica Microspheres with Controlled Organic Contents (2009)
  • Author(s): Yusuke YAMAUCHI, Norihiro SUZUKI, Gupta Prashant, Keisuke SATO, Naoki FUKATA, Miwa MURAKAMI, Tadashi Shimizu, Satoru INOUE, Tatsuo Kimura
  • Journal Title: SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS Vol.10, No.2
  • Peer Reviewed
• [Journal Article] Active Mercury(II) Ion Removal : Stoichiometrically Controlled Thiol-Functionalized Mesoporous Silica by a Mass Production Spray Dry System (2009)
  • Author(s): Yusuke Yamauchi, Norihiro Suzuki, Keisuke Sato, Naoki Fukata, Miwa Murakami, Tadashi Shimizu
  • Journal Title: Bull.Chem.Soc.Jpn. Vol.82, No.8 Pages: 1039-1043
  • NAID: 10025127328
  • Peer Reviewed
• [Journal Article] Stacking of Bacteriochlorophyll c Macrocycles in Chlorosome from Chlorobium limicola As Revealed by Intermolecular 13C Magnetic-Dipole Correlation, X-Ray Diffraction, and Quadrupole Coupling in 25Mg NMR (2009)
  • Author(s): Y.Kakitani, Y.Koyama, Y.Shimoikeda, T.Nakai, H.Utsumi, T.Shimizu, H.Nagae
  • Journal Title: Biochemistry 48 Pages: 74-86
  • Peer Reviewed
• [Journal Article] Intra-and Intermolecular Effects on 1H Chemical Shifts in a Silk Model Peptide Determined by High-Field Solid State 1H NMR and Empirical Calculations (2009)
  • Author(s): Yu Suzuki, Rui Takahashi, Tadashi Shimizu, Masataka Tansho, Kazuo Yamauchi, Mike P.Williamson, Tetsuo Asakura
  • Journal Title: J.Phys.Chem.B 113 Pages: 9756-9761
  • Peer Reviewed
• [Journal Article] Improvement of 1H-2H cross polarization under magic-angle spinning by using amplitude/frequency modulation (2009)
  • Author(s): Miwa Murakami
  • Journal Title: SOLID STATE NUCLEAR MAGNETIC RESONANCE 36 Pages: 172-176
  • Peer Reviewed
• [Journal Article] ^<11>B-^<11>B two-dimensional correlation nuclear magnetic resonance on sodium borosilicate glass (2009)
  • Author(s): Miwa Murakami
  • Journal Title: CHEMISTRY LETTERS 39 Pages: 32-33
  • Peer Reviewed
• [Journal Article] 強磁場固体NMRによるチーグラー・ナッタ触媒の構造解析 (2008)
  • Author(s): 齋藤雅由、清水禎
  • Journal Title: 次世代ポリオレフィン総合研究 Vol.2 Pages: 39-39
  • Peer Reviewed
• [Journal Article] 11B nuclear magnetic resonance in boron-doped diamond (2008)
  • Author(s): Miwa MURAKAMI, Tadashi Shimizu, Masataka TANSHO, Yoshihiko TAKANO
  • Journal Title: SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS Vol.9, No.4
  • Peer Reviewed
• [Journal Article] NMR study of YbAl3C3 in high magnetic field (2008)
  • Author(s): Satoru Tomisawa, Takeshi Mito, Shinji Wada, Kenjiro Hashi, Tadashi Shimizu, Atsushi Goto, Shinobu Ohki, Yoshiaki Kato, Masashi Kosaka
  • Journal Title: J.Phys.Soc.Jpn. 77 Pages: 291-293
  • Peer Reviewed
• [Journal Article] High field 17O solid-state NMR study of alanine tripeptides (2008)
  • Author(s): Kazuo.Yamauchi, Michi.Okonogi, Hiromichi Kurosu, Masataka Tansho, Tadashi Shimizu, Terry Gullion, Tetsuo Asakura
  • Journal Title: Journal of Magnetic Resonance 190 Pages: 327-332
  • Peer Reviewed
• [Journal Article] One-Dimensional Bromo-Bridged NiIII Complexes [Ni(S,S-bn)2Br]Br2 (S,S-bn=2S,3S-diaminobutane): Synthesis, Physical Properties, and Electrostatic Carrier Doping/One-Dimensional Bromo-Bridged NiIII Complexes [Ni(S,S-bn)_2Br]Br_2 (S,S-bn=2S,3S-diaminobutane): Synthesis, Physical Properties, and Electrostatic Carrier Doping (2008)
  • Author(s): S.Takaishi, M.Yamashita, H.Matsuzaki, H.Okamoto, H.Tanaka, S.Kuroda, A.Goto, T.SHIMIZU, T.Takenobu, Y.Iwasa
  • Journal Title: CHEMISTRY-A EUROPEAN JOURNAL 472477 Pages: 14-2
  • Peer Reviewed
• [Journal Article] High field ^<17>O solid-state NMR study of alanine tripeptides (2008)
  • Author(s): K.Yamauchi, M.Okanogi, H.Kurosu, T.Shimizu, T, Asakura
  • Journal Title: Journal of Magnetic Resonance 190 Pages: 327-332
  • Peer Reviewed
• [Journal Article] 強磁場固体NMRによるチーグラー・ナッタ触媒の構造解析 (2008)
  • Author(s): 齋藤雅由
  • Journal Title: 次世代ポリオレフィン総合研究 Vol. 2 Pages: 39-43
  • Peer Reviewed
• [Journal Article] NMR study of YbAl_3C_3 in high magnetic field NMR study of YbAl_3C_3 in high magnetic field (2008)
  • Author(s): Satoshi Tomizawa
  • Journal Title: JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN 77(Suppl. A.) Pages: 291-293
  • Peer Reviewed
• [Journal Article] Characterization of boron-doped diamonds using ^<11>B high-resolution NMR at high magnetic fields (2008)
  • Author(s): Miwa Murakami
  • Journal Title: DIAMOND AND RELATED MATERIALS 17 Pages: 1835-1839
  • Peer Reviewed
• [Journal Article] Fullerene as a Standard Sample for Adjusting the NMR Spectral Resolution in Multiple-Quantum Magic Angle Spinning Experiments (2007)
  • Author(s): Yuichi SHIMOIKEDA, Hiroaki UTSUMI, Koji SAITO, Tadashi Shimizu, Toshihito NAKAI
  • Journal Title: ANALYTICAL SCIENCES AUGUST VOL.23 Pages: 1007-1007
  • NAID: 10019747799
  • Peer Reviewed
• [Presentation] 固体NMR緩和時間測定によるチーグラー・ナッタ固体触媒中の電子供与体の分子運動性 (2010)
  • Author(s): 斉藤雅由, ほか
  • Organizer: 第59回高分子討論会
  • Place of Presentation: 北海道大学(北海道)
• [Presentation] 47Ti,49TiのNMR～強磁場固体NMRによるチーグラー・ナッタ触媒の構造解析 (2009)
  • Author(s): 齋藤雅由,藤田孝,清水禎,出口健三,中井利仁,内海博明
  • Organizer: NMR研究会
  • Place of Presentation: 東京工業大学(東京)
  • Year and Date: 2009-10-15
• [Presentation] Application of ^<11>B/^<14>N MAS NMR on mesoporous BCN and BN (2009)
  • Author(s): Miwa Murakami
  • Organizer: 49^<th> ENC (Experimental NMR Conference)
  • Place of Presentation: Asikimar Conference Grounds, Pacific Grove, California, 米国
  • Year and Date: 2009-04-17
• [Presentation] 強磁場固体NMRによるチーグラー・ナッタ触媒の構造解析 (2008)
  • Author(s): 齋藤雅由,藤田孝,清水禎,出口健三,内海博明,中井利仁
  • Organizer: イノベーションつくば2008
  • Place of Presentation: つくば国際会議場(つくば市)
  • Year and Date: 2008-11-16
• [Presentation] 多重パルスと待ち時間を用いたリンギングの抑制 (2008)
  • Author(s): 大橋竜太郎
  • Organizer: NMR討論会
  • Place of Presentation: つくば市、筑波大学
  • Year and Date: 2008-11-12
• [Presentation] 多孔質BCN系における^<11>B-^<14>Nの交差分極法とHETCORの応用 (2008)
  • Author(s): 村上美和
  • Organizer: NMR討論会
  • Place of Presentation: つくば市、筑波大学
  • Year and Date: 2008-11-12
• [Presentation] 強磁場固体NMRによるチーグラー・ナッタ固体触媒中の構造解析 (2008)
  • Author(s): 齋藤雅由,清水禎,出口健三,内海博明,中井利仁
  • Organizer: 第57回高分子討論会
  • Place of Presentation: 大阪市立大学 杉本キャンパス(大阪市)
  • Year and Date: 2008-10-17
• [Presentation] アルカリ金属を吸着したソダライトのNMR (2008)
  • Author(s): 五十嵐睦夫
  • Organizer: 日本物理学会
  • Place of Presentation: 盛岡市、岩手大学
  • Year and Date: 2008-09-20
• [Presentation] 強磁場固体NMRによるチーグラー・ナッタ触媒の構造解析 (2008)
  • Author(s): 齋藤雅由
  • Organizer: 高分子学会
  • Place of Presentation: 横浜市、パシフィコ横浜
  • Year and Date: 2008-05-28
• [Remarks] 平成22年度触媒工業協会技術賞受賞「強磁場固体NMRによるチグラー・ナッタ触媒の構造解析)
• [Patent(Industrial Property Rights)] 密封式MAS試料管 (2009)
  • Inventor(s): 清水禎、品川秀行、大木忍
  • Industrial Property Rights Holder: (独)物質・材料研究機構
  • Industrial Property Number: 2009-242932
  • Filing Date: 2009-10-22
• [Patent(Industrial Property Rights)] 磁気共鳴装置 (2009)
  • Inventor(s): 清水禎
  • Industrial Property Rights Holder: (独)物質・材料研究機構
  • Industrial Property Number: 2009-138073
  • Filing Date: 2009-06-09
• [Patent(Industrial Property Rights)] 超伝導磁石用シミング装置 (2009)
  • Inventor(s): 清水禎、端健二郎、木田、
  • Industrial Property Rights Holder: (独)物質・材料研究機構
  • Industrial Property Number: 2009-158687
  • Filing Date: 2009-07-03
• [Patent(Industrial Property Rights)] プローブへの液状試料取り付け方法と液状試料容器 (2008)
  • Inventor(s): 品川秀行, 清水禎, 大木忍, 藤戸輝昭
  • Industrial Property Rights Holder: (独)物質・材料研究機構
  • Industrial Property Number: 2008-191549
  • Filing Date: 2008-07-25