Solid-state NMR in an Ultra High Magnetic Field and its application to local structure in materials.
Project/Area Number |
20550132
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Research Category |
Grant-in-Aid for Scientific Research (C)
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Allocation Type | Single-year Grants |
Section | 一般 |
Research Field |
Functional materials chemistry
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Research Institution | National Institute for Materials Science |
Principal Investigator |
SHIMIZU Tadashi National Institute for Materials Science, ナノ計測センター, グループリーダー (00354366)
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Project Period (FY) |
2008 – 2010
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Project Status |
Completed (Fiscal Year 2010)
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Budget Amount *help |
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
Fiscal Year 2008: ¥1,820,000 (Direct Cost: ¥1,400,000、Indirect Cost: ¥420,000)
|
Keywords | NMR / 強磁場 / 多核NMR / 構造解析 / 触媒 / 固体NMR / 四極子核 |
Research Abstract |
The nuclei of more than 60% elements are quadrupolar nuclei which have NMR resolution much poorer than the dipolar NMR. High-magnetic-field is the only way to improve the resolution of solid-state quadrupolar NMR, because the line broadening due to quadrupole effect disappears in a high-magnetic-field. The higher magnetic field we have, the more elements we can study.
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Report
(4 results)
Research Products
(40 results)
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[Journal Article] One-Dimensional Bromo-Bridged NiIII Complexes [Ni(S,S-bn)2Br]Br2 (S,S-bn=2S,3S-diaminobutane): Synthesis, Physical Properties, and Electrostatic Carrier Doping/One-Dimensional Bromo-Bridged NiIII Complexes [Ni(S,S-bn)_2Br]Br_2 (S,S-bn=2S,3S-diaminobutane): Synthesis, Physical Properties, and Electrostatic Carrier Doping2008
Author(s)
S.Takaishi, M.Yamashita, H.Matsuzaki, H.Okamoto, H.Tanaka, S.Kuroda, A.Goto, T.SHIMIZU, T.Takenobu, Y.Iwasa
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Journal Title
CHEMISTRY-A EUROPEAN JOURNAL 472477
Pages: 14-2
Related Report
Peer Reviewed
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