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Elucidation and application of the functional expression mechanism of the environment-oriented mutifunctional hybrid complex

Research Project

Project/Area Number 20550138
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Environmental chemistry
Research InstitutionKochi University

Principal Investigator

YONEMURA Toshiaki  Kochi University, 教育研究部・総合科学系, 教授 (90240382)

Co-Investigator(Kenkyū-buntansha) OZAWA Tomohiro  名古屋工業大学, 工学研究科, 准教授 (70270999)
UEDA Tadaharuueda  高知大学, 教育研究部総合科系, 准教授 (50294822)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,810,000 (Direct Cost: ¥3,700,000、Indirect Cost: ¥1,110,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Keywords環境対応 / 複合材料 / 物性 / 合成化学 / イオン結晶 / 複合材料・物性 / 複合材料・特性
Research Abstract

From the results of this research, it is obvious that the stereoselectivity of the dinuclear complexes to generate due to the redox ability of the complexes, and further the stereoselectivity of the polynuclear complexes were also changed by that reason. It is clarified that the polynuclear complexes having different structures were formed stereoselectively by a reaction at various ratio of the complex ion or mononuclear complex with thiocarboxylic acid. We were able to get the knowledge concerning the contribution to antimicrobe or antifungus activity. There is no examination treating such stereoselectivity so far, and it is thought that it is very significant results were obtained from the viewpoint of stereo control and function.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (37 results)

All 2011 2010 2009 2008

All Journal Article (13 results) (of which Peer Reviewed: 9 results) Presentation (24 results)

  • [Journal Article] Pentaaquatri-μ_3-hydroxido-tris (imin odiacetato)-μ_3-oxido-tetrahedrocalc ium (II) tricobalt (III) 2.54-hydrate2010

    • Author(s)
      T.Ama, T.Yonemura, S.Morita, M.Yamaguchi
    • Journal Title

      Acta Cryst. E66

    • Related Report
      2010 Final Research Report
  • [Journal Article] Nitrile hydration by Co (III) complex with oxygenated S atoms inserted into mesoporous silica2010

    • Author(s)
      T.Ozawa, T.Shibayama, T.Yano, Y.Funahashi, H.Masuda
    • Journal Title

      Jpn.J.Appl.Phys. 50

    • NAID

      210000138283

    • Related Report
      2010 Final Research Report
  • [Journal Article] Pentaaquatri-μ3-hydroxido-tris(iminodiacetato)-μ3-oxido-tetrahedrocalcium (II)tricobalt(III) 2.54-hydrate2010

    • Author(s)
      T.Ama, T.Yonemura, S.Morita, M.Yamaguchi
    • Journal Title

      Acta Cryst.

      Volume: E66 Pages: 483-484

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Crystal structure of a mixed metal compound cross-linked by 2-ethynylpyridine, [PtRu_3(μ4-η^1:η^2:η^2-C≡CPy-κN)(η^1-C≡CPy)(CO)_9(PMe_2Ph)_2]2010

    • Author(s)
      S.Yamazaki, T.Yonemura
    • Journal Title

      Anal.Sci.: X-Ray Struct.Anal.Online

      Volume: 26 Pages: 47-48

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A square-planar Ni(II) complex with an asymmetric N2S2 donor set as a model for the active site of nickel-containing SOD : Structural conversion driven by addition of a strong donor ligand in the high oxidation state2010

    • Author(s)
      D.Nakane, Y.Funahashi, T.Ozawa, H.Masuda
    • Journal Title

      Chem.Lett.

      Volume: 39 Pages: 344-346

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A square-planar Ni(II) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxidew2010

    • Author(s)
      D.Nakane, S.Kuwasako, M.Tsuge, M.Kubo, Y.Funahashi, T.Ozawa, T.Ogura H.Masuda
    • Journal Title

      Chem.Commun.

      Volume: 46 Pages: 2142-2144

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nitrile hydration by Co(III) complex with oxygenated S atoms inserted into mesoporous silica2010

    • Author(s)
      T.Ozawa, T.Shibayama, T.Yano, Y.Funahashi, H.Masuda
    • Journal Title

      Jpn.J.Appl.Phys.

      Volume: 50

    • NAID

      210000138283

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Square-planar Ni(II)Complex with an Asymmetric N_2S_2 Donor Set as a Model for the Active Site of Nickel-containing SOD : Structural Conversion Driven by Addition of a Strong Donor Ligand in the High Oxidation State2010

    • Author(s)
      D.Nakane, 他
    • Journal Title

      Chem.Lett. 29

      Pages: 344-346

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] trans-(Pyrimidine-2-thiolato-K^2-N, S) [tris (2-aminoethy1) amine-k^4-N, N', N'', N''')] Cobalt (III) Chloride Hexafluoridophospate2009

    • Author(s)
      T.Yonemura, K.Fujihara
    • Journal Title

      Acta Cryst. E65

    • Related Report
      2010 Final Research Report
  • [Journal Article] trans-(Pyrimidine-2-thiolato-κ^2-N,5)[tris(2-aminoethyl)amine-κ^4-N,N',N'',N''')]Cobalt(III)Chloride Hexafluoridophospate2009

    • Author(s)
      T.Yonemura, 他
    • Journal Title

      Acta Cryst. E65

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Nitrosyl tris(Pyridine-2-thiolato-κ^2-N,S)Molybdenum(II)Dihydrate2009

    • Author(s)
      T.Yonemura
    • Journal Title

      Acta Cryst. E65

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of an N_3S_2-type Ni(II)Complex Directed to NiSOD Active Site and Its Structural, Electrochemical, and Spectroscopic Properties2009

    • Author(s)
      D.Nakane, 他
    • Journal Title

      Trans.Mater.Res.Soc.Jpn. 34

      Pages: 513-516

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Release of NO from cis(NO,NO)-trans(N,S)Isomer of Dinitrosyl-Molybdenum Complexes with 4,6-dimethyl-2-pyrimidinethiolate2009

    • Author(s)
      T.Yonemura
    • Journal Title

      J.Biol.Inorg.Chem. 14

    • Related Report
      2009 Annual Research Report
  • [Presentation] 銀-コバルト混合錯体の形成に及ぼす芳香族チオラト配位子の影響(1)2011

    • Author(s)
      矢倉輝祥, 石ヶ休正樹, 松本健司, 小澤智宏, 米村俊昭
    • Organizer
      日本化学会第91春季年会,日本化学会第91春季年会(2011)講演予稿集
    • Year and Date
      2011-03-11
    • Related Report
      2010 Final Research Report
  • [Presentation] 銀-コバルト混合錯体の形成に及ぼす芳香族チオラト配位子の影響(1)2011

    • Author(s)
      矢倉輝祥, 石ヶ休正樹, 松本健司, 小澤智宏, 米村俊昭
    • Organizer
      日本化学会第91春季年会
    • Place of Presentation
      日本化学会第91春季年会(2011)(講演予稿集)
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report
  • [Presentation] Investigation of Superoxide Reduction Mechanism in NiSOD Using Ni(II)-N_2S_2 Type Complexes2011

    • Author(s)
      D.Nakane, T.Inomata, Y.Funahashi, T.Ozawa, H.Masuda
    • Organizer
      ISPlasma2011
    • Place of Presentation
      名古屋工業大学(愛知)
    • Year and Date
      2011-03-08
    • Related Report
      2010 Annual Research Report
  • [Presentation] 一酸化窒素高選択性を示すN2S2型コバルト(III)錯体の構築とその金電極への修飾2010

    • Author(s)
      小澤智宏・鶴留大介・矢野卓真・舩橋靖博・猪股智彦・増田秀樹
    • Organizer
      第20回日本MRS学術シンポジウム
    • Place of Presentation
      横浜市開港記念会館(神奈川)
    • Year and Date
      2010-12-21
    • Related Report
      2010 Annual Research Report
  • [Presentation] Application of Co-Ag dodecanuclear thiolato complexes toward eco-friendly type antimicrobial agent2010

    • Author(s)
      米村俊昭
    • Organizer
      International Chemical Congress of Pacific Basin
    • Place of Presentation
      米国
    • Year and Date
      2010-12-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Application of Co-Ag dodecanuclear thiolato complexes toward eco-friendly type antimicrobial agent2010

    • Author(s)
      T.Yonemura
    • Organizer
      International Chemical Congress of Pacific Basin
    • Place of Presentation
      Hawaii(米国)
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] 三脚型配位子を含むコバルト(III)錯体の集積化に及ぼす芳香族チオラト配位子の影響2010

    • Author(s)
      藤原啓介, 小澤智宏, 米村俊昭
    • Organizer
      日本化学会西日本大会
    • Place of Presentation
      熊本大学(熊本)
    • Year and Date
      2010-11-06
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Stereoselective Syntheses, Properties, and Reaction of Cobalt (III) Complexes Containing 2-Meracaptopyrimidine Derivatives2010

    • Author(s)
      K.Fujihara, R. Inoue, K. Matsumoto, T.Yonemura
    • Organizer
      The 60th Anniversary Conference on Coordination Chemistry in Osaka
    • Place of Presentation
      大阪国際交流センター(大阪)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Stereoselective Syntheses, Properties, and Reaction of Cobalt(III) Complexes Containing 2-Meracaptopyrimidine Derivatives2010

    • Author(s)
      K.Fujihara, R.Inoue, K.Matsumoto, T.Yonemura
    • Organizer
      The 60th Anniversary Conference on Coordination Chemistry in Osaka
    • Place of Presentation
      大阪国際交流センター(大阪)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Reactivity and Selectivity for Nitric Oxide using Fe(III) complexes with N_2O_2-type coordination environment2010

    • Author(s)
      T.Ozawa, T.Suwabe, T.Inomata, Y.Funahashi, H.Masuda
    • Organizer
      The 60th Anniversary Conference on Coordination Chemistry in Osaka
    • Place of Presentation
      大阪国際交流センター(大阪)
    • Year and Date
      2010-09-27
    • Related Report
      2010 Annual Research Report
  • [Presentation] Construction of N2S2-type Co(III) complexes with High Selectivity for Nitric Oxide and their Application to NO Sensing Electrode2010

    • Author(s)
      T.Ozawa, D.Tsurudome, T.Yano, T.Inomata, Y.Funahashi, H.Masuda
    • Organizer
      The 6th World Congress of Biomechanics
    • Place of Presentation
      Suntec(シンガポール)
    • Year and Date
      2010-08-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] NO Release Reaction of Dinitrosyl-Molybdenum Complexes with 2-Pyrimidinethiolate Derivatives2010

    • Author(s)
      T.Yonemura
    • Organizer
      The 6th International Conference on the Biology, Chemistry, and Therapeutic Applications of Nitric Oxide
    • Place of Presentation
      京都国際会館(京都)
    • Year and Date
      2010-06-15
    • Related Report
      2010 Annual Research Report
  • [Presentation] N_2S_2型配位環境を有するNO高選択性コバルト錯体の構築とその電極表面修飾2010

    • Author(s)
      小澤智宏・鶴留大介・矢野卓真・猪股智彦・舩橋靖博・増田秀樹
    • Organizer
      ナノ学会第8回大会
    • Place of Presentation
      分子科学研究所(愛知)
    • Year and Date
      2010-05-13
    • Related Report
      2010 Annual Research Report
  • [Presentation] 三脚型配位子を含むコバルト(III)錯体の集積化に及ぼすチオラト配位子の影響2009

    • Author(s)
      藤原啓介・小澤智宏・米村俊昭
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学(長崎)
    • Year and Date
      2009-09-25
    • Related Report
      2010 Final Research Report 2009 Annual Research Report
  • [Presentation] Role of Sulfenate Coordination in Nitrile Hydratase through a Model Complex Chemistry2009

    • Author(s)
      T.Ozawa
    • Organizer
      14th International Conference on Biological Inorganic Chemistry
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2009-07-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] Release of NO from cis(NO,NO)-trans(N,S)Isomer of Dinitrosyl-Molybdenum Complexes with 4,6-dimethyl-2-pyrimidinethiolate2009

    • Author(s)
      T.Yonemura
    • Organizer
      14th International Conference on Biological Inorganic Chemistry
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2009-07-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Spectroscopic and Electrochemical Studies on Influences of Hydrogen Bonding in NiSOD Active Center2009

    • Author(s)
      中根大輔, 他
    • Organizer
      14th International Conference on Biological Inorganic Chemistry
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2009-07-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] NiSODの第2配位圏における静電的相互作用が活性中心に与える影響への一考察2009

    • Author(s)
      中根大輔, 他
    • Organizer
      第59回錯体化学討論会
    • Place of Presentation
      長崎大学(長崎)
    • Year and Date
      2009-07-26
    • Related Report
      2009 Annual Research Report
  • [Presentation] Photodecarboxylation Reaction of Thiocarboxylato Coblt Complexes to form a Co-S-CH_2 Three-Membered Chelate Ligand2009

    • Author(s)
      米村俊昭
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds
    • Place of Presentation
      ガトーキングダムト札幌(北海道)
    • Year and Date
      2009-07-06
    • Related Report
      2010 Final Research Report
  • [Presentation] Photodecarboxylation Reaction of Thiocarboxylato Cobalt Complexes to form a Co-S-CH_2 Three-Membered Chelate Ligand2009

    • Author(s)
      T.Yonemura
    • Organizer
      18th International Symposium on the Photochemistry and Photophysics of Coordination Compounds
    • Place of Presentation
      ガトーキングダム札幌(北海道)
    • Year and Date
      2009-07-06
    • Related Report
      2009 Annual Research Report
  • [Presentation] チオシアヌル酸を配位子にもつジニトロシルモリブデン錯体の合成と反応2009

    • Author(s)
      小川奈津美, 池野卓, 米村俊昭, 阿万智治
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学(千葉)
    • Year and Date
      2009-03-28
    • Related Report
      2008 Annual Research Report
  • [Presentation] Selective NO sensing Materials Similar to the Active site of Nitrile Hydratase2008

    • Author(s)
      T. Ozawa, T. Yano, T. Inomata, H. Masuda
    • Organizer
      The IUMRS international Conference in Asia 2008
    • Place of Presentation
      名古屋国際会議場(愛知)
    • Year and Date
      2008-12-11
    • Related Report
      2008 Annual Research Report
  • [Presentation] Preparation of Co (III) complexes with a high selectivity for NO sensing2008

    • Author(s)
      T.Ozawa, T.Yano, T.Inomata, H.Masuda
    • Organizer
      Pacific RIM Meeting on Electrochemical and Solid-State Science 2008
    • Place of Presentation
      米国
    • Year and Date
      2008-10-15
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation of Co(III) complexes with a high selectivity for NO sensing2008

    • Author(s)
      T. Ozawa, T. Yano, T. Inomata, H. Masuda
    • Organizer
      Pacific RIM Meeting on Electrochemical and Solid-State Science 2008
    • Place of Presentation
      ハワイ(米国)
    • Year and Date
      2008-10-15
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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