Dehalogenation of Aryl halides mediated by macrocyclic metal complex catalysts.
| Project/Area Number |
20550139
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Environmental chemistry
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| Research Institution | Yokohama City University |
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Principal Investigator |
MOTIDUKI Katura Yokohama City University, 生命ナノシステム科学研究科, 教授 (60150562)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥5,330,000 (Direct Cost: ¥4,100,000、Indirect Cost: ¥1,230,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2008: ¥4,030,000 (Direct Cost: ¥3,100,000、Indirect Cost: ¥930,000)
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| Keywords | 環状配位子 / 金属錯体 / 脱ハロゲン化 / 触媒 |
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| Research Abstract |
We have synthesized some new macrocyclic metal complexes, which have been applied for the studies on metal-mediated dehalogenation of arly halides. In the course of this study, we have developed a new photochemical system for debromination of aryl bromides mediated by nickel(II) complexes with macrocyclic ligands.
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Report
(4 results)
Research Products
(31 results)
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[Journal Article] Synthesis of {15-benzyloxy-3,7,11,17- tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene} nickel(II) perchlorate and its analogs, and their catalytic behavior in reductive debromination of 1-bromo-4-tert-butylbenzene2010
Author(s)
Mochizuki K., Sugita T., Kuroiwa S., Yamada F., Hayano K., Ohgami Y., Suzuki M., Kato S.
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Journal Title
Inorg. Chim. Acta 363
Pages: 3151-3157
Related Report
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[Journal Article] Synthesis of {15-benzyloxy-3,7,11,17-tetraazabicyclo[11.3.1]heptadeca-1(17),13,15-triene} nickel(II) perchlorate and its analogs, and their catalytic behavior in reductive debromination of 1-bromo-4-tert-butylbenzene2010
Author(s)
Mochizuki K., Sugita T., Kuroiwa S., Yamada F., Hayano K., Ohgami Y., Suzuki M., Kato S
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Journal Title
Inorg.Chim.Acta
Volume: 363
Pages: 3151-3157
Related Report
Peer Reviewed
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[Journal Article] New bis(macrocyclic) dinickel(II) complexes obtained by oxidation of bis(5,7-dimethyl- 1,4,8,11-tetraazacyclotetradeca- 4,7-dien-6- yl)dinickel(II) perchlorate2009
Author(s)
Mochizuki K., Sugita T., Yamada F., Mochizuki N., Hayano K., Ohgami Y.
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Journal Title
Inorg. Chim. Acta 362(4)
Pages: 1204-1208
Related Report
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[Journal Article] New bis (macrocyclic) dinickel (II) complexes obtained by oxidation of bis (5, 7-dimethyl-1, 4, 8, 11-tetraazacyclotetradeca-4, 7-dien-6-yl) dinickel (II) perchlorate2009
Author(s)
Mochizuki K., Sugita T., Yamada F., Mochizuki N., Hayano K., Ohgami Y.
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Journal Title
Inorg. Chim. Ada 362
Pages: 1204-1208
Related Report
Peer Reviewed
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