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Preparation of semiconducting block copolymers for controll of domain orientation

Research Project

Project/Area Number 20550160
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Functional materials/Devices
Research InstitutionTokyo University of Agriculture and Technology

Principal Investigator

OGINO Kenji  Tokyo University of Agriculture and Technology, 大学院・工学研究院, 教授 (10251589)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥650,000 (Direct Cost: ¥500,000、Indirect Cost: ¥150,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥3,510,000 (Direct Cost: ¥2,700,000、Indirect Cost: ¥810,000)
Keywordsブロック共重合体 / ミクロ相分離 / ラメラ / 光電変換素子 / 垂直配向 / 有機半導体 / 自己組織性 / ブレンド薄膜 / 形態制御 / ポリスチレン / ポリチオフェン / 光電変換効率 / 溶媒アニール / 熱アニール / シリンダー / 光電変換 / トリアリールアミン
Research Abstract

The conversion efficiency of organic solar cells strongly depends on the morphology of the composites. In this study, in order to controll the morphology and the orientation of phase separated each domain, novel methodology utilizing block copolymers consisting of regioregular poly (3-hexylthiophene) (P3HT) and electrically inert polymer. The film morphology of the composites of block copolymers with fullerene derivative was strongly dependent on the nature of inert block. P3HT-b-polystyrene composite showed distinct and larger domain compared with P3HT/PCBM. On the other hand, P3HT-b-poly (ethylene oxide) showed smaller size of regular phase separated structure.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (37 results)

All 2011 2010 2009 2008 2000 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (23 results) Remarks (4 results)

  • [Journal Article] Annealing Effect on Performance and Morphology of Photovoltaic Devices Based on Poly (3-hexylthiophene)-b-Poly (ethylene oxide)2011

    • Author(s)
      Zhijie Gu, Tatsuya Kanto, Kousuke Tsuchiya, Takeshi Shimomura, Kenji Ogino
    • Journal Title

      J.Polym.Sci.Part-A : Polym.Chem. 49

      Pages: 2645-2652

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis and Characterization of Poly(3-hexyl- thiophene)-b-Polystyrene for Photo- voltaic Application2011

    • Author(s)
      Zhijie Gu, Ying Tan, Kousuke Tsuchiya, Takeshi Shimomura, Kenji Ogino
    • Journal Title

      Polymers 3

      Pages: 558-570

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2010

    • Author(s)
      Zhijie Gu, Tatsuya Kanto, Kousuke Tsuchiya, Kenji Ogino
    • Journal Title

      J.Photopolym.Sci.Technol. 23

      Pages: 405-406

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Poly(3-hexylthiophene)-b-poly(ethylene oxide) for Application to Photovoltaic Device2010

    • Author(s)
      Zhijie Gu
    • Journal Title

      J.Photopolym.Sci.Technol.

      Volume: 23 Pages: 405-406

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Poly(4-diphenylaminostyrene) with a well-defined polymer chain structure : Controllable optical and electrical properties2010

    • Author(s)
      Itaru Natori
    • Journal Title

      Polymer

      Volume: 51 Pages: 1501-1506

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of bipolar charge transporting block copolymers and characterization for organic light-emitting diodes2010

    • Author(s)
      Kousuke Tsuchiya
    • Journal Title

      J.Polym.Sci.Part A : Polym.Chem.

      Volume: 48 Pages: 1461-1468

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Diblock Copolymer Based on Poly(4-n-butyl- triphenylamine) via Palladium Coupling Polymerization2009

    • Author(s)
      Kousuke Tsuchiya, Takeshi Shimomura, Kenji Ogino
    • Journal Title

      Polymer 50

      Pages: 95-101

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of C-60 end-capped poly(4-diphenylaminostyrene) : Addition of poly(4-diphenylaminostyryl)lithium to C-602009

    • Author(s)
      Itaru Natori
    • Journal Title

      Reactive & Functional Polymers 69

      Pages: 613-618

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of diblock copolymer based on poly (4-n-buty1triphenylamine) via palladium coupling polymerization2009

    • Author(s)
      Kousuke Tsuchiya
    • Journal Title

      Polymer 50

      Pages: 95-101

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Conformation-Related Exciton Localization and Charge-Pair Formation in Polythiophenes : Ensemble and Single-Molecule Study2000

    • Author(s)
      Toshikazu Sugimoto
    • Journal Title

      Journal of Physical Chemistry B 113

      Pages: 12220-12226

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Presentation] 相分離型太陽電池を指向したブロック共重合体の合成および機能評価2011

    • Author(s)
      坂倉嵩、土屋康佑、荻野賢司
    • Organizer
      平成23年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2010 Final Research Report
  • [Presentation] 光電変換素子を指向したチオフェン系ブロック共重合体の合成と評価2011

    • Author(s)
      安藤健次、土屋康佑、荻野賢司
    • Organizer
      第60回高分子学会年次大会
    • Place of Presentation
      大阪国際会議場(大阪)
    • Related Report
      2010 Final Research Report
  • [Presentation] トリフェニルアミンを有する半導体ポリマーからなるブロックコポリマーの合成と物性評価2010

    • Author(s)
      坂倉嵩、土屋康佑、荻野賢司
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(札幌)
    • Related Report
      2010 Final Research Report
  • [Presentation] ブロックコポリマーブレンドを用いた有機薄膜光電変換素子のモルフォロジー制御2010

    • Author(s)
      土屋康佑、関東達也、ソギン マリ、荻野賢司
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道大学高等教育機能開発総合センター(札幌)
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis of Poly(3-hexylthiophene)-block-Polystyrene and Characterization of Its Morphology in Thin Film2010

    • Author(s)
      Zhijie Gu, Kousuke Tsuchiya, Kenji Ogino
    • Organizer
      International Conference on Science and Technology of Synthetic Metals 2010 (ICSM 2010)
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis of Poly(3-hexylthiophene)-b-poly(ethylene oxide) for Application to Photovoltaic Device2010

    • Author(s)
      Zhijie Gu, Tatsuya Kanto, Kousuke Tsuchiya, Kenji Ogino
    • Organizer
      27th International Conference of Photopolymer Science and Technology
    • Place of Presentation
      Chiba, Japan
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリチオフェンブロック共重合-を用いた有機薄膜光電変換素子の評価2010

    • Author(s)
      関東達也、谷志杰、土屋康佑、荻野賢司
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      パシフィコ横浜(横浜)
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis of Poly(3-hexylthiophene)-block-Polystyrene and Characterization of Its Morphology in Thin Film2010

    • Author(s)
      Zhijie Gu
    • Organizer
      International Conference on Science and Tee hnology of Synthetic Metals 2010
    • Place of Presentation
      Kyoto, Japan
    • Related Report
      2010 Annual Research Report
  • [Presentation] ペリレンジイミドを含むブロック共重合体の合成と物性評価2010

    • Author(s)
      市倉祥太
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜・パシフィコ横浜
    • Related Report
      2010 Annual Research Report
  • [Presentation] トリフェニルアミンを主鎖骨指に有する共役ポリマーの合成と物性評価2010

    • Author(s)
      土屋康佑
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜・パシフィコ横浜
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリチオフェンブロック共重合〓を用いた有機薄膜光電変換素子の評価2010

    • Author(s)
      関東達也
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜・パシフィコ横浜
    • Related Report
      2010 Annual Research Report
  • [Presentation] ブロックコポリマーブレンドを用いた有機薄膜光電変換素子のモルフォロジー制御2010

    • Author(s)
      土屋康佑
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      北海道・北海道大学
    • Related Report
      2010 Annual Research Report
  • [Presentation] ポリパラフェニレンを有する新規ブロック共重合体の精密合成および特性の評価2009

    • Author(s)
      関川博之
    • Organizer
      第58回高分子討論会
    • Place of Presentation
      熊本・熊本大学
    • Year and Date
      2009-09-15
    • Related Report
      2009 Annual Research Report
  • [Presentation] 機能性ブロックコポリマーブレンドの相分離構造を利用した光電変換デバイスの開発2009

    • Author(s)
      土屋康佑
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      東京・船堀タワーホール
    • Year and Date
      2009-06-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] ポリスチレン-block-ポリトリフェニルアミンの合成2009

    • Author(s)
      菊池達朗
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      東京・船堀タワーホール
    • Year and Date
      2009-06-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Synthesis and characterization of poly(3-hexyl- thiophene)-block-polystyrene for photovoltaic device2009

    • Author(s)
      Z.Gu, K.Tsuchiya, K.Ogino
    • Organizer
      The 4th International Conference on Advanced Fibers and Polymer Materials (ICAFPM2009)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2010 Final Research Report
  • [Presentation] 機能性ブロックコポリマーブレンドの相分離構造を利用した光電変換デバイスの開発2009

    • Author(s)
      土屋康佑, 飯野匠太, 関東達也, 荻野賢司
    • Organizer
      平成21年度繊維学会年次大会
    • Place of Presentation
      タワーホール船堀(東京)
    • Related Report
      2010 Final Research Report
  • [Presentation] Synthesis and characterization of poly(3-hexylthiophene)-block-polystyrene for photovoltaic device2009

    • Author(s)
      Gu Zhijie
    • Organizer
      The 4^<th> International Conference on Advanced Fibers and Polymer Materials(ICAFPM2009)
    • Place of Presentation
      Shanghai, China
    • Related Report
      2009 Annual Research Report
  • [Presentation] 触媒的酸化重合によるポリ(3-ヘキシルチオフェン)の合成2008

    • Author(s)
      土屋 康佑
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] PEO-フラーレンを用いた有機薄膜太陽電池の光電変換特性の評価2008

    • Author(s)
      飯野 匠太
    • Organizer
      第57回高分子討論会
    • Place of Presentation
      大阪市立大学杉本キャンパス
    • Year and Date
      2008-09-25
    • Related Report
      2008 Annual Research Report
  • [Presentation] ポリ(4-ブチルトリフェニルアミン)-ポリ(ニチレンオキサイド)ブロックポリマーの合成と性質2008

    • Author(s)
      藤岡 正洋
    • Organizer
      平成20年度繊維学会年次大会
    • Place of Presentation
      東京、タワーホール船堀
    • Year and Date
      2008-06-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] 片末端官能基化ポリ(4-ブチルトリフェニルアミン)を用いたジブロックコポリマーの合成2008

    • Author(s)
      上屋 康佑
    • Organizer
      平成20年度繊維学会年次大会
    • Place of Presentation
      東京、タワーホール船堀
    • Year and Date
      2008-06-18
    • Related Report
      2008 Annual Research Report
  • [Presentation] ポリ(3-ヘキシルチオフェン)-b-ポリ(エチレンオキシド)の合成と相分離構造の評価2008

    • Author(s)
      関東 達也
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜、パシフイコ横浜
    • Year and Date
      2008-05-28
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ

    • URL

      http://www.tuat.ac.jp/~oginolab/

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~oginolab/

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~oginolab/

    • Related Report
      2009 Annual Research Report
  • [Remarks]

    • URL

      http://www.tuat.ac.jp/~oginolab/

    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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