Syntheses of water-soluble phthalocyanine dyes responsible to visible-near-infrared light

• Project/Area Number: 20550170
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Organic industrial materials
• Research Institution: National Institute for Materials Science
• Principal Investigator: ISAGO Hiroaki National Institute for Materials Science, 光触媒材料センター, 主幹研究員 (40343850)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000); Fiscal Year 2008: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
• Keywords: フタロシアニン / アンチモン / 水溶性 / 近赤外 / 有機工業化学 / 機能性色素

Research Abstract

Novel water-soluble antimony (V)-phthalocyanines have been synthesized and their water-solubility and aggregation behaviors have been spectroscopically studied.

Research Products

• [Journal Article] The synthesis and spectral properties of amber phthalocyanines (2011)
  • Author(s): Hiroaki Isago, Yutaka Kagaya, Harumi Fujita, Tamotsu Sugimori
  • Journal Title: Dyes and Pigments 88巻 Pages: 187-194
  • Peer Reviewed
• [Journal Article] The synthesis and spectral properties of amber phthalocyanines (2011)
  • Author(s): 砂金宏明、加賀屋豊、藤田晴美、杉森保
  • Journal Title: Dyes and Pigments Volume: 88 Pages: 187-194
  • Peer Reviewed
• [Journal Article] (2009)
  • Author(s): Hiroaki Isago, Yutaka Kagaya
  • Journal Title: Journal of Porphyrins and Phthalocyanines 13巻 Pages: 382-389
  • Peer Reviewed
• [Journal Article] Synthesis and spectral properties of adihydroxo (phthalocyaninato) antimony(V) complex (2009)
  • Author(s): 砂金宏明、加賀屋豊
  • Journal Title: Journal of Porphyrins and Phthalocyanines 13 Pages: 382-389
  • Peer Reviewed
• [Journal Article] Synthesis and spectral properties of a dihydroxo(phthalocyaninato)antimony(V) complex (2009)
  • Author(s): 砂金宏明, 加賀屋豊
  • Journal Title: Journal of Porphyrins and Phthalocyanines 13
  • Peer Reviewed
• [Presentation] 水溶性フタロシアニン無金属体の脱プロトン化反応 (2011)
  • Author(s): 砂金宏明、藤田晴美
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 日本化学会第91春季年会(2011)(講演予稿集)
  • Year and Date: 2011-03-11
• [Presentation] ジヒドロキソ(フタロシナニナト)アンチモン(V)錯体の反応 (2011)
  • Author(s): 加賀屋豊、砂金宏明
  • Organizer: 日本化学会第91春季年会
  • Place of Presentation: 日本化学会第91春季年会(2011)(講演予稿集)
  • Year and Date: 2011-03-11
• [Presentation] Syntheses of novel water-soluble phthalocyanines and their aggregation behaviors in aqueous and non-aqueous media (2010)
  • Author(s): 砂金宏明、加賀屋豊、藤田晴美、杉森保
  • Organizer: 環太平洋化学国際会議2010
  • Place of Presentation: 米国(一般講演)
  • Year and Date: 2010-12-19
• [Presentation] Syntheses of novel water-soluble phthalocyanines and their aggregation behaviors in aqueous and non-aqueous media (2010)
  • Author(s): 砂金宏明、加賀屋豊、藤田晴美、杉森保
  • Organizer: 環太平洋化学国際会議2010
  • Place of Presentation: Hilton Hawaiian Village(米国)
  • Year and Date: 2010-12-19
• [Presentation] ジヒドロキソ(フタロシアニナト)アンチモン(V)錯体の反応 (2010)
  • Author(s): 加賀屋豊、砂金宏明
  • Organizer: 第37回有機典型元素化学討論会
  • Place of Presentation: 室蘭市民会館(北海道)
  • Year and Date: 2010-11-26
• [Presentation] Syntheses and unusual characteristics of antimony phthalocyanines (2010)
  • Author(s): 砂金宏明
  • Organizer: Thr 6^<th> International Symposium on Novel Materials and their Synthesis & the 20^<th> International Symposium on Fine Chemistry and Functional Polymers
  • Place of Presentation: 中国(招待講演)
  • Year and Date: 2010-10-11
• [Presentation] Syntheses and unusual characteristics of antimony-phthalocyanines (2010)
  • Author(s): 砂金宏明
  • Organizer: The 6th IUPAC International Symposium on Novel Materials and their Synthesis (NMS-VI) & the 20th International Symposium on Fine Chemistry and Functional Polymers (FCFP-XX)
  • Place of Presentation: South-Central University for Nationalities(中国)
  • Year and Date: 2010-10-11
• [Presentation] 水溶性フタロシアニン錯体の合成と水溶液中における会合-非会合特性 (2010)
  • Author(s): 砂金宏明、藤田晴美、杉森保
  • Organizer: 第60回錯体化学討論会
  • Place of Presentation: 大阪国際交流センター(大阪府)
  • Year and Date: 2010-09-29
• [Presentation] 琥珀色のフタロシアニン錯体の合成と性質 (2010)
  • Author(s): 砂金宏明、藤田晴美、杉森保
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス(東大阪市)
  • Year and Date: 2010-03-28
• [Presentation] ジヒドロキソ(フタロシアニナト)アンチモン(V)錯体の合成と性質 (2010)
  • Author(s): 加賀屋豊、砂金宏明、藤田晴美
  • Organizer: 日本化学会第90春季年会
  • Place of Presentation: 近畿大学本部キャンパス(東大阪市)
  • Year and Date: 2010-03-28
• [Presentation] 水溶性アンチモン(V)ーフタロシアニン錯体の合成と性質 (2009)
  • Author(s): 砂金宏明、加賀屋豊、藤田晴美、尾山洋一、杉森保
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2009-09-26
• [Presentation] ジヒドロキソ(フタロシアニナト)アンチモン(V)錯体の合成 (2009)
  • Author(s): 加賀屋豊、砂金宏明
  • Organizer: 第59回錯体化学討論会
  • Place of Presentation: 長崎大学(長崎市)
  • Year and Date: 2009-09-26
• [Presentation] アンチモン(V)フタロシアニン錯体の金属酸化物への固定化 (2009)
  • Author(s): 砂金宏明
  • Organizer: 日本化学会第89回年会
  • Place of Presentation: 日本大学理工学部
  • Year and Date: 2009-03-29
• [Presentation] テトラブトキシフタロシアニン-アンチモン錯体の合成と性質 (2008)
  • Author(s): 砂金宏明
  • Organizer: 第85錯体化学討論会
  • Place of Presentation: 金沢大学
  • Year and Date: 2008-09-21
• [Presentation] Synthesis of novel hydrophilic phthalocyanines containing antimony as the central element (2008)
  • Author(s): 砂金宏明
  • Organizer: The 5th International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: ロシア(招待講演)
  • Year and Date: 2008-07-11
• [Presentation] Synthesis of novel hydrophilic phthalocyanines containing antimony as the central element (2008)
  • Author(s): 砂金宏明
  • Organizer: The 5th International Conference on Porphyrins and Phthalocyanines
  • Place of Presentation: Moscow (Russia Science Academy)
  • Year and Date: 2008-07-11
• [Patent(Industrial Property Rights)] フタロシアニン-アンチモン(V)錯陽イオン、その塩及び塩の製造方法 (2011)
  • Inventor(s): 砂金宏明、加賀屋豊
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2011-094341
  • Filing Date: 2011-04-20
• [Patent(Industrial Property Rights)] 水溶性五価アンチモン試薬とそれを用いた抗リーシュマニア症治療薬 (2010)
  • Inventor(s): 砂金宏明、加賀屋豊、尾山洋一、藤田晴美
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2010-034421
  • Filing Date: 2010-02-19
• [Patent(Industrial Property Rights)] 水溶性フタロシアニン (2010)
  • Inventor(s): 砂金宏明、藤田晴美
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2010-013707
  • Filing Date: 2010-01-26
• [Patent(Industrial Property Rights)] 水溶性フタロシアニン色素 (2010)
  • Inventor(s): 砂金宏明、加賀屋豊、尾山洋一、藤田晴美
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2010-034421
  • Filing Date: 2010-02-24
• [Patent(Industrial Property Rights)] 水溶性フタロシアニン色素 (2010)
  • Inventor(s): 砂金宏明、加賀屋豊、尾山洋一、藤田晴美
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Filing Date: 2010-02-24
  • Overseas
• [Patent(Industrial Property Rights)] 水溶性フタロシアニン色素 (2010)
  • Inventor(s): 砂金宏明、加賀屋豊、尾山洋一、藤田晴美
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Filing Date: 2010-02-24
  • Overseas
• [Patent(Industrial Property Rights)] 水溶性フタロシアニン色素 (2009)
  • Inventor(s): 砂金宏明, 加賀屋豊, 尾山洋一藤田晴美
  • Industrial Property Rights Holder: 独立行政法人物質・材料研究機構
  • Industrial Property Number: 2009-040073
  • Filing Date: 2009-02-24