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Photocatalytic Degradation of Gaseous Chlorinated Ethanes on TiO_2 and sulfated TiO_2 -Effect of Surface Acidity and Conversion to Useful Alkenes-

Research Project

Project/Area Number 20550179
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic industrial materials
Research InstitutionYamaguchi University

Principal Investigator

YAMAZAKI Suzuko  Yamaguchi University, 大学院・理工学研究科, 教授 (80202240)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,940,000 (Direct Cost: ¥3,800,000、Indirect Cost: ¥1,140,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,730,000 (Direct Cost: ¥2,100,000、Indirect Cost: ¥630,000)
Keywords光触媒 / 反応機構 / ブレンステッド酸点 / ルイス酸点 / 有機塩素化合物 / 物質変換 / 環境材料 / 触媒・化学プロセス / 表面・界面物性 / 複合材料・物性
Research Abstract

Volatile chlorinated organic compounds (VCOCs) have been serious environmental problems because they are toxic and carcinogenic to animals. Titanium dioxide photocatalysts have been good candidates as the remediation technique for the degradation of VCOCs. However, the photocatalytic activity decreases during the photocatalytic degradation of gaseous chlorinated ethanes. This study has clarified the degradation mechanism of the chlorinated ethanes and the reason for the deactivation of the photocatalysis. Furthermore, we found that in the absence of oxygen in the reactant gas stream, the photocatalytic degradation of chlorinated ethanes formed ethylene and ethylene chloride which are useful alkenes for chemical industries. Conversion to these alkenes from the chlorinated ethanes was studied under various experimental conditions.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (9 results)

All 2010 2009 2008 Other

All Journal Article (3 results) (of which Peer Reviewed: 3 results) Presentation (5 results) Remarks (1 results)

  • [Journal Article] Photocatalytic degradation of chlorinated ethanes in the gas phase on the porous TiO_2 pellets-Effect of surface acidity-2010

    • Author(s)
      S.Yamazaki, K.Ichikawa, A.Saeki, T.Tanimura, K.Adachi
    • Journal Title

      J.Phys.Chem.A 114

      Pages: 5092-5098

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Photocatalytic Degradation of Chlorinated Ethanes in the Gas Phase on the Porous TiO 2 Pellets : Effect of Surface Acidity2010

    • Author(s)
      S.Yamazaki, et al.
    • Journal Title

      Journal of Physical Chemistry, A 114

      Pages: 5092-5098

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Effect of thermal treatment on the photocatalytic degradation of ethylene, trichloroethylene, and chloroform2009

    • Author(s)
      Suzuko Yamazaki
    • Journal Title

      Research on Chemical Intermediates 35

      Pages: 91-101

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 酸化タングステン光触媒による揮発性有機塩素化合物の分解反応2010

    • Author(s)
      山崎鈴子
    • Organizer
      光化学討論会
    • Place of Presentation
      千葉、千葉大学
    • Year and Date
      2010-09-09
    • Related Report
      2010 Final Research Report
  • [Presentation] 酸化タングステン光触媒による揮発性有機塩素化合物の分解反応2010

    • Author(s)
      山崎鈴子
    • Organizer
      2010年光化学討論会
    • Place of Presentation
      千葉大学
    • Year and Date
      2010-09-09
    • Related Report
      2010 Annual Research Report
  • [Presentation] 有機塩素化合物の光触媒反応における触媒表面上の酸点の影響2009

    • Author(s)
      山崎鈴子
    • Organizer
      光化学討論会
    • Place of Presentation
      群馬、桐生市市民文化会館
    • Year and Date
      2009-09-18
    • Related Report
      2010 Final Research Report
  • [Presentation] 有機塩素化合物の光触媒反応における触媒表面上での酸点の影響2009

    • Author(s)
      山崎鈴子, ほか
    • Organizer
      2009年光化学討論会
    • Place of Presentation
      群馬県桐生市市民文化会館
    • Year and Date
      2009-09-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] 粒子サイズをコントロールした銅担持光触媒による色素や有機塩素化合物の光触媒分解2008

    • Author(s)
      山崎鈴子
    • Organizer
      2008年光化学討論会
    • Place of Presentation
      大阪府立大学
    • Year and Date
      2008-09-11
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ等 なし

    • Related Report
      2010 Final Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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