Electrochemical Formation of Nanomultilayer Structures of Manganese Oxides Intercalated with Photofunctional Molecules
| Project/Area Number |
20550180
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| Research Category |
Grant-in-Aid for Scientific Research (C)
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| Allocation Type | Single-year Grants |
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| Section | 一般 |
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| Research Field |
Inorganic industrial materials
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| Research Institution | Yamaguchi University |
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Principal Investigator |
NAKAYAMA Masaharu Yamaguchi University, 大学院・理工学研究科, 准教授 (70274181)
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| Project Period (FY) |
2008 – 2010
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| Project Status |
Completed (Fiscal Year 2010)
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| Budget Amount *help |
¥5,070,000 (Direct Cost: ¥3,900,000、Indirect Cost: ¥1,170,000)
Fiscal Year 2010: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2009: ¥1,560,000 (Direct Cost: ¥1,200,000、Indirect Cost: ¥360,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
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| Keywords | 層状マンガン酸化物 / ポルフィリン / ルテニウムビピリジン / メチルビオロゲン / 界面活性剤 / 電析 / 光電子移動 / 反応場 / ルテニウムビピリジン錯体 / 4-アミノベンゼン / 電気化学析出法 / 薄膜 |
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| Research Abstract |
We successfully electrodeposited layered manganese oxides intercalated with photofunctional molecules (porphyrin, ruthenium bipyridine comlex), electron transfer mediator (methyl viologen), and cationic surfactants with large hydrophobic moiety. Photo irradiation to the layered manganese oxide films with photofunctional molecules did not cause a significant photocurrent. On the other hand, cationic surfactants form an organic phase which functioned as a reaction field toward catalytic oxidation of hydroquinone.
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Report
(4 results)
Research Products
(75 results)
