Budget Amount *help |
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
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Research Abstract |
Polyurethanes crosslinked by an eight-figure shaped azobis(crown ether) and a necklace shaped polyrotaxane, which consists of 12 cyclodextrins and poly(ethylene oxide), were synthesized and characterized. The polyurethane crosslinked by the eight-figure shaped bis(crown ether) showed high elongation performance because of sliding effect arisen from the rotaxane structure. Introduction of the relatively-rigid polyrotaxane as the crosslink points to the polyurethane structure resulted in keeping of the elastic performance in high temperature region.
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