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Development of Polyurethane Elastomers Crosslinked by Rotaxane and Polyrotaxane

Research Project

Project/Area Number 20550191
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Polymer/Textile materials
Research InstitutionNagasaki University

Principal Investigator

MURAKAMI Hiroto  Nagasaki University, 生産科学研究科, 助教 (30274624)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥5,200,000 (Direct Cost: ¥4,000,000、Indirect Cost: ¥1,200,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2008: ¥3,380,000 (Direct Cost: ¥2,600,000、Indirect Cost: ¥780,000)
Keywordsポリウレタン / ポリロタキサン / 架橋高分子 / ロタキサン / ネットワークポリマー
Research Abstract

Polyurethanes crosslinked by an eight-figure shaped azobis(crown ether) and a necklace shaped polyrotaxane, which consists of 12 cyclodextrins and poly(ethylene oxide), were synthesized and characterized. The polyurethane crosslinked by the eight-figure shaped bis(crown ether) showed high elongation performance because of sliding effect arisen from the rotaxane structure. Introduction of the relatively-rigid polyrotaxane as the crosslink points to the polyurethane structure resulted in keeping of the elastic performance in high temperature region.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (24 results)

All 2011 2010 2009 2008 Other

All Presentation (20 results) Remarks (4 results)

  • [Presentation] シクロデキストリン含有ポリロタキサンを架橋点にもつポリウレタンの合成と物性評価2011

    • Author(s)
      村上裕人、福島恵、小椎尾謙
    • Organizer
      日本ゴム協会九州支部事例発表会
    • Place of Presentation
      久留米
    • Year and Date
      2011-03-11
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Synthesis and Property of a Novel Polyurethane Crosslinked by a Poryrotaxane2011

    • Author(s)
      福島恵、小椎尾謙、村上裕人
    • Organizer
      Japan-Taiwan 4 Universities Joint Symposium on Material Science for Next Generation Energy and Nano Science
    • Place of Presentation
      長崎
    • Year and Date
      2011-01-20
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Synthesis and Property of a Novel Polyurethane Crosslinked by a Polyrotaxane2010

    • Author(s)
      福島恵、小椎尾謙、村上裕人
    • Organizer
      Asian Workshop on Polymer Processing in Hanoi 2010
    • Place of Presentation
      ハノイ
    • Year and Date
      2010-12-08
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] ポリロタキサンをマルチ架橋点とするポリウレタンの合成と物性評価2010

    • Author(s)
      村上裕人、福島恵、小椎尾謙
    • Organizer
      第59回高分子討論会
    • Place of Presentation
      札幌
    • Year and Date
      2010-09-16
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] ポリロタキサンを導入したポリウレタンの合成2010

    • Author(s)
      福島恵、小椎尾謙、村上裕人
    • Organizer
      第47回化学関連支部合同九州大会
    • Place of Presentation
      北九州
    • Year and Date
      2010-07-10
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] ポリロタキサン架橋ポリウレタンの合成2010

    • Author(s)
      村上裕人、福島恵、小椎尾謙
    • Organizer
      第59回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2010-05-29
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] ポリロタキサン架橋ポリウレタンの合成と物性評価2010

    • Author(s)
      村上裕人、福島恵、小椎尾謙
    • Organizer
      日本ゴム協会、2010年年次大会
    • Place of Presentation
      東京
    • Year and Date
      2010-05-20
    • Related Report
      2010 Final Research Report
  • [Presentation] ポリロタキサン架橋ポリウレタンの合成と物性評価2010

    • Author(s)
      村上裕人、福島恵、小椎尾謙
    • Organizer
      日本ゴム協会2010年年次大会
    • Place of Presentation
      東京
    • Year and Date
      2010-05-20
    • Related Report
      2010 Annual Research Report
  • [Presentation] スイッチングをキーワードにした材料開発2010

    • Author(s)
      村上裕人
    • Organizer
      プラスチック成形加工学会第102回企画員会講演会
    • Place of Presentation
      東京
    • Year and Date
      2010-03-29
    • Related Report
      2010 Final Research Report
  • [Presentation] スイッチングをキーワードにした材料開発2010

    • Author(s)
      村上裕人
    • Organizer
      プラスチック成形加工学会講演会
    • Place of Presentation
      東京
    • Year and Date
      2010-03-29
    • Related Report
      2009 Annual Research Report
  • [Presentation] Molecular Shuttles Based on Rotaxanes2009

    • Author(s)
      Hiroto Murakami
    • Organizer
      Nagasaki University and National Tsing Hua University Joint seminar on Nano material Sciences
    • Place of Presentation
      Taiwan
    • Year and Date
      2009-12-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] Molecular Shuttles Based on Rotaxanes2009

    • Author(s)
      Hiroto Murakami
    • Organizer
      Nagasaki University and National Taiwan University Joint seminar on Nano material Science
    • Place of Presentation
      Taiwan
    • Year and Date
      2009-12-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] Physical and Mechanical Properties of Polyurethanes Crosslinked by [3]Rotaxane2009

    • Author(s)
      村上裕人、草野亮介、大平慎士、古川睦久、小椎尾謙、相樂隆正
    • Organizer
      Nagasaki Symposium on Nano-Dynamics 2009
    • Place of Presentation
      長崎
    • Year and Date
      2009-01-27
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] 8字架橋ポリウレタンの物性評価2008

    • Author(s)
      村上裕人、草野亮介、大平慎士、古川睦久、小椎尾謙、相樂隆正
    • Organizer
      第16回プラスチック成形加工学会秋季大会
    • Place of Presentation
      福井
    • Year and Date
      2008-10-30
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] Thermal and Mechanical Properties of Polyurethanes Containing an Azobiscrown Compound as a Crosslink Point2008

    • Author(s)
      村上裕人、草野亮介、大平慎士、古川睦久、小椎尾謙、相樂隆正
    • Organizer
      Yamada Conference 2008 "Topological Molecules"
    • Place of Presentation
      淡路島
    • Year and Date
      2008-09-02
    • Related Report
      2010 Final Research Report
  • [Presentation] Thermal and Mechanical Properties of Polyurethanes Containing an Azobiscrown Compound as a Crosslink Point2008

    • Author(s)
      村上裕人, (他5名)
    • Organizer
      Yamada Conference 2008 “Topological Molecules"
    • Place of Presentation
      淡路島
    • Year and Date
      2008-09-02
    • Related Report
      2008 Annual Research Report
  • [Presentation] Synthesis and Physical Properties of Rotaxane Cross-linked Polyurethanes2008

    • Author(s)
      村上裕人、草野亮介、大平慎士、古川睦久、小椎尾謙、相樂隆正
    • Organizer
      The Asian Workshop on Polymer Processing 2008
    • Place of Presentation
      東京
    • Year and Date
      2008-08-29
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] Synthesis and Characterization of Novel Polyurethanes Linked via Rotaxane2008

    • Author(s)
      村上裕人、草野亮介、大平慎士、古川睦久、小椎尾謙、相樂隆正
    • Organizer
      The 10th Joint Symposium of Cheju National University and Nagasaki University on Science and Technology
    • Place of Presentation
      Cheju
    • Year and Date
      2008-06-05
    • Related Report
      2010 Final Research Report
  • [Presentation] ロタキサン架橋ポリウレタンに関する研究2008

    • Author(s)
      大平慎士、草野亮介、小椎尾謙、古川睦久、相樂隆正、村上裕人
    • Organizer
      第57回高分子学会年次大会
    • Place of Presentation
      横浜
    • Year and Date
      2008-05-29
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] ロタキサン架橋を導入したポリウレタンの合成とその物性評価2008

    • Author(s)
      村上裕人、草野亮介、大平慎士、古川睦久、小椎尾謙、相樂隆正
    • Organizer
      日本ゴム協会2008年年次大会
    • Place of Presentation
      東京
    • Year and Date
      2008-05-22
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://naosite.lb.nagasaki-u.ac.jp/dspace/handle/10069/9852

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://naosite.lb.nagasaki-u.ac.jp/dspace/handle/10069/21328

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://naosite.lb.nagasaki-u.ac.jp/dspace/handle/10069/9852

    • Related Report
      2010 Annual Research Report
  • [Remarks]

    • URL

      http://naosite.lb.nagasaki-u.ac.jp/dspace/handle/10069/21328

    • Related Report
      2010 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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