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CONSTRUCTION OF REACTION MECHANISM FOR HCCI COMBUSTION USING HIGH-PRESSURE SHOCK TUBE

Research Project

Project/Area Number 20560201
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Thermal engineering
Research InstitutionSophia University

Principal Investigator

TAKAHASHI Kazuo  上智大学, 理工学部, 准教授 (10241019)

Co-Investigator(Kenkyū-buntansha) KUZE Nobuhiko  上智大学, 理工学部, 准教授 (80286757)
Project Period (FY) 2008 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥3,900,000 (Direct Cost: ¥3,000,000、Indirect Cost: ¥900,000)
Fiscal Year 2011: ¥520,000 (Direct Cost: ¥400,000、Indirect Cost: ¥120,000)
Fiscal Year 2010: ¥780,000 (Direct Cost: ¥600,000、Indirect Cost: ¥180,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
KeywordsHCCI燃焼 / 衝撃波管 / 着火特性 / 着火誘導期 / 燃焼反応機構ヘプタン / イソオクタン / トルエン / 燃焼反応機構 / ベンゼン / 原子共鳴吸収分光法 / ヘプタン / レーザー光分解 / 混合燃料
Research Abstract

To construct the comprehensive reaction model that can predict the ignition timing in the homogeneous charge compression ignition(HCCI) engine cycles, ignition delay times(τ) were measured in a newly produced high-pressure shock tube. The reaction models for heptane, iso-octane, and toluene ignitions were updated by using the rate coefficients determined experimentally and theoretically for the key reactions. These model calculations could reproduce the observed. in the wide pressure range. However, the ignition delay times for two-component mixtures of these hydrocarbon fuels could not be reproduced by the reaction models constructed by combining each mechanism. These disagreements are caused by the cross reactions, which are the reactions between the radical intermediates, so elucidation of the cross reactions is a challenge for the future.

Report

(6 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (49 results)

All 2012 2011 2010 2009 2008

All Journal Article (25 results) (of which Peer Reviewed: 25 results) Presentation (24 results)

  • [Journal Article] Shock-tube Sudies on the Reactions of o-, m-, and p-Xylenes with O(^3P) Atoms.2012

    • Author(s)
      Kazuo Takahashi, et al.
    • Journal Title

      Proceedings of the Twenty-Ei0ghth International Symposium on Shock Waves

      Volume: (in press)

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Study of the Structure and Conformation of 1, 1-Dicyclopropylethene by Gas Electron Diffraction and Ab Initio Calculations2012

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Structure

      Volume: 1014 Pages: 26-31

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Shock-tube Sudies on the Reactions of o-, m-, and p-Xylenes with O(^3P) Atoms2012

    • Author(s)
      Kazuo Takahashi, et al
    • Journal Title

      Proceedings of the Twenty-Eighth International Symposium on Shock Waves

      Volume: (in press)

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Study of the Structure and Conformation of 1,1-Dicyclopropylethene by Gas Electron Diffraction and Ab Initio Calculations2012

    • Author(s)
      Nobuhiko Kuze, et al
    • Journal Title

      Journal of Molecular Structure

      Volume: 1014 Pages: 26-31

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Metastable Atates in NO^+_2 Probed with Auger Spectroscopy2011

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Physical Chemistry and Chemical Physics

      Volume: 13 Pages: 18436-18446

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] A Search for Interstellar Carbon Chain Alcohol HC_4OH in Star-Forming Region L1527 and Dark Cloud TMC-12011

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      The Astrophysical Journal

      Volume: 163 Pages: 744-744

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Metastable Atates in NO_2^+ Probed with Auger Spectroscopy2011

    • Author(s)
      Nobuhiko Kuze, et al
    • Journal Title

      Physical Chemistry and Chemical Physics

      Volume: 13 Pages: 18436-18446

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] A Search for Interstellar Carbon Chain Alcohol HC_4OH in Star-Forming Region L1527 and Dark Cloud TMC-12011

    • Author(s)
      Nobuhiko Kuze, et al
    • Journal Title

      The Astrophysical Journal

      Volume: 744 Pages: 163-163

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Shock-tube studies on the reactions of some aromatic compounds with chain carriers in combustion2010

    • Author(s)
      Kazuo Takahashi, et al.
    • Journal Title

      Proceedings of the Twenty-Seventh International Symposium on Shock Waves

      Volume: 432

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Molecular structure of(E)-benzaldehyde oxime from gas-phase electron diffraction, quantum-chemical calculations and microwave spectroscopy2010

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Structure

      Volume: 987 Pages: 195-200

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Valence photoelectron spectroscopy of N_2 and CO : Recoil-induced rotational excitation, relative intensities, and atomic orbital composition of molecular orbitals2010

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      The Journal of Chemical Physics

      Volume: 133 Pages: 1-13

    • Related Report
      2011 Final Research Report 2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Molecular structure of (E)-benzaldehyde oxime from gas-phase electron diffraction, quantum-chemical calculations and microwave spectroscopy.2010

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Structure 987

      Pages: 195-200

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Molecular structure of (E)-benzaldehyde oxime from gas-phase electron diffraction, quantum-chemical calculations and microwave spectroscopy2010

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Structure

      Volume: 987 Pages: 195-200

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, inversion splittings and quadrupole coupling constants of NHDCl and ND_2Cl.2009

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Spectroscopy

      Volume: 253 Pages: 77-87

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, molecular structure and theoretical calculation of two isotopic species of acetyl isocyanate CD_3C(O) NCO and^<13> CH_3C(O) NCO2009

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Spectroscopy

      Volume: 256 Pages: 163-168

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, inversion splittings and quadrupole coupling constants of NHDCl and ND2Cl.2009

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Spectroscopy 253

      Pages: 77-87

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, molecular structure and theoretical calculation of two isotopic species of acetyl isocyanate CD_3C(O)NCO and <13>^CH_3C(O)NCO.2009

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Spectroscopy 256

      Pages: 163-168

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, molecular structure and theoretical calculation of two isotopic species of acetyl isocyanate CD_3C(O)NCO and ^<13>CH_3C(O)NCO2009

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Spectroscopy 256

      Pages: 163-168

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, inversion splittings and quadrupole coupling constants of NHDC1 and ND_2C12009

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Spectroscopy 253

      Pages: 77-87

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, molecular structures, and theoretical calculations of(E)-sp and (E)-ac isomers of 2-methylpropanal oxime2008

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Structure

      Volume: 876 Pages: 186-193

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Laboratory detection of a linear carbon chain alcohol : HC_4OH and its deuterated species2008

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Astrophysical Journal

      Volume: 680

    • Related Report
      2011 Final Research Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, molecular structures, and theoretical calculations of (E)-sp and (E)-ac isomers of 2-methylpropanal oxime.2008

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular Structure 876

      Pages: 186-193

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Laboratory detection of a linear carbon chain alcohol : HC4OH and its deuterated species.2008

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Astrophysical Journal 680

      Pages: 93-96

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Microwave spectra, molecular structures, and theoretical calcu-1ations of (E)-sp and (E)-ac isomers of 2-methylpropanal oxime2008

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Journal of Molecular structure 876

      Pages: 186-193

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Laboratory detection of a linear carbon chain alcohol : HC_4OH and its deuterated species2008

    • Author(s)
      Nobuhiko Kuze, et al.
    • Journal Title

      Astrophysieal Journal 680

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] 衝撃波管-原子共鳴吸収分光法によるアルキルベンゼンと酸素原子との高温反応追跡2012

    • Author(s)
      高橋和夫, 他
    • Organizer
      平成23年度衝撃波シンポジウム
    • Place of Presentation
      東京大学(柏)
    • Year and Date
      2012-03-09
    • Related Report
      2011 Final Research Report
  • [Presentation] 衝撃波管-原子共鳴吸収分光法によるアルキルベンゼンと酸素原子との高温反応追跡2012

    • Author(s)
      高橋和夫, 他
    • Organizer
      平成22年度衝撃波シンポジウム
    • Place of Presentation
      柏
    • Year and Date
      2012-03-09
    • Related Report
      2011 Annual Research Report
  • [Presentation] 量子化学計算による2-butyn-1-olの熱分解反応機構2011

    • Author(s)
      久世信彦, 他
    • Organizer
      分子科学討論会
    • Place of Presentation
      札幌
    • Year and Date
      2011-09-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] Shock-tube Sudies on the Reactions of o-, m-, and p-Xylenes with O(^3P) Atoms2011

    • Author(s)
      Kazuo Takahashi, et al
    • Organizer
      28th International Symposium on Shock Waves
    • Place of Presentation
      Manchester (UK)
    • Year and Date
      2011-07-21
    • Related Report
      2011 Annual Research Report
  • [Presentation] The Molecular Structure of Camphor by Gas Electron Diffraction and Quantum-Chemical Calculations2011

    • Author(s)
      Nobuhiko Kuze, et al
    • Organizer
      14th European Symposium on Gas Electron Diffraction
    • Place of Presentation
      Moscow (Russia)
    • Year and Date
      2011-06-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] 衝撃波管を用いた芳香族炭化水素燃焼の速度論的研究-キシレンと酸素原子との高温反応-2011

    • Author(s)
      高橋和夫, 他
    • Organizer
      平成22年度衝撃波シンポジウム
    • Place of Presentation
      平成22年度衝撃波シンポジウム
    • Year and Date
      2011-03-17
    • Related Report
      2011 Final Research Report
  • [Presentation] 衝撃波管を用いた芳香族炭化水素燃焼の速度論的研究-キシレンと酸素原子との高温反応-2011

    • Author(s)
      高橋和夫, 他
    • Organizer
      平成22年度衝撃波シンポジウム
    • Place of Presentation
      青山学院大学(相模原)
    • Year and Date
      2011-03-17
    • Related Report
      2010 Annual Research Report 2010 Self-evaluation Report
  • [Presentation] 高圧衝撃波管を用いたガソリン燃料成分の着火研究-着火誘導期の圧力依存性-2010

    • Author(s)
      高橋和夫, 他
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡ガーデンパレス & 都久志会館(福岡)
    • Year and Date
      2010-12-01
    • Related Report
      2011 Final Research Report
  • [Presentation] 高圧衝撃波管を用いたガソリン燃料成分の着火研究-着火誘導期の圧力依存性-2010

    • Author(s)
      高橋和夫, 他
    • Organizer
      第48回燃焼シンポジウム
    • Place of Presentation
      福岡ガーデンパレス&都久志会館(福岡)
    • Year and Date
      2010-12-01
    • Related Report
      2010 Annual Research Report 2010 Self-evaluation Report
  • [Presentation] 量子化学計算による2-butyn-1-olの熱分解反応機構2010

    • Author(s)
      久世信彦, 他
    • Organizer
      第4回分子科学討論会2010
    • Place of Presentation
      大阪大学(豊中)
    • Year and Date
      2010-09-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] 気体電子回折とマイクロ波分光による2-フェニルエタノールの分子構造解析2010

    • Author(s)
      久世信彦, 他
    • Organizer
      第4回分子科学討論会2010
    • Place of Presentation
      大阪大学(豊中)
    • Year and Date
      2010-09-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] ROTATIONAL SPECTRUM, POTENTIAL FUNCTION OF RING PUCKERING, MOLECULAR STRUCTURE, AND QUANTUM CHEMICAL CALCULATION OF CYCLOBUTANONE OXIME AND ITS PYROLYSIS MECHANISM2010

    • Author(s)
      Nobuhiko Kuze, et al.
    • Organizer
      The 21st International Conference on High Resolution Molecular Spectroscopy
    • Place of Presentation
      The Adam Mickiewicz Univ.(Poznan, Poland)
    • Year and Date
      2010-09-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Rotational spectrum of the pyrolysate of 2-butyn-1-ol in the gas phase2010

    • Author(s)
      Nobuhiko Kuze, et al.
    • Organizer
      第26回化学反応討論会
    • Place of Presentation
      広島大学(広島)
    • Year and Date
      2010-06-02
    • Related Report
      2010 Annual Research Report
  • [Presentation] 29-90 GHz帯における星形成領域L1527の炭素鎖分子ライン探査2010

    • Author(s)
      久世信彦, 他
    • Organizer
      第10回分子分光研究会
    • Place of Presentation
      東京工業大学(東京)
    • Year and Date
      2010-05-14
    • Related Report
      2010 Annual Research Report
  • [Presentation] Molecular conformation, dipole moment, quadruple coupling constants and barriers to C-C rotation of 2-methyl-2-propenal oxime by rotational spectroscopy and quantum chemical calculation2010

    • Author(s)
      久世信彦, et al.
    • Organizer
      23rd Austin Symposium on Molecular Structure
    • Place of Presentation
      Austin, U.S.A.
    • Year and Date
      2010-03-09
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高圧衝撃波管を用いたガソリン燃料成分の着火特性-着火誘導期と着火反応機構の当量比依存性-2009

    • Author(s)
      高橋和夫, 他
    • Organizer
      第47回燃焼シンポジウム
    • Place of Presentation
      札幌コンベンションセンター(札幌)
    • Year and Date
      2009-12-04
    • Related Report
      2011 Final Research Report 2010 Self-evaluation Report 2009 Annual Research Report
  • [Presentation] HC_4OHの振動励起状態のマイクロ波分光2009

    • Author(s)
      久世信彦, 他
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学(名古屋)
    • Year and Date
      2009-09-24
    • Related Report
      2009 Annual Research Report
  • [Presentation] おうし座分子雲TMC-1とL1527における酸素を含む炭素鎖分子の観測2009

    • Author(s)
      久世信彦, 他
    • Organizer
      第3回分子科学討論会
    • Place of Presentation
      名古屋大学(名古屋)
    • Year and Date
      2009-09-22
    • Related Report
      2009 Annual Research Report
  • [Presentation] Shock-tube studies on the reactions of some aromatic compounds with chain carriers in combustion.2009

    • Author(s)
      Kazuo Takahashi, et al.
    • Organizer
      27th International Symposium on Shock Waves
    • Place of Presentation
      St.Petersburg, Russia
    • Year and Date
      2009-07-21
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Shock-tube studies on the reactions of some aromatic compounds with chain carriers in combustion2009

    • Author(s)
      高橋和夫, et al.
    • Organizer
      27th International Symposium on Shock Waves
    • Place of Presentation
      St.Petersburg, Russia
    • Year and Date
      2009-07-21
    • Related Report
      2009 Annual Research Report
  • [Presentation] Molecular structure and 2D potential energy surface of 1, 1-dicyclopropylethene2009

    • Author(s)
      久世信彦, et al.
    • Organizer
      13th European Symp.on Gas Electron Diffraction
    • Place of Presentation
      Blaubeuren, Germany
    • Year and Date
      2009-06-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] 高圧衝撃波管を用いたガソリンサロゲート燃料の着火研究-着火遅れと着火反応機構の圧力依存性-2009

    • Author(s)
      高橋和夫, 他
    • Organizer
      平成20年度衝撃波シンポジウム
    • Place of Presentation
      名古屋大学(名古屋)
    • Year and Date
      2009-03-19
    • Related Report
      2011 Final Research Report 2010 Self-evaluation Report 2008 Annual Research Report
  • [Presentation] 高圧におけるガソリン燃料成分の着火特性と反応モデル解析2008

    • Author(s)
      高橋和夫, 他
    • Organizer
      第46回燃焼シンポジウム
    • Place of Presentation
      京都テルサ(京都)
    • Year and Date
      2008-12-04
    • Related Report
      2011 Final Research Report 2010 Self-evaluation Report 2008 Annual Research Report
  • [Presentation] 直線炭素鎖アルコールHC40Hとその重水素置換体のマイクロ波分光2008

    • Author(s)
      久世信彦, 他
    • Organizer
      第2回分子科学討論会
    • Place of Presentation
      福岡国際会議場(福岡)
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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