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Improvement of insulator/ Germanium interface by surface passivation for high-mobility Ge based transistor.

Research Project

Project/Area Number 20560300
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Electronic materials/Electric materials
Research InstitutionOsaka University

Principal Investigator

KANASHIMA Takeshi  大阪大学, 基礎工学研究科, 准教授 (30283732)

Project Period (FY) 2008 – 2011
Project Status Completed (Fiscal Year 2011)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2011: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,040,000 (Direct Cost: ¥800,000、Indirect Cost: ¥240,000)
Fiscal Year 2008: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Keywords作成・評価技術 / 量子化学計算 / 表面 / Ge / 分子軌道計算 / 表面・界面物性 / High-k / 表面反応 / 表面処理 / 硫化アンモニウム / 作製・評価技術 / HCl
Research Abstract

Germanium has been attracting much attention for high-performance ULSI, because it has higher electron and hole mobilities than Si. However, Ge-based MIS transistors still have the problems such as a high interface state density. So, the passivation of the Ge surface has been studied to reduce the interface state density. The theoretical analysis was carried out to search for alternative terminal materials on the Ge surface, and the passivation effects have been characterized experimentally. As a result, it is shown that F, Cl and S treatments can reduce the interface state density.

Report

(6 results)
  • 2011 Annual Research Report   Final Research Report ( PDF )
  • 2010 Annual Research Report   Self-evaluation Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (38 results)

All 2012 2011 2010 2009 2008 Other

All Journal Article (15 results) (of which Peer Reviewed: 8 results) Presentation (22 results) Remarks (1 results)

  • [Journal Article] Passivation of Ge(100) and(111) Surfaces by Termination of Nonmetal Elements2012

    • Author(s)
      D. Lee, K. Kubo, T. Kanashima and M. Okuyama
    • Journal Title

      Jpn. J. Appl. Phys

      Volume: 51

    • NAID

      210000072099

    • Related Report
      2011 Final Research Report
  • [Journal Article] Improvement in the Electrical Characteristics of a Fluorinated HfO_2/ Ge Gate Stack by Using a Nitrogen Radical Treatment2011

    • Author(s)
      D. Lee, H. Lee, H. Imajo, Y. Yoshioka, T. kanashima and M. Okuyama
    • Journal Title

      J. Korean Phys. Soc

      Volume: 59 Pages: 2503-2508

    • Related Report
      2011 Final Research Report
  • [Journal Article] Improvement in the Property of Field Effect Transistor Having the HfO_2/ Ge Structure Chemical Vapor Deposition with Fluorine Treatment Fabricated by Photoassisted Metal Organic2011

    • Author(s)
      D. Lee, H. Imajo, T. Kanashima and M. Okuyama
    • Journal Title

      Jpn. J. Appl

      Volume: 50

    • Related Report
      2011 Final Research Report
  • [Journal Article] Improvement in the Electrical Characteristics of a Fluorinated Hf_2O/Ge Gate Stack by Using a Nitrogen Radical Treatment2011

    • Author(s)
      DongHun Lee, Hyun Lee, Hideto Imajo, Yuichi Yoshioka, Takeshi kanashima, Masanori Okuyama
    • Journal Title

      J.Korean Phys.Soc.

      Volume: 59 Issue: 3(1) Pages: 2503-2508

    • DOI

      10.3938/jkps.59.2503

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Improvement in the Property of Field Effect Transistor Having the HfO_2/Ge Structure Fabricated by Photoassisted Metal Organic Chemical Vap or Deposition with Fluorine Treatment2011

    • Author(s)
      DongHun Lee, Hideto Imajo, Takeshi Kanashima, Masanori Okuyama
    • Journal Title

      Jpn.J.Appl.Phys.

      Volume: 50 Issue: 4S Pages: 04DA11-04DA11

    • DOI

      10.1143/jjap.50.04da11

    • Related Report
      2011 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Theoretical Analysis of Fluorine-Passivated Germanium Surface for High-k/ Ge Gate Stack by Molecular Orbital Method2010

    • Author(s)
      D. Lee, H. Lee, T. Kanashima and M. Okuyama
    • Journal Title

      Appl. Surf. Sci

      Volume: 257 Pages: 917-920

    • Related Report
      2011 Final Research Report
  • [Journal Article] Theoretical Analysis of Fluorine-Passivated Germanium Surface for High-k/Ge Gate Stack by Molecular Orbital Method2010

    • Author(s)
      D.Lee, H.Lee, T.Kanashima, M.Okuyama
    • Journal Title

      Appl.Surf.Sci. 257

      Pages: 917-920

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Theoretical Analysis of Fluorine-Passivated Germanium Surface for High-k/Ge Gate Stack by Molecular Orbital Method2010

    • Author(s)
      D.H, Lee, H.Lee, T.Kanashima, M.Okuyama
    • Journal Title

      Appl.Surf.Sci.

      Volume: 257 Pages: 917-920

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] HfO2/Ge MIS構造のF2処理と窒素ラジカル処理による電気的特性の向上2009

    • Author(s)
      今庄秀人, Hyun Lee, Dong-Hun Lee, 吉岡祐一, 金島岳, 奥山雅則
    • Journal Title

      電子情報通信学会技術研究報告書 SDM2009

      Pages: 43-48

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Preparation and Characterization of Hafnium Silicate Dielectric Layers by Photo-Assisted MOCVD Using Mixed Precursor of Hf(O-t-C_4H_9)_4 and Si(O-t-C_4H_9)_42008

    • Author(s)
      H. Lee, T. Kanashima and M. Okuyama
    • Journal Title

      Integrated Ferroelectrics

      Volume: 97 Pages: 103-110

    • Related Report
      2011 Final Research Report
  • [Journal Article] Characteristics improvement of HfO_2/ Ge gate stack structure by fluorine treatment of germanium surface2008

    • Author(s)
      H. Lee, D. H. Lee, T. Kanashima and M. Okuyama
    • Journal Title

      Appl. Surf. Sci

      Volume: 254 Pages: 6932-6936

    • Related Report
      2011 Final Research Report
  • [Journal Article] Fixed-Oxide-Charge Characterization by Photoreflectance Spectroscopy in HfO_2 on Ge Treated by Fluorine2008

    • Author(s)
      T.Kanashima, H.Lee, Y.Mori, H.Imajo, M.Okuyama.
    • Journal Title

      Proceedings of ECS Transactions(PRiME2008) Volume 16, Issue 10

      Pages: 699-705

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of Hafnium Silicate Dielectric Layers by Photo-Assisted MOCVD Using Mixed Precursor of Hf(O-t-C_4H_9)_4 and Si(O-t-C_4H_9)_42008

    • Author(s)
      H.Lee, T.Kanashima, M.Okuyama
    • Journal Title

      Integrated Ferroelectrics 97

      Pages: 103-110

    • Related Report
      2010 Self-evaluation Report
    • Peer Reviewed
  • [Journal Article] Characteristics improvement of HfO_2/Ge gate stack structure by fluorinetreatment of germanium surface2008

    • Author(s)
      H. Lee, D. H. Lee, T. Kanashima, M. Okuyama
    • Journal Title

      Applied Surface Sciencet 254

      Pages: 6932-6936

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation and Characterization of Hafnium Silicate Dielectric Layers by Photo-Assisted MOCVD Using Mixed Precursor of Hf(O-t-C_4H_9)_4 and Si(O-t-C_4H_9)_42008

    • Author(s)
      H. Lee, T. Kanashima, M. Okuyama
    • Journal Title

      Integrated Ferroelectrics 97

      Pages: 103-110

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] HfO_2/Ge MIS構造のHCl表面処理による電気的特性の向上2011

    • Author(s)
      久保和樹, Dong Hun Lee, 金島岳
    • Organizer
      第58回応用物理学関係連合講演会
    • Place of Presentation
      神奈川工科大学(神奈川県)
    • Year and Date
      2011-03-27
    • Related Report
      2011 Annual Research Report
  • [Presentation] Passivation of Ge(100) and(111) Surfaces by Termination of Nonmetal Elements2011

    • Author(s)
      D. H. Lee, K. Kubo, T. Kanashima and M. Okuyama
    • Organizer
      2011 International Conference on Solid State Devices and Materials
    • Place of Presentation
      Nagoya, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Passivation of Ge(100) and (111) Surfaces by Termination of Nonmetal Elements2011

    • Author(s)
      D.H.Lee, K.Kubo, T.Kanashima, M.Okuyama
    • Organizer
      2011 International Conference on Solid State Devices and Materials
    • Place of Presentation
      愛知県産業労働センターウインクあいち(愛知県)
    • Related Report
      2011 Annual Research Report
  • [Presentation] Characterization of Interface States of HfO_2/Ge with Fluorine Treatment by Using DLTS/ICTS2010

    • Author(s)
      T.Kanashima, Y.Yoshioka, D.Lee, M.Okuyama
    • Organizer
      218th ECS Meeting
    • Place of Presentation
      Las Vegas ; NV, USA
    • Year and Date
      2010-10-10
    • Related Report
      2010 Annual Research Report
  • [Presentation] Improvement of The Property of FET having The HfO_2/Ge Structure Fabricated by Photo-Assisted MOCVD with Fluorine Treatment2010

    • Author(s)
      D.H.Lee, H.Imajo, T.Kanashima, M.Okuyama
    • Organizer
      2010 International Conference on SOLID STATE DEVICES AND MATERIALS (SSDM2010)
    • Place of Presentation
      Tokyo, Japan
    • Year and Date
      2010-09-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Post nitridation of fluorinated HfO_2/Ge gate stack by nitrogen radical treatment2010

    • Author(s)
      D.H, Lee, H.Lee, H.Imajo, Y.Yoshioka, T.Kanashima, M.Okuyama
    • Organizer
      The 8th Japan-Korea Conference on Ferroelectrics (JKC-FE08)
    • Place of Presentation
      Himeji, Japan
    • Year and Date
      2010-08-03
    • Related Report
      2010 Annual Research Report
  • [Presentation] F_2添加光MOCVD法により作製したHfO_2/Ge FETの特性向上2010

    • Author(s)
      Donghun Lee, 今庄秀人, 吉岡裕一, 金島岳, 奥山雅則
    • Organizer
      第57回応用物理学会学関係連合講演会
    • Place of Presentation
      東海大学
    • Year and Date
      2010-03-18
    • Related Report
      2009 Annual Research Report
  • [Presentation] Improvement of The Property of FET Having The HfO_2/ Ge Structure Fabricated by Photo-Assisted MOCVD with Fluorine Treatment2010

    • Author(s)
      D. Lee, H. Imajo, T. Kanashima and M. Okuyama
    • Organizer
      2010 International Conference on SOLID STATE DEVICES AND MATERIALS
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2011 Final Research Report
  • [Presentation] Post nitridation of fluorinated HfO_2/ Ge gate stack by nitrogen radical treatment2010

    • Author(s)
      D. H. Lee, H. Lee, H. Imajo, Y. Yoshioka, T. Kanashima and M. Okuyama
    • Organizer
      The 8th Japan-Korea Conference on Ferroelectrics
    • Place of Presentation
      Himeji, Japan,
    • Related Report
      2011 Final Research Report
  • [Presentation] Characterization of Interface States of HfO_2/ Ge with Fluorine Treatment by Using DLTS/ ICTS2010

    • Author(s)
      T. Kanashima, Y. Yoshioka, D. H. Lee and M. Okuyama
    • Organizer
      ECS Transactions
    • Related Report
      2011 Final Research Report
  • [Presentation] Characterization of Interface States of HfO_2/Ge with Fluorine Treatment by Using DLTS/ICTS2010

    • Author(s)
      T.Kanashima, Y.Yoshioka, D.Lee, M.Okuyama
    • Organizer
      218th ECS Meeting, p.1879.
    • Place of Presentation
      Las Vegas, NV
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Improvement of The Property of FET Having The HfO_2/Ge Structure Fabricated by Photo-Assisted MOCVD with Fluorine Treatment2010

    • Author(s)
      D.Lee, H.Imajo, T.Kanashima, M.Okuyama
    • Organizer
      2010 International Conference on SOLID STATE DEVICES AND MATERIALS, P-1-12.
    • Place of Presentation
      Tokyo, Japan
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Post nitridation of fluorinated HfO2/Ge gate stack by nitrogen radical treatment2010

    • Author(s)
      D.H.Lee, H.Lee, H.Imajo, Y.Yoshioka, T.Kanashima, M.Okuyama
    • Organizer
      The 8th Japan-Korea Conference on Ferroelectrics(JKC-FE08)P1-026.
    • Place of Presentation
      Himeji, Japan
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Ge(100)表面と元素の反応の分子軌道解析と結合の安定性2009

    • Author(s)
      Donghun Lee, 金島岳, 奥山雅則
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] DLTSおよびICTS法によるHfO□/GeのMIS構造の界面状態評価2009

    • Author(s)
      吉岡祐一, Donghun Lee, 今庄秀人, 金島岳, 奥山雅則
    • Organizer
      第70回応用物理学会学術講演会
    • Place of Presentation
      富山大学
    • Year and Date
      2009-09-11
    • Related Report
      2009 Annual Research Report
  • [Presentation] HfO_2/ Ge MIS構造のF_2処理と窒素ラジカル処理による電気的特性の向上2009

    • Author(s)
      今庄秀人, H. Lee, D.-H. Lee, 吉岡祐一, 金島岳, 奥山雅則
    • Organizer
      シリコンテクノロジー(共催:電子情報通信学会シリコン材料・デバイス研究会(SDM))
    • Place of Presentation
      応用物理学会分科会,東京大学
    • Related Report
      2011 Final Research Report
  • [Presentation] F_2表面処理したHfO_2/ Ge MIS構造の電気的特性評価2008

    • Author(s)
      今庄秀人, H. Lee, 吉岡祐一, 金島岳, 奥山雅則
    • Organizer
      電子情報通信学会シリコン材料・デバイス研究会(SDM)
    • Place of Presentation
      京都大学,桂キャンパス,
    • Related Report
      2011 Final Research Report
  • [Presentation] Theoretical analysis of fluorine-passivated germanium surface for high-k/ Ge gate stack by molecular orbital method2008

    • Author(s)
      H. Lee, D. H. Lee, T. Kanashima and M. Okuyama
    • Organizer
      The 7th Korea-Japan Conference on Ferroelectricity
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2011 Final Research Report
  • [Presentation] Fixed-Oxide-Charge Characterization by Photoreflectance Spectroscopy in HfO_2 on Ge Treated by Fluorine2008

    • Author(s)
      T. Kanashima, H. Lee, Y. Mori, H. Imajo and M. Okuyama
    • Organizer
      Proceedings of ECS Transactions(PRiME2008)
    • Related Report
      2011 Final Research Report
  • [Presentation] Fixed-Oxide-Charge Characterization by Photoreflectance Spectroscopy in HfO_2 on Ge Treated by Fluorine2008

    • Author(s)
      T.Kanashima, H.Lee, Y.Mori, H.Imajo, M.Okuyama.
    • Organizer
      Pacific Rim Meeting on Electrochemical and Solid-State Science, PRiME2008, p.2451.
    • Place of Presentation
      Honolulu
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Theoretical analysis of fluorine-passivated germanium surface for high-k/Ge gate stack by molecular orbital method2008

    • Author(s)
      H.Lee, D.H.Lee, T.Kanashima, M.Okuyama
    • Organizer
      The 7th Korea-Japan Conference on Ferroelectricity(KJC-FE07)P-08-27.
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2010 Self-evaluation Report
  • [Presentation] Theoretical analysis of fluorine-passivated germanium surface for high-k/Ge gate stack by molecular orbital method2008

    • Author(s)
      H. Lee, D. H. Lee, T. Kanashima, M. Okuyama
    • Organizer
      The 7th Korea-Japan Conference on Ferroelectric-ity
    • Place of Presentation
      Jeju, Korea
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.semi.ee.es.osaka-u.ac.jp/shiraishilab/

    • Related Report
      2011 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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