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Influence of defect on thermoelectric properties of metal-hexaborides

Research Project

Project/Area Number 20560613
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Physical properties of metals
Research InstitutionNagaoka University of Technology

Principal Investigator

TAKEDA Masatoshi  Nagaoka University of Technology, 工学部, 准教授 (30293252)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2008: ¥2,600,000 (Direct Cost: ¥2,000,000、Indirect Cost: ¥600,000)
Keywords熱電変換材料 / ゼーベック係数 / 電気伝導率 / キャリア濃度 / 格子欠陥 / 結晶構造解析 / 金属六ホウ化物 / 焼結体 / 熱重変換材料
Research Abstract

Influence of defect on the thermoelectric properties of divalent hexaborides (CaB_6, SrB_6, YbB_6) were examined. Carrier concentration of the hexabiredes we examined was changed by synthesis condition, and as the result, electrical conductivity and the Seebeck coefficient were varied as a function of the carrier concentration. Chemical and crystal structure analyses revealed that metaliboron ratio affects the carrier concentration. In addition, p-n control was demonstrated in the YbB_6.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (15 results)

All 2010 2009 2008 Other

All Presentation (14 results) Remarks (1 results)

  • [Presentation] SrB6の熱電特性に及ぼす格子欠陥の影響2010

    • Author(s)
      武田雅敏, 高波翼
    • Organizer
      20th Academic Symposium of MRS-Japan
    • Place of Presentation
      横浜
    • Year and Date
      2010-12-22
    • Related Report
      2010 Annual Research Report
  • [Presentation] Influence of defect on the thrmoelectric properties of YbB62010

    • Author(s)
      K.Kayamura, K.Inayoshi, H.Kitagawa, M.Takeda
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-17
    • Related Report
      2010 Final Research Report
  • [Presentation] Influence of defect on the thermoelectric properties of YbB62010

    • Author(s)
      K.Kayamura, K.Inayoshi, H.Kitagawa, M.Takeda
    • Organizer
      3rd International Congress on Ceramics
    • Place of Presentation
      大阪
    • Year and Date
      2010-11-17
    • Related Report
      2010 Annual Research Report
  • [Presentation] Possible improvement in thermoelectric property of p-type hexabride2010

    • Author(s)
      K.Kayamura, M.Takeda
    • Organizer
      29th International Conference on Thermoelectrics
    • Place of Presentation
      Shanghai/China
    • Year and Date
      2010-06-01
    • Related Report
      2010 Final Research Report
  • [Presentation] Possible improvement in thermoelectric property of p-type hexaborde2010

    • Author(s)
      K.Kayamura, M.Takeda
    • Organizer
      29th International Conference on Thermoelectrics
    • Place of Presentation
      Shanghai (China)
    • Year and Date
      2010-06-01
    • Related Report
      2010 Annual Research Report
  • [Presentation] YbB6における熱電特性の温度依存性2009

    • Author(s)
      萱村耕治, 武田雅敏
    • Organizer
      平成21年度日本金属学会北陸信越支部連合講演会
    • Place of Presentation
      長岡技術科学大学(長岡市)
    • Year and Date
      2009-12-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] 六ホウ化物の熱伝導特性改善による熱電性能向上の可能性2009

    • Author(s)
      稲吉香織, 武田雅敏, 他3名
    • Organizer
      第6回日本熱電学会学術講演会
    • Place of Presentation
      東北大学(仙台市)
    • Year and Date
      2009-08-10
    • Related Report
      2009 Annual Research Report
  • [Presentation] Thermal conductivity reduction of metal hexabores by alloying2009

    • Author(s)
      M.Takeda
    • Organizer
      28th International Concerence on Thermoelectrics
    • Place of Presentation
      Feiburg/Germany
    • Year and Date
      2009-07-28
    • Related Report
      2010 Final Research Report
  • [Presentation] Thermal conductivity reduction of metal hexaborides by alloying2009

    • Author(s)
      武田雅敏
    • Organizer
      28th International Conference on Thermoelectrics
    • Place of Presentation
      Freiburg(ドイツ)
    • Year and Date
      2009-07-28
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属六ホウ化物における熱伝導率低減の試み2009

    • Author(s)
      武田雅敏, 他3名
    • Organizer
      日本金属学会2009年春期大会
    • Place of Presentation
      東京工業大学
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] Cluster-based Boron-rich Material:Candidate for Thermal to Electric Energy Conversion Material2009

    • Author(s)
      武田雅敏
    • Organizer
      International Symposium on Multifunctional Ceramic Materials Based on Nanotechnology
    • Place of Presentation
      長岡市
    • Year and Date
      2009-02-14
    • Related Report
      2008 Annual Research Report
  • [Presentation] 金属六ホウ化物の合金化による熱電性能向上の試み2008

    • Author(s)
      井口憲一, 中川光聖, 武田雅敏
    • Organizer
      日本金属学会北信越支部講演会
    • Place of Presentation
      信州大学
    • Year and Date
      2008-12-06
    • Related Report
      2008 Annual Research Report
  • [Presentation] Cluster-Based Boron-rich Thermoelectric Material2008

    • Author(s)
      M.Takeda
    • Organizer
      The 1st International Symposium on Hebrid Materials and Processing
    • Place of Presentation
      Busan/Korea
    • Year and Date
      2008-10-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Cluster-Based Boron-rich Thermoelectric Material2008

    • Author(s)
      武田雅敏
    • Organizer
      The 1st International Symposium on Hybrid Materials and Processing
    • Place of Presentation
      Busan/Korea
    • Year and Date
      2008-10-27
    • Related Report
      2008 Annual Research Report
  • [Remarks] ホームページ等

    • URL

      http://meweb.nagaokaut.ac.jp/~takeda

    • Related Report
      2010 Final Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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