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Sol-gel preparation of phosphor and photocatalyst materials based on germanium and tantalum oxides

Research Project

Project/Area Number 20560632
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Inorganic materials/Physical properties
Research InstitutionRitsumeikan University

Principal Investigator

KOJIMA Kazuo  Ritsumeikan University, 生命科学部, 教授 (30131311)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥910,000 (Direct Cost: ¥700,000、Indirect Cost: ¥210,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥2,470,000 (Direct Cost: ¥1,900,000、Indirect Cost: ¥570,000)
Keywords蛍光体 / 光触媒 / 薄膜 / 酸化ゲルマニウム / 酸化亜鉛 / 酸化マグネシウム / 酸化タンタル / ゾル・ゲル法 / 酸化ニオブ / 酸化ハフニウム
Research Abstract

Sol-gel derived zinc oxide-germanium oxide green-color phosphors, doped with manganese and europium ions, showed long afterglow lasting for over 3 hours. Magnesium oxide-zinc oxide-germanium oxide ceramics, doped with manganese ions, were found to be red, yellow, or green phosphors, depending on the ceramics composition. Zinc germanate transparent thin films, prepared by sol-gel method, showed high photocatalytic activity. These films doped with manganese ions emitted intense green phosphorescence. Tantalum-oxide photocatalytic thin films were also produced.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (48 results)

All 2011 2010 2009 2008 Other

All Journal Article (10 results) (of which Peer Reviewed: 10 results) Presentation (36 results) Remarks (2 results)

  • [Journal Article] Preparation of a Mn^<2+> doped ZnO-Ta_2O_5 phosphor by a sol-gel method2011

    • Author(s)
      T.Sanada、S.Kato、Y.Morimoto、S.Ikeda、K.Kojima、N.Wada
    • Journal Title

      Journal of Ceramic Processing Research 12

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of a Mn^<2+> doped ZnO-Ta_2O_5 Phosphor by a sol-gel method2011

    • Author(s)
      T.Sanada, S.Kato, Y.Morimoto, S.Ikeda, K.Kojima, N.Wada
    • Journal Title

      Journal of Ceramic Processing Research

      Volume: 12 Pages: 5-8

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Eu^<3+>-doped Ta_2O_5 phosphor particles by sol-gel method2010

    • Author(s)
      T.Sanada、Y.Wakai、H.Nakashita、T.Matsumoto、C.Yogi、S.Ikeda、N.Wada、K.Kojima
    • Journal Title

      Optical Materials 33

      Pages: 164-169

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Luminescence and long-lasting afterglow in Mn^<2+> and Eu^<3+> co-doped ZnO-GeO_2 glasses and glass ceramics prepared by sol-gel method2010

    • Author(s)
      T.Sanada、H.Seto、Y.Morimoto、Y.Yamamoto、N.Wada、K.Kojima
    • Journal Title

      J.Sol-Gel Sci.Tech. 56

      Pages: 82-86

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of Eu^<3+>-doped Ta_2O_5 phosphor particles by sol-gel method2010

    • Author(s)
      T.Sanada, Y.Wakai, H.Nakashita, T.Matsumoto, C.Yogi, S.Ikeda, N.Wada, K.Kojima
    • Journal Title

      Optical Materials

      Volume: 33 Pages: 164-169

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Luminescence and long-lasting afterglow in Mn^<2+> and Eu^<3+> co-doped ZnO-GeO_2 glasses and glass ceramics prepared by sol-gel method.2010

    • Author(s)
      T.Sanada, H.Seto, Y Morimoto, Y Yamamoto, N.Wada, K.Kojima
    • Journal Title

      J.Sol-Gel Sci.Tech.

      Volume: 56 Pages: 82-86

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Dispersion and Fluorescence of Tb^<3+> in B_2O_3-CaO Glass2009

    • Author(s)
      N.Wada、M.Katayama、K.Kojima、K.Ozutsumi
    • Journal Title

      Phys.Chem.Glasses (European Journal of Glass Science and Technology Part B) 50

      Pages: 361-366

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Dispersion and Fluorescence of Tb^<3+> in B_2O_3-CaO Glass2009

    • Author(s)
      N.Wada, M.Katayama, K.Kojima, K.Ozutsumi
    • Journal Title

      Phys.Chem.Glasses(European Journal of Glass Science and Technology Part B) 50

      Pages: 361-366

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of undoped and Tb^<3+>-doped fluorescent HfO_2 sperical particles2008

    • Author(s)
      T.Sanada、M.Kawai、H.Nakashita、T.Matsumoto、N.Wada、K.Kojima
    • Journal Title

      J.Ceram.Soc.Jpn. 116

      Pages: 1265-1269

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Preparation of undoped and Tb^<3+>-doped fluorescent HfO_2 sperical particles2008

    • Author(s)
      T. Sanada, M. Kawai, H. Nakashita, T. Matsumoto, N. Wada, K. Kojima
    • Journal Title

      J. Ceram. Soc. Jpn. 116

      Pages: 1265-1269

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] ゾル-ゲル法で作製したMn^<2+>含有Zn_2GeO_4薄膜の発光特性と光触媒性2011

    • Author(s)
      眞田智衛、山田絵美、中山美智代、小島一男、和田憲幸
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学(静岡県)
    • Year and Date
      2011-03-16
    • Related Report
      2010 Final Research Report
  • [Presentation] ゾルーゲル法で作製したMn^<2+>含有Zn_2GeO_4薄膜の発光特性と光触媒性2011

    • Author(s)
      眞田智衛、山田絵美、中山美智代、小島一男、和田憲幸
    • Organizer
      日本セラミックス協会2011年年会
    • Place of Presentation
      静岡大学(静岡県)
    • Year and Date
      2011-03-16
    • Related Report
      2010 Annual Research Report
  • [Presentation] Sol-gel preparation of undoped and Mn^<2+>-doped Zn_2GeO_4 Thin Films by Sol-Gel Method2010

    • Author(s)
      K.Kojima、E.Yamada、M.Nakayama、C.Yogi、T.Sanada、N.Wada
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      ホノルル(米国)
    • Year and Date
      2010-12-18
    • Related Report
      2010 Final Research Report
  • [Presentation] Sol-gel preparation of undoped and Mn^<2+>-doped Zn_2GeO_4 films for photo catalyst and phosphor2010

    • Author(s)
      K.Kojima, E.Yamada, M.Nakayama, C.Yogi, T.Sanada, N.Wada
    • Organizer
      The 2010 International Chemical Congress of Pacific Basin Societies
    • Place of Presentation
      Honolulu, USA
    • Year and Date
      2010-12-18
    • Related Report
      2010 Annual Research Report
  • [Presentation] Evaluation of Photocatalytic Activity of Ta_2O_5 Films Prepared by Sol-Gel Method2010

    • Author(s)
      K.Otoizumi、C.Yogi、N.Wada、K.Kojima
    • Organizer
      3^<rd> International Congress on Ceramics
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Preparation and Optical Properties of Tb^<3+>-doped GeO_2-ZrO_2 Thin Films by Sol-Gel Method2010

    • Author(s)
      T.Sanada、M.Abe、K.Yamamoto、N.Wada、K.Kojima、
    • Organizer
      3^<rd>International Congress on Ceramics
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2010-11-05
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation and Optical Properties of Tb^<3+>-doped GeO_2-ZrO_2 Thin Filmsby Sol-Gel Method2010

    • Author(s)
      T.Sanada, M.Abe, K.Yamamoto, N.Wada, K.Kojima
    • Organizer
      3^<rd> International Congress on Ceramics
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2010-11-05
    • Related Report
      2010 Annual Research Report
  • [Presentation] ゾル-ゲル法を用いて作製したMn^<2+>およびEu^<3+>を共含有したZnO-GeO_2ガラスセラミックスの発光と構造評価2010

    • Author(s)
      秋田大地、眞田智衛、和田憲幸、小島一男、片山真祥、稲田康宏、小堤和彦
    • Organizer
      第13回XAFS討論会
    • Place of Presentation
      立命館大学(滋賀県)
    • Year and Date
      2010-09-06
    • Related Report
      2010 Final Research Report
  • [Presentation] ゾルーゲル法を用いて作製したMn^<2+>およびEu^<3+>を共含有したZnO-GeO_2ガラスセラミックスの発光と構造評価2010

    • Author(s)
      秋田大地、眞田智衛、和田憲幸、小島一男、片山真祥、稲田康宏、小堤和彦
    • Organizer
      第13回XAFS討論会
    • Place of Presentation
      立命館大学(滋賀県)
    • Year and Date
      2010-09-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] 可視光照射下におけるAgNbO_3光触媒膜の評価2010

    • Author(s)
      井田貴夫、与儀千尋、眞田智衛、和田憲幸、小島一男
    • Organizer
      日本ゾルーゲル学会第8回討論会
    • Place of Presentation
      名古屋大学(愛知県)
    • Year and Date
      2010-07-30
    • Related Report
      2010 Annual Research Report 2010 Final Research Report
  • [Presentation] Preparation of Eu^<3+>-doped Ta_2O_5 phosphor particles by sol-gel method2010

    • Author(s)
      T.Sanada、Y.Wakai、H.Nakashita、T.Matsumoto、C.Yogi、S.Ikeda、N.Wada、K.Kojima
    • Organizer
      3^<rd> International Workshop on Photoluminescence in Rare Earth : Photonic Materials and Devices
    • Place of Presentation
      フィレンツェ(イタリア)
    • Year and Date
      2010-04-29
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation of Eu^<3+>-doped Ta_2O_5 phosphor particles by sol-gel method2010

    • Author(s)
      T.Sanada, Y.Wakai, H.Nakashita, T.Matsumoto, C.Yogi, S.Ikeda, N.Wada, K.Kojima
    • Organizer
      3^<rd> International Workshop on Photoluminescence in Rare Earth : Photonic Materials and Devices
    • Place of Presentation
      Florence, Italy
    • Year and Date
      2010-04-29
    • Related Report
      2010 Annual Research Report
  • [Presentation] Tb^<3+>含有HfO_2 球状粒子の作製および光学特性2010

    • Author(s)
      明光真澄、小島一男、眞田智衛、池田慎吾、松本太一、中下宏、河合雅士
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      近畿大学(大阪府)
    • Year and Date
      2010-03-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Tb^<3+>含有HfO_2球状粒子の作製および光学特性2010

    • Author(s)
      明光真澄、小島一男、眞田智衛、池田慎吾、松本太一、中下宏、河合雅士
    • Organizer
      日本化学会第90春季年会
    • Place of Presentation
      大阪府(近畿大学)
    • Year and Date
      2010-03-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] Zn_2GeO_4光触媒膜のゾル-ゲル法による作製と評価2009

    • Author(s)
      山田絵美、与儀千尋、眞田智衛、和田憲幸、小島一男
    • Organizer
      第16回シンポジウム光触媒反応の最近の展開
    • Place of Presentation
      川崎市KSPホール(神奈川県)
    • Year and Date
      2009-12-02
    • Related Report
      2010 Final Research Report
  • [Presentation] Zn_2GeO_4光触媒膜のゾルーゲル法による作製と評価2009

    • Author(s)
      山田絵美、与儀千尋、眞田智衛、和田憲幸、小島一男
    • Organizer
      第16回シンポジウム「光触媒反応の最近の展開」
    • Place of Presentation
      神奈川県(川崎市KSPホール)
    • Year and Date
      2009-12-02
    • Related Report
      2009 Annual Research Report
  • [Presentation] 可視光照射下におけるAgNbO_3光触媒膜の評価2009

    • Author(s)
      井田貴夫、与儀千尋、和田憲幸、池田慎吾、小島一男
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学(愛媛県)
    • Year and Date
      2009-11-08
    • Related Report
      2010 Final Research Report
  • [Presentation] 可視光照射下におけるAgNbO_3光触媒膜の評価2009

    • Author(s)
      井田貴夫、与儀千尋、和田憲幸、池田慎吾、小島一男
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛県(愛媛大学)
    • Year and Date
      2009-11-08
    • Related Report
      2009 Annual Research Report
  • [Presentation] ゾル-ゲル法によるTb^<3+>含有HfO_2-Ta_2O_5系薄膜の作製と光学特性2009

    • Author(s)
      増川芳昭、眞田智衛、池田慎吾、和田憲幸、小島一男
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学(愛媛県)
    • Year and Date
      2009-11-07
    • Related Report
      2010 Final Research Report
  • [Presentation] ゾル-ゲル法によって作製したMn含有MgO-ZnO-GeO_2系ガラスセラミックスの発光2009

    • Author(s)
      森本悠介、眞田智衛、池田慎吾、和田憲幸、小島一男
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛大学(愛媛県)
    • Year and Date
      2009-11-07
    • Related Report
      2010 Final Research Report
  • [Presentation] ゾルーゲル法によるTb^<3+>含有HfO_2-Ta_2O_5系薄膜の作製と光学特性2009

    • Author(s)
      増川芳昭、眞田智衛、和田憲幸、池田慎吾、和田憲幸、小島一男
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛県(愛媛大学)
    • Year and Date
      2009-11-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] ゾルーゲル法によって作製したMn含有MgO-ZnO-GeO_2系ガラスセラミックスの発光2009

    • Author(s)
      森本悠介、眞田智衛、池田慎吾、和田憲幸、小島一男
    • Organizer
      日本化学会西日本大会2009
    • Place of Presentation
      愛媛県(愛媛大学)
    • Year and Date
      2009-11-07
    • Related Report
      2009 Annual Research Report
  • [Presentation] Preparation of Mn^<2+> doped ZnO-Ta_2O_5 phosphor by sol-gel method2009

    • Author(s)
      T.Sanada、S.Kato、Y.Morimoto、S.Ikeda、K.Kojima、N.Wada
    • Organizer
      THE PHOSPHOR SAFARI
    • Place of Presentation
      新潟NST Hall(新潟県)
    • Year and Date
      2009-11-05
    • Related Report
      2010 Final Research Report
  • [Presentation] Luminescence of Mn doped MgO-ZnO-GeO_2 glass ceramics2009

    • Author(s)
      Y.Morimoto、T.Sanada、S.Ikeda、K.Kojima、N.Wada
    • Organizer
      THE PHOSPHOR SAFARI
    • Place of Presentation
      新潟NST Hall(新潟県)
    • Year and Date
      2009-11-05
    • Related Report
      2010 Final Research Report
  • [Presentation] Preparation of Mn^<2+> doped ZnO-Ta_2O_5 phosphor by sol-gel method2009

    • Author(s)
      T.Sanada, S.Kato, Y.Morimoto, S.Ikeda, K.Kojima, N.Wada
    • Organizer
      THE PHOSPHOR SAFARI
    • Place of Presentation
      新潟県(NST Hall)
    • Year and Date
      2009-11-05
    • Related Report
      2009 Annual Research Report
  • [Presentation] Luminescence of Mn doped MgO-ZnO-GeO_2 glass ceramics2009

    • Author(s)
      Y.Morimoto, T.Sanada, S.Ikeda, K.Kojima, N.Wada
    • Organizer
      THE PHOSPHOR SAFARI
    • Place of Presentation
      新潟県(NST Hall)
    • Year and Date
      2009-11-04
    • Related Report
      2009 Annual Research Report
  • [Presentation] ゾル-ゲル法によって作製したMn含有ZnO-Ta_2O_5系ガラスおよびセラミックスの発光2009

    • Author(s)
      加藤慧、森本悠介、眞田智衛、池田慎吾、和田憲幸、小島一男
    • Organizer
      日本ゾルーゲル学会第7回討論会
    • Place of Presentation
      メルパルク京都(京都府)
    • Year and Date
      2009-07-31
    • Related Report
      2010 Final Research Report
  • [Presentation] ゾルーゲル法によって作製したMn含有ZnO-Ta_2O_5系ガラスおよびセラミックスの発光2009

    • Author(s)
      加藤慧、森本悠介、眞田智衛、池田慎吾、和田憲幸、小島一男
    • Organizer
      日本ゾルーゲル学会第7回討論会
    • Place of Presentation
      京都府(メルパルク京都)
    • Year and Date
      2009-07-31
    • Related Report
      2009 Annual Research Report
  • [Presentation] 蛍光材料、光触媒、金属ナノ粒子分散高分子材料の作製2009

    • Author(s)
      眞田智衛、与儀千尋、池田慎吾、小島一男
    • Organizer
      第4回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      関西大学(大阪府)
    • Year and Date
      2009-07-23
    • Related Report
      2010 Final Research Report
  • [Presentation] 蛍光材料・光触媒・金属ナノ粒子分散高分子材料の作製2009

    • Author(s)
      眞田智衛、与儀千尋、池田慎吾、小島一男
    • Organizer
      第4回日本セラミックス協会関西支部学術講演会
    • Place of Presentation
      大阪府(関西大学)
    • Year and Date
      2009-07-23
    • Related Report
      2009 Annual Research Report
  • [Presentation] ゾルーゲル法によるEu^<3+>含有Ta_2O_5蛍光体粒子の作製と特性2009

    • Author(s)
      若井保孝、中下宏、松本太一、和田憲幸、眞田智衛、池田慎吾、小島一男
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      日本大学理工学部(千葉県)
    • Year and Date
      2009-03-29
    • Related Report
      2010 Final Research Report
  • [Presentation] ゾルーゲル法によるEu^<3+>含有Ta_2O_5蛍光体粒子の作製と特性2009

    • Author(s)
      若井保孝, 中下宏, 松本太一, 和田憲幸, 眞田智衛, 池田慎吾, 小島一男
    • Organizer
      日本化学会第89春季年会
    • Place of Presentation
      千葉、日大理工
    • Year and Date
      2009-03-29
    • Related Report
      2008 Annual Research Report
  • [Presentation] ゾルーゲル法を用いて作製したTb^<3+>含有HfO_2薄膜の光学特性2009

    • Author(s)
      田中岳志、眞田智衛、和田憲幸、小島一男
    • Organizer
      第47回セラミックス基礎科学討論会
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2009-01-08
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] ゾルーゲル法によるZnO-GeO_2系光触媒膜の作製2009

    • Author(s)
      山田絵美、与儀千尋、眞田智衛、和田憲幸、小島一男
    • Organizer
      第47回セラミックス基礎科学討論会
    • Place of Presentation
      大阪国際会議場(大阪府)
    • Year and Date
      2009-01-08
    • Related Report
      2010 Final Research Report 2008 Annual Research Report
  • [Presentation] Luminescence and Afterglow in Mn^<2+> and Eu^<3+> Co-doped ZnO-GeO_2 Glasses and Glass Ceramics Prepared by Sol-Gel Method2008

    • Author(s)
      T.Sanada、H.Seto、Y.Morimoto、Y.Yamamoto、N.Wada 、K.Kojima
    • Organizer
      Joint Conference of The 2^<nd>International Conference on Science and Technology for Advanced Ceramics and The 1^<st> International Conference on Science and Technology of Solid Surface and Interface
    • Place of Presentation
      千葉OVTA(千葉県)
    • Year and Date
      2008-05-31
    • Related Report
      2010 Final Research Report
  • [Presentation] Luminescence and Afterglow in Mn^<2+> and Eu^<3+> Co-Doped ZnO-GeO_2 Glasses and Glass Ceramics Prepared by Sol-Gel Method2008

    • Author(s)
      T. Sanada, H. Seto, Y. Morimoto, K. Yamamoto, N. Wada, K. Kojima
    • Organizer
      Joint Conferences of The 2^<nd> International Conference on Science and Technology for Advanced Ceramics and The 1^<st> International Conference on Science and Technology of Solid Surface and Interface
    • Place of Presentation
      千葉OVTA
    • Year and Date
      2008-05-31
    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.ritsumei.ac.jp/lifescience/achem/kojima/LAB.html

    • Related Report
      2008 Annual Research Report
  • [Remarks]

    • URL

      http://www.ritsumei.ac.jp/kenkyu/2database/21.html

    • Related Report
      2008 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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