Production of bulk glassy composites with large-size ultra-high strength and enhanced plasticity by spark plasma sintering

• Project/Area Number: 20560639
• Research Category: Grant-in-Aid for Scientific Research (C)
• Allocation Type: Single-year Grants
• Section: 一般
• Research Field: Composite materials/Physical properties
• Research Institution: Tohoku University
• Principal Investigator: XIE Guoqiang 東北大学, 金属材料研究所, 准教授 (50422134)
• Project Period (FY): 2008 – 2010
• Project Status: Completed (Fiscal Year 2010)
• Budget Amount: ¥4,420,000 (Direct Cost: ¥3,400,000、Indirect Cost: ¥1,020,000); Fiscal Year 2010: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000); Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000); Fiscal Year 2008: ¥1,690,000 (Direct Cost: ¥1,300,000、Indirect Cost: ¥390,000)
• Keywords: 金属ガラス / 放電プラズマ焼結 / 複合効果 / 電子顕微鏡 / 微細構造 / 延性 / 粉末焼結 / 強度 / 結晶化

Research Abstract

Using a spark plasma sintering process, production of the bulk metallic glassy matrix composites with large-size ultra-high strength and enhanced plasticity has been carried out. Effect of the glassy alloy classification, microstructure, species of the crystalline particulates, fraction, particulate size, and distribution on the properties of the obtained composites was investigated. The improvement of plasticity of the fabricated bulk glassy alloy composites originates from the structural inhomogeneity caused by the particles inclusion. The additional particulates act as a resisting media causing deviation, branching and multiplication of shear bands.

Research Products

• [Journal Article] Bulk metallic glassy composites with excellent electrical conductivity and enhanced plasticity fabricated by spark plasma sintering (2011)
  • Author(s): G. Q. Xie, D. V. Louzguine, M. Fukuhara and A. Inoue
  • Journal Title: Mater. Sci. Forum Volume: Vol.675-677 Pages: 197-200
  • Peer Reviewed
• [Journal Article] Bulk metallic glassy composites with excellent electrical conductivity and enhanced plasticily fabricated by spark plasma sintering (2011)
  • Author(s): G.Q.Xie, D.V.Louzguine, M.Fukuhara, A.Inoue
  • Journal Title: Materials Science Forum Volume: 675-677 Pages: 197-200
  • Peer Reviewed
• [Journal Article] Cu particulate dispersed Cu_(50)Zr_<45> A_<l5> bulk metallic glassy composite with enhanced electrical conductivity (2010)
  • Author(s): G. Q. Xie, D. V. Louzguine, M. Fukuhara, H. Kimura and A. Inoue
  • Journal Title: Intermetallics Volume: Vol.18(10) Pages: 1973-1977
  • Peer Reviewed
• [Journal Article] Ultrasonic characteristics of porous Zr_<55> Cu_<30> Al_<10> Ni_5 bulk metallic glass fabricated by spark plasma sintering (2010)
  • Author(s): G. Q. Xie, M. Fukuhara, D. V. Louzguine and A. Inoue
  • Journal Title: Intermetallics Volume: Vol.18(10) Pages: 2014-2018
  • Peer Reviewed
• [Journal Article] Microstructure and mechanical properties of crystalline particulates dispersed Ni-based metallic glassy composites fabricated by spark plasma sintering (2010)
  • Author(s): G. Q. Xie, D. V. Louzguine, H. Kimura and A. Inoue
  • Journal Title: Intermetallics Volume: Vol.18(5) Pages: 851-858
  • Peer Reviewed
• [Journal Article] Consolidation behavior of Cu-Zr-Al metallic glass powder by spark plasma sintering (2010)
  • Author(s): G. Q. Xie, D. V. Louzguine, M. Fukuhara, H. Kimura and A. Inoue
  • Journal Title: Mater. Sci. Forum Volume: Vols. 654-656 Pages: 1086-1089
  • Peer Reviewed
• [Journal Article] Cu particulate dispersed Cu_<50>Zr_<45>Al_5 bulk metallic glassy composite with enhanced electrical conductivity (2010)
  • Author(s): G.Q.Xie, D.V.Louzguine, M.Fukuhara, H.Kimura, A.Inoue
  • Journal Title: Intermetallics Volume: 18 Pages: 1973-1977
  • Peer Reviewed
• [Journal Article] Ultrasonic characteristics of porous Zr_<55>Cu_<30>Al_<10>Ni_5 bulk metallic glass fabricated by spark plasma sintering (2010)
  • Author(s): G.Q.Xie, M.Fukuhara, D.V.Louzguine, A.Inoue
  • Journal Title: Intermetallics Volume: 18 Pages: 2014-2018
  • Peer Reviewed
• [Journal Article] Consolidation behavior of Cu-Zr-Al metallic glass powder by spark plasma sintering (2010)
  • Author(s): G.Q.Xie, D.V.Louzguine, M.Fukuhara, H.Kimura, A.Inoue
  • Journal Title: Materials Science Forum Volume: 654-656 Pages: 1086-1089
  • Peer Reviewed
• [Journal Article] Microstructure and mechanical properties of crystalline particulates dispersed Ni-based metallic glassy composites fabricated by spark plasma sintering (2010)
  • Author(s): G.Q.Xie, D.V.Louzguine, H.Kimura, A.Inoue.
  • Journal Title: Intermetallics 18 Pages: 851-858
  • Peer Reviewed
• [Journal Article] Dual phase metallic glassy composites with large-size and ultra-high strength fabricated by spark plasma sintering (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine, S. Li, H. Kimura and A. Inoue
  • Journal Title: Intermetallics Volume: Vol.17(7) Pages: 512-516
  • Peer Reviewed
• [Journal Article] Densification of gas atomized Ni-based metallic glassy powders by spark plasma sintering (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine, S. Li, H. Kimura and A. Inoue
  • Journal Title: Mater. Trans. Volume: Vol.50(6) Pages: 1273-1278
  • NAID: 10024815529
  • Peer Reviewed
• [Journal Article] Characterization of interface between the particles in NiNbZrTiPt metallic glassy matrix composite containing SiC fabricated by spark plasma sintering (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine and A. Inoue
  • Journal Title: J. Alloys Compd. Volume: Vol.483(1-2) Pages: 239-242
  • Peer Reviewed
• [Journal Article] Dual phase metallic glassy composites with large-size and ultra-high strength fabricated by spark plasma sintering (2009)
  • Author(s): G.Q.Xie, D.V.Louzguine, S.Li, H.Kimura, A.Inoue
  • Journal Title: Intermetallics 17 Pages: 512-516
  • Peer Reviewed
• [Journal Article] Densification of gas atomized Ni-based metallic glassy powders by spark plasma sintering (2009)
  • Author(s): G.Q.Xie, D.V.Louzguine, S.Li, H.Kimura, A.Inoue
  • Journal Title: Materials Transactions 50 Pages: 1273-1278
  • NAID: 10024815529
  • Peer Reviewed
• [Journal Article] Characterization of interface between the particles in NiNbZrTiPt metallic glassy matrix composite containing SiC fabricated by spark plasma sintering (2009)
  • Author(s): G.Q.Xie, D.V.Louzguine, A.Inoue
  • Journal Title: Journal of Alloys Compounds 483 Pages: 239-242
  • Peer Reviewed
• [Journal Article] Large-size ultra-high strength Ni-based bulk metallic glassy matrix composites with enhanced ductility fabricated by spark plasma sintering (2008)
  • Author(s): G. Q. Xie, D. V. Louzguine, H. Kimura, A. Inoue and F. Wakai
  • Journal Title: Appl. Phys. Lett Volume: Vol.92(12) Pages: 121907-121907
  • Peer Reviewed
• [Journal Article] Microstructure and properties of ceramic particulate reinforced metallic glassy matrix composites fabricated by spark plasma sintering (2008)
  • Author(s): G. Q. Xie, D. V. Louzguine, F. Wakai, H. Kimura and A. Inoue
  • Journal Title: Mater. Sci. Eng. B Volume: Vol.148 Pages: 77-81
  • Peer Reviewed
• [Journal Article] Large-size ultra-high strength Ni-based bulk metallic glassy matrix composites with enhanced ductility fabricated by spark plasma sintering (2008)
  • Author(s): G. Q. Xie, D. V. Louzguitie, H. Kimura, A. Inoue and F. Wakai
  • Journal Title: Applied Physics Letters 92 Pages: 101207-101207
  • Peer Reviewed
• [Journal Article] Microstructure and properties of ceramic particulate reinforced metallic glassy matrix composites fabricated by spark plasma sintering (2008)
  • Author(s): G. Q. Xie, D. V. Louzguine, F. Wakai, H. Kimura and A. Inoue
  • Journal Title: Materials Science and Engineering B 148 Pages: 77-81
  • Peer Reviewed
• [Presentation] Microstructure of interface between particles in Ni-based glassy matrix composites produced by spark plasma sintering (2011)
  • Author(s): G. Q. Xie, D. V. Louzguine, H. Kimura, F. Wakai and A. Inoue.
  • Organizer: The International Symposium on Visualization in Joining & Welding Science through Advanced Measurements and Simulation (Visual-JW2010), Proceedings of the Visual-JW 2010
  • Place of Presentation: Osaka, Japan
• [Presentation] 放電プラズマ焼結によるCu粒子分散金属ガラス複合材の開発 (2010)
  • Author(s): 謝国強、D. V. Louzguine、木村久道、井上明久
  • Organizer: 粉体粉末冶金協会2010年秋季大会発表
  • Place of Presentation: 京都大学、日本
• [Presentation] 放電プラズマ焼結による作製したZr基ポーラス金属ガラスの超音波特性 (2010)
  • Author(s): 謝国強、福原幹夫、D. V. Louzguine、井上明久
  • Organizer: 日本金属学会2010年秋期(第147回)大会発表
  • Place of Presentation: 北海道大学、日本
• [Presentation] Consolidation behavior of Cu-Zr-Al metallic glass powder by spark plasma sintering (2010)
  • Author(s): G. Q. Xie, D. V. Louzguine, M. Fukuhara, H. Kimura and A. Inoue
  • Organizer: The 7th Pacific Rim International Conference on Advanced Materials and Processing (PRICM-7)
  • Place of Presentation: Cairns, Australia
• [Presentation] Two-phase bulk metallic glasses produced by spark plasma sintering (2010)
  • Author(s): G. Q. Xie, D. V. Louzguine, H. Kimura and A. Inoue.
  • Organizer: 17th International Symposium on Metastable, Amorphous and Nanostructured Materials (ISMANAM 2010)
  • Place of Presentation: Zurich, Switzerland.
• [Presentation] Production of bulk metallic glasses and the composites by spark plasma and microwave sintering (2010)
  • Author(s): G. Q. Xie, D. V. Louzguine, S. Li, H. Kimura and A. Inoue.
  • Organizer: The 7th International Forum on Advanced Material Science and Technology (IFAMST-7)
  • Place of Presentation: Dalian, P. R. China
• [Presentation] Characterization of interface nanostructure in Ni-based metallic glassy composites produced by spark plasma sintering (2010)
  • Author(s): G. Q. Xie, D. V. Louzguine and A. Inoue
  • Organizer: International Conference on Nanomaterials : Synthesis, Characterization and Applications (ICN-2010)
  • Place of Presentation: Kottayam, India.
• [Presentation] 放電プラズマ焼結法によるFe基金属ガラス及びその複合材料の作製と評価 (2010)
  • Author(s): 謝国強、D. V. Louzguine、福原幹夫、木村久道、井上明久
  • Organizer: 日本金属学会2010年春期(第146回)大会発表
  • Place of Presentation: 筑波大学、日本
• [Presentation] Characterization of interface nanostructure in Ni-based metallic glassy composites produced by spark plasma sintering (2010)
  • Author(s): G.Q.Xie, D.V.Louzguinc A.Inoue
  • Organizer: International Conference on Nanomaterials : Synthesis, Characterization and Applications (ICN-2010)
  • Place of Presentation: Kottayam, India
• [Presentation] Production of bulk metallic glasses and the composites by spark plasma and microwave sintering (2010)
  • Author(s): G.Q.Xie, D.V.Louzguine, S.Li, H.Kimura, A.Inoue
  • Organizer: The 7^<th> International Forum on Advanced Material Science and Technology (IFAMST-7)
  • Place of Presentation: Dalian, P.R.China
• [Presentation] Two-phase bulk metallic glasses produced by spark plasma sintering (2010)
  • Author(s): G.Q.Xie, D.V.Louzguine, H.Kimura, A.Inoue
  • Organizer: 17^<th> International Symposium on Metastable, Amorphous and Nanostructured Materials (ISMANAM 2010)
  • Place of Presentation: Zurich, Switzerland
• [Presentation] Consolidation behavior of Cu-Zr-Al metallic glass powder by spark plasma sintering (2010)
  • Author(s): G.Q.Xie, D.V.Louzguine, M.Fukuhara, H.Kimura, A.Inoue
  • Organizer: The 7^<th> Pacific Rim International Conference on Advanced Materials and Processing (PRICM-7)
  • Place of Presentation: Carins, Australia
• [Presentation] 放電プラズマ焼結による作製したZr基ポーラス金属ガラスの超音波特性 (2010)
  • Author(s): 謝国強、福原幹夫、D.V.Louzguine、井上明久
  • Organizer: 日本金属学会2010年秋期(第147回)大会
  • Place of Presentation: 北海道大学
• [Presentation] 放電プラズマ焼結によるCu粒子分散金属ガラス複合材の開発 (2010)
  • Author(s): 謝国強, D.V.Louzguine、木村久道、井上明久
  • Organizer: 粉体粉末冶金協会2010年秋季大会
  • Place of Presentation: 京都大学
• [Presentation] Microstructure of interface between particles in Ni-based glassy matrix composites produced by spark plasma sintering (2010)
  • Author(s): G.Q.Xie, D.V.Louzguine, H.Kimura, F.Wakai, A.Inoue
  • Organizer: The International Symposium on Visualization in Joining & Welding Science through Advanced Measurements and Simulation (Visual-JW2010) and the Advanced Materials Development and Integration of Novel Structured Metallic and Inorganic Materials
  • Place of Presentation: Osaka, Japan
• [Presentation] 放電プラズマ焼結法によるFe基金属ガラス及びその複合材料の作製と評価 (2010)
  • Author(s): 謝国強, D.V.Louzguine, 福原幹夫, 木村久道, 井上明久
  • Organizer: 日本金属学会2010年春期(第146回)大会
  • Place of Presentation: 筑波大学
• [Presentation] Cu particulates reinforced bulk metallic glassy composites with large size ultra-high strength and excellent electrical conductivity (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine, H. Kimura and A. Inoue.
  • Organizer: The 7th International Conference on Bulk Metallic Glasses (BMG2009)
  • Place of Presentation: Busan, Korea.
• [Presentation] Ultrasonic characteristics of porous Zr55Cu30Al10Ni5 bulk metallic glass fabricated by spark plasma sintering (2009)
  • Author(s): G. Q. Xie, M. Fukuhara, D. V. Louzguine and A. Inoue.
  • Organizer: The 7th International Conference on Bulk Metallic Glasses (BMG2009)
  • Place of Presentation: Busan, Korea.
• [Presentation] 延性を示す高強度結晶粒子分散Ni基金属ガラス複合材料の作製と評価 (2009)
  • Author(s): 謝国強、D. V. Louzguine、木村久道、井上明久
  • Organizer: 粉体粉末冶金協会2009年秋季大会発表
  • Place of Presentation: 名古屋国際会議場、日本
• [Presentation] Bulk metallic glasses and its composites fabricated by spark plasma sintering (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine, W Zhang, H. Kimura and A. Inoue.
  • Organizer: The 5th Japan-Korea Workshop on Metallic Glasses
  • Place of Presentation: Okinawa, Japan
• [Presentation] Characterization of particulates reinforced Ni-based metallic glassy matrix composites fabricated by spark plasma sinterin (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine and A. Inoue.
  • Organizer: The 12th Frontiers of Electron Microscopy in Materials Science (FEMMS2009)
  • Place of Presentation: Sasebo, Japan.
• [Presentation] 放電プラズマ焼結法によるCu粒子分散金属ガラス複合材料の作製と評価 (2009)
  • Author(s): 謝国強、D. V. Louzguine、木村久道、井上明久
  • Organizer: 日本金属学会2009年秋期(第145回)大会発表
  • Place of Presentation: 京都大学、日本
• [Presentation] Production and properties of bulk metallic glassy and the composites by spark plasma sintering (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine, S. Li, H. Kimura and A. Inoue
  • Organizer: 16th International Symposium on Metastable, Amorphous and Nanostrustured Materials (ISMANAM2009)
  • Place of Presentation: Beijing, P. R. China.
• [Presentation] Two-phase metallic glass composites fabricated by spark plasma sintering (2009)
  • Author(s): 謝国強、D. V. Louzguine、李松、木村久道、P. Sharma、井上明久
  • Organizer: 日本金属学会2009年春期(第144回)大会発表
  • Place of Presentation: 東京工業大学、日本
• [Presentation] Fabrication and mechanical properties of metal particulates reinforced Ni-based metallic glass composites by spark plasma and microwave sintering (2009)
  • Author(s): G. Q. Xie, D. V. Louzguine, S. Li and A. Inoue
  • Organizer: TMS 2009 : 138th Annual Meeting & Exhibition
  • Place of Presentation: San Francisco, U. S. A
• [Presentation] Production and properties of bulk metallic glassy and the composites by spark plasma sintering (2009)
  • Author(s): 謝国強, D.V.Louzguine, 木村久道, 井上明久
  • Organizer: 16^<th> International Symposium on Metastable, Amorphous and Nanostrustured Materials(ISMANAM2009)
  • Place of Presentation: Beijing, P.R. China
• [Presentation] 放電プラズマ焼結法によるCu粒子分散金属ガラス複合材料の作製と評価 (2009)
  • Author(s): 謝国強、D.V.Louzguine、木村久道、井上明久
  • Organizer: 日本金属学会2009年秋期(第145回)大会
  • Place of Presentation: 京都大学
• [Presentation] Characterization of particulates reinforced Ni-based metallic glassy matrix composites fabricated by spark plasma sintering (2009)
  • Author(s): G.Q.Xie, D.V.Louzguine, A.Inoue
  • Organizer: The 12^<th> Frontiers of Electron Microscopy in Materials Science(FEMMS2009)
  • Place of Presentation: Sasebo, Japan
• [Presentation] Bulk metallic glasses and its composites fabricated by spark plasma sintering (2009)
  • Author(s): G.Q.Xie, D.V.Louzguine, W Zhang, H.Kimura, A.Inoue
  • Organizer: The 5^<th> Japan-Korea Workshop on Metallic Glasses
  • Place of Presentation: Okinawa, Japan
• [Presentation] 延性を示す高強度結晶粒子分散Ni基金属ガラス複合材料の作製と評価 (2009)
  • Author(s): 謝国強, D.V.Louzguine, 木村久道, 井上明久
  • Organizer: 粉体粉末冶金協会2009年秋季大会
  • Place of Presentation: 名古屋国際会議場
• [Presentation] Ultrasonic characteristics of porous Zr_<55>Cu_<30>Al_<10>Ni_5 bulk metallic glass fabricated by spark plasma sintering (2009)
  • Author(s): G.Q.Xie, M.Fukuhara, D.V.Louzguine, A.Inoue
  • Organizer: The 7^<th> International Conference on Bulk Metallic Glasses(BMG2009)
  • Place of Presentation: Busan, Korea
• [Presentation] Cu particulates reinforced bulk metallic glassy composites with large size ultra-high strength and excellent electrical conductivity (2009)
  • Author(s): G.Q.Xie, D.V.Louzguine, H.Kimura, A.Inoue
  • Organizer: The 7^<th> International Conference on Bulk Metallic Glasses(BMG2009)
  • Place of Presentation: Busan, Korea
• [Presentation] Fabrication and mechanical properties of metal particulates reinforced Ni-based metallic glass composites by spark plasma and microwave sintering (2009)
  • Author(s): G. Q. Xie
  • Organizer: TMS 2009 : 138^<th> Annual Meeting & Exhibition
  • Place of Presentation: San Francisco, U.S.A.
• [Presentation] Two-phase metallic glass composites fabricated by spark plasma sintering (2009)
  • Author(s): 謝国強
  • Organizer: 日本金属学会2009年春期(第144回)大会
  • Place of Presentation: 東京工業大学
• [Presentation] Large-size ultra-high strength Ni-based bulk metallic glass and its composites fabricated by spark plasma sintering process (2008)
  • Author(s): G. Q. Xie, D. V. Louzguine, S. Li, H. Kimura, F. Wakai and A. Inoue.
  • Organizer: International Symposium of Amorphous Alloys
  • Place of Presentation: Hangzhou, P. R. China
• [Presentation] 延性を示す高強度Ni基金属ガラス複合焼結体の作製と結晶質粒子添加の効果 (2008)
  • Author(s): 謝国強、D. V. Louzguine、李松、木村久道、井上明久
  • Organizer: 日本金属学会2008年秋期(第143回)大会発表
  • Place of Presentation: 熊本大学、日本
• [Presentation] 延性を示す高強度Ni基金属ガラス複合焼結体の作製と結晶質粒子添加の効果 (2008)
  • Author(s): 謝国強
  • Organizer: 日本金属学会2008年秋期(第143回)大会
  • Place of Presentation: 熊本大学
• [Book] Fabrication and characterization of metallic glassy matrix composite reinforced with ZrO2 particulate by spark plasma sintering process, inFrontiers in Materials Research, Vol.10 of Series : Advances in Materials Research (2008)
  • Author(s): G. Q. Xie, D. V. Louzguine, W. Zhang, H. Kimura and A. Inoue
  • Publisher: Springer-Verlag Berlin Heidelberg
• [Book] "Frontiers in Materials Research, Vol.10 of Series : Advances in Materials Research" Edited by Y. Fujikawa, K. Nakajima and T. Sakurai (2008)
  • Author(s): G. Q. Xie, D. V. Louzguine, W. Zhang, H. Kimura and A. Inoue
  • Publisher: Springer-Verlag Berlin Heidelberg
• [Patent(Industrial Property Rights)] 金属ガラス複合構造物及び金属ガラス複合構造物の製造方法 (2009)
  • Inventor(s): 謝国強、井上明久、D. V. Louzguine、木村久道、李松
  • Industrial Property Rights Holder: 東北大学
  • Industrial Property Number: 2009-107145
  • Filing Date: 2009-04-24
• [Patent(Industrial Property Rights)] 金属ガラス複合構造物及び金属ガラス複合構造物の製造方法 (2009)
  • Inventor(s): 謝国強、井上明久、D. V. Louzguine、木村久道、李松
  • Industrial Property Rights Holder: 東北大学
  • Filing Date: 2009-01-22