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Fabrication of bulk metallic glasses with improved mechanical properties in corrosive aqueous solutions and in cryogenic temperatures

Research Project

Project/Area Number 20560644
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionTohoku University

Principal Investigator

KAWASHIMA Asahi  東北大学, 金属材料研究所, 特別教育研究教員 (50005964)

Co-Investigator(Kenkyū-buntansha) KURISHITA Hiroaki  東北大学, 金属材料研究所, 准教授 (50112298)
Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,550,000 (Direct Cost: ¥3,500,000、Indirect Cost: ¥1,050,000)
Fiscal Year 2010: ¥1,170,000 (Direct Cost: ¥900,000、Indirect Cost: ¥270,000)
Fiscal Year 2009: ¥1,430,000 (Direct Cost: ¥1,100,000、Indirect Cost: ¥330,000)
Fiscal Year 2008: ¥1,950,000 (Direct Cost: ¥1,500,000、Indirect Cost: ¥450,000)
Keywords金属ガラス / 機械的性質 / 応力腐食割れ / 低温 / 塑性ひずみ / 機械的質性 / 腐食性水溶液 / 透過電子顕微鏡 / 引張強度 / 塑性伸び / 圧縮強度
Research Abstract

In general, metallic materials suffer brittle fracture when they are under the combined reactions of tensile stress and specific environments. This phenomenon is called stress corrosion cracking (SCC)and very important from the standpoint of safe designing. Accordingly, we investigated SCC properties of bulk metallic glasses (BMGs)in NaCl solutions. It was found for the first time that Zr_<70> Cu_6Al_8Ni_<16> BMG showed no susceptibility to SCC. The mechanical properties for CuZr-and Ni-based BMGs were also examined at cryogenic temperature (77K). We obtained the new results in which the BMGs possess both high strength and improved plastic train at cryogenic temperatures.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (38 results)

All 2010 2009 2008

All Journal Article (16 results) (of which Peer Reviewed: 16 results) Presentation (20 results) Book (2 results)

  • [Journal Article] Microstructure in a Ni_<60> Pd_<20> P_<17> B_3 metallic glass compressively fractured at cryogenic temperature2010

    • Author(s)
      A. Kawashima, Y. Q. Zeng, G. Xie, N. Nishiyama, A. Inoue
    • Journal Title

      Mater. Sci. Eng. A

      Volume: 528 Pages: 391-395

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Deformation and fracture behavior of metallic glassy alloys and glassy-crystal composites2010

    • Author(s)
      D. V. Louzguine-Luzgin, A. Vinogradov, S. Li, A. Kawashima, G. Xie, A. R. Yavari and A. Inoue
    • Journal Title

      Metall. Mater. Tran. A, published online

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Zr-based bulk glassy alloy with improved resistance to stress corrosion cracking in sodium chloride solutions2010

    • Author(s)
      A. Kawashima, Y. Yokoyama and A. Inoue
    • Journal Title

      Corros Sci.

      Volume: 52 Pages: 2950-2957

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Local atomic structure of Ni_<60> Pd_<20> P_<20> and Ni_<60> Pd_<20> P_<17> B_3 bulk metallic glasses and the origin of glass-forming ability2010

    • Author(s)
      M. Matsuura, T. Fujita, A. Kawashima, Y. Q. Zeng, 他6名
    • Journal Title

      J Alloys Comp.

      Volume: 496 Pages: 135-139

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Zr-based bulk glassy alloy with improved resistance to stress corrosion cracking in sodium chloride solutions2010

    • Author(s)
      A.Kawashima
    • Journal Title

      Corrosion Science

      Volume: 52 Pages: 2950-2957

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Microstructure in a Ni_<60>Pd_<20>P_<17>B_3 bulk glassy alloy compressively fractured at cryogenic temperature2010

    • Author(s)
      A.Kawashima
    • Journal Title

      Material Science and Engineering A

      Volume: 528 Pages: 391-396

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Deformation and fracture behavior of metallic glassy alloys and glassy-crystal composites2010

    • Author(s)
      D.V.Louzguine-Luzgin
    • Journal Title

      Metallurgical Materials Transactions A

      Volume: 17(Published online)

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Local atomic structure of Ni_<60>Pd_<20>P_<20> and Ni_<60>Pd_<20>P_<17>B_3 bulk metallic glasses and the origin of glass-forming ability2010

    • Author(s)
      M.Matsuura
    • Journal Title

      Journal of Alloys and Compounds

      Volume: 496 Pages: 135-139

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced tensile strength and plasticity of Zr-Cu-Al bulk glassy alloys at cryogenic temperatures2009

    • Author(s)
      A. Kawashima, Y. Yokoyama, I. Seki, H. Kurishita, M. Fukuhara, H. Kimura and A. Inoue
    • Journal Title

      Mater. Trans.

      Volume: 50 Pages: 2685-2690

    • NAID

      10025559304

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Enhanced tensile strength and plasticity of Zr-Cu-Al bulk glassy alloys at cryogenic temperatures2009

    • Author(s)
      A.Kawashima
    • Journal Title

      Materials Transaction 50

      Pages: 2685-2690

    • NAID

      10025559304

    • Related Report
      2009 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Influences of temperature and strain rate on the mechanical behavior of Cu_<45> Zr_<45> Al_5Ag_5 bulk glassy alloy2008

    • Author(s)
      T. Okuno, A. Kawashima, H. Kurishita, W. Zhang, H. Kimura and A. Inoue
    • Journal Title

      Mater. Trans.

      Volume: 49 Pages: 513-517

    • NAID

      10021144898

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties of a Ni_<60> Pd_<20> P_<17> B_3 bulk glassy alloy at cryogenic temperatures2008

    • Author(s)
      A. Kawashima, Y. Q. Zeng, M. Fukuhara, H. Kurishita, N. Nishiyama, H. Miki, A. Inoue
    • Journal Title

      Mater. Sci. Eng. A

      Volume: 498 Pages: 475-481

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Low temperature dependence of elastic parameters and internal frictions of glassy alloy Cu_<45> Zr_<45> Al_5Ag_52008

    • Author(s)
      M. Fukuhara, A. Kawashima, W. Zhang, A. Inoue, F. Yin
    • Journal Title

      J. Appl. Phys.

      Volume: 103 Pages: 13503-13503

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Influences of temperature and strain rate on the mechanical behavior of Cu45Zr45A15Ag5 bulk glassy alloy2008

    • Author(s)
      T. Okuno
    • Journal Title

      Materials Transaction 49

      Pages: 513-517

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Low temperature dependence of elastic parameters and internal frictions of glassy alloy Cu45Zr45A15Ag52008

    • Author(s)
      M. Fukuhara
    • Journal Title

      Journal of Applied Physics 103

      Pages: 13503-13503

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Mechanical properties of a Ni60Pd20P17B3 hulk glassy alloy at cryogenic temperatures2008

    • Author(s)
      A. Kawashima.
    • Journal Title

      Materials Science and Engineering A 498

      Pages: 475-481

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Au基バルク金属ガラスの低温域における機械的性質2010

    • Author(s)
      郭海、張偉、川嶋朝日、潘登、陳明偉、井上明久
    • Organizer
      日本金属学会
    • Place of Presentation
      北海道大学
    • Year and Date
      2010-09-25
    • Related Report
      2010 Final Research Report
  • [Presentation] Au基バルク金属ガラスの低温域における機械的性質2010

    • Author(s)
      郭海
    • Organizer
      日本金属学会
    • Place of Presentation
      北海道大学(札幌市)
    • Year and Date
      2010-09-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] Zr-based bulk glassy alloy with low susceptibility to stress corrosion cracking in sodium chloride solutions2010

    • Author(s)
      A. Kawashima, Y. Yokoyama, A. Inoue
    • Organizer
      ISMANAM 2010
    • Place of Presentation
      Zurich, Switzerland
    • Year and Date
      2010-07-06
    • Related Report
      2010 Final Research Report
  • [Presentation] Zr-based bulk glassy alloy with low susceptibility to stress corrosion cracking in sodium chloride solutions2010

    • Author(s)
      A.Kawashima
    • Organizer
      ISMANAM 2010
    • Place of Presentation
      ETH(チューリッヒ、スイス)
    • Year and Date
      2010-07-06
    • Related Report
      2010 Annual Research Report
  • [Presentation] Zr基ガラス合金の応力腐食割れ挙動2010

    • Author(s)
      川嶋朝日、横山嘉彦、井上明久
    • Organizer
      日本金属学会
    • Place of Presentation
      つくば
    • Year and Date
      2010-03-30
    • Related Report
      2010 Final Research Report
  • [Presentation] Zr基バルクガラス合金の応力腐食割れ挙動2010

    • Author(s)
      川嶋朝日
    • Organizer
      日本金属学会
    • Place of Presentation
      つくば大学(つくば市)
    • Year and Date
      2010-03-30
    • Related Report
      2009 Annual Research Report
  • [Presentation] 金属ガラスNi_<60> Pd_<20> P_<20-x> B_x(x=0-5)合金のPd, Ni局所構造の温度変化2009

    • Author(s)
      松浦真、川嶋朝日、曽宇喬、木村久道、藤田武志、陳明偉、井上明久、今野一弥、浅田格
    • Organizer
      日本金属学会
    • Place of Presentation
      京都大学
    • Year and Date
      2009-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 低温で圧縮変形したNi基ガラス合金の微細構造観察2009

    • Author(s)
      川嶋朝日、曽宇喬、謝国強、西山信行、井上明久
    • Organizer
      日本金属学会
    • Place of Presentation
      京都大学
    • Year and Date
      2009-09-17
    • Related Report
      2010 Final Research Report
  • [Presentation] 低温で圧縮変形したNi基ガラス合金の微細構造観察2009

    • Author(s)
      川嶋朝日
    • Organizer
      日本金属学会
    • Place of Presentation
      京都大学(京都市)
    • Year and Date
      2009-09-17
    • Related Report
      2009 Annual Research Report
  • [Presentation] Ni-based bulk glassy alloy with enhanced compressive strength and plasticity at cryogenic temperatures2009

    • Author(s)
      A. Kawashima, Y. Q. Zeng, M. Fukuhara, H. Kurishita, N. Nishiyama, A. Inoue
    • Organizer
      THERMEC' 2009
    • Place of Presentation
      Berlin
    • Year and Date
      2009-08-27
    • Related Report
      2010 Final Research Report
  • [Presentation] Ni-based bulk glassy alloy with enhanced strength and plasticity at cryogenic temperatures2009

    • Author(s)
      川嶋朝日
    • Organizer
      THERMEC 2009
    • Place of Presentation
      マリティムホテル(ベルリン)ドイツ
    • Year and Date
      2009-08-27
    • Related Report
      2009 Annual Research Report
  • [Presentation] CuZrおよびNi基ガラス合金の低温域における機械的特性2009

    • Author(s)
      川嶋朝日、曽宇喬、福原幹夫、栗下裕明、張偉、木村久道、西山信行、井上明久
    • Organizer
      粉体粉末冶金協会
    • Place of Presentation
      京都工芸繊維大学.
    • Year and Date
      2009-06-03
    • Related Report
      2010 Final Research Report
  • [Presentation] CuZrおよびNi基ガラス合金の低温域における機械的特性2009

    • Author(s)
      川嶋朝日
    • Organizer
      粉体粉末冶金協会
    • Place of Presentation
      京都工芸繊維大学(京都市)
    • Year and Date
      2009-06-03
    • Related Report
      2009 Annual Research Report
  • [Presentation] Zr基ガラス合金の低温における引張特性2009

    • Author(s)
      川嶋朝日、横山嘉彦、関一郎、栗下裕明、福原幹夫、木村久道、井上明久
    • Organizer
      日本金属学会
    • Place of Presentation
      東京
    • Year and Date
      2009-03-30
    • Related Report
      2010 Final Research Report
  • [Presentation] Zr基ガラス合金の低温下における引張特性2009

    • Author(s)
      川嶋朝日
    • Organizer
      日本金属学会
    • Place of Presentation
      東京都目黒区
    • Year and Date
      2009-03-30
    • Related Report
      2008 Annual Research Report
  • [Presentation] Mechanical behavior of Cu_<45> Zr_<45> Al_5Ag_5 bulk glassy alloy at cryogenic temperatures2008

    • Author(s)
      A. Kawashima, T. Okuno, H. Kurishita, M. Fukuhara, W. Zhang, H. Kimura, A. Inoue
    • Organizer
      IUMRS-ICA 2008
    • Place of Presentation
      Nagoya
    • Year and Date
      2008-12-12
    • Related Report
      2010 Final Research Report
  • [Presentation] Mechanical behavior of Cu45Zr45A15Ag5 bulk glassy alloy at cryogenic temperatures2008

    • Author(s)
      川嶋朝日
    • Organizer
      IUNRS-ICA 2008
    • Place of Presentation
      愛知県名古屋市
    • Year and Date
      2008-12-12
    • Related Report
      2008 Annual Research Report
  • [Presentation] Ni基ガラス合金の低温における機械的および超音波特性2008

    • Author(s)
      川嶋朝日、曽宇喬、栗下裕明、西山信行、三木寛之、井上明久
    • Organizer
      日本金属学会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-24
    • Related Report
      2010 Final Research Report
  • [Presentation] 金属ガラスCu_<45> Zr_<45> Al_5Ag_5の低温弾性パラメータと内耗2008

    • Author(s)
      福原幹夫、川嶋朝日、張偉、井上明久、殷福星
    • Organizer
      日本金属学会
    • Place of Presentation
      熊本大学
    • Year and Date
      2008-09-24
    • Related Report
      2010 Final Research Report
  • [Presentation] Ni基ガラス合金の低温域における機械的および超音波特性2008

    • Author(s)
      川嶋朝日
    • Organizer
      日本金属学会
    • Place of Presentation
      熊本県熊本市
    • Year and Date
      2008-09-24
    • Related Report
      2008 Annual Research Report
  • [Book] 低温強度(新機能材料金属ガラスの基礎と産業への応用、監修井上明久)2009

    • Author(s)
      川嶋朝日
    • Publisher
      テクノシステム
    • Related Report
      2010 Final Research Report
  • [Book] 新機能材料金属ガラスの基礎と産業への応用2009

    • Author(s)
      川嶋朝日
    • Publisher
      株式会社テクノシステム
    • Related Report
      2008 Annual Research Report

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Published: 2008-04-01   Modified: 2016-04-21  

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