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Characterization of electrochemical reaction on mix conductive SOFC cathode materials

Research Project

Project/Area Number 20560659
Research Category

Grant-in-Aid for Scientific Research (C)

Allocation TypeSingle-year Grants
Section一般
Research Field Structural/Functional materials
Research InstitutionUniversity of Yamanashi

Principal Investigator

KAKINUMA Katuyoshi  University of Yamanashi, 燃料電池ナノ材料研究センター, 准教授 (60312089)

Project Period (FY) 2008 – 2010
Project Status Completed (Fiscal Year 2010)
Budget Amount *help
¥4,680,000 (Direct Cost: ¥3,600,000、Indirect Cost: ¥1,080,000)
Fiscal Year 2010: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2009: ¥1,300,000 (Direct Cost: ¥1,000,000、Indirect Cost: ¥300,000)
Fiscal Year 2008: ¥2,080,000 (Direct Cost: ¥1,600,000、Indirect Cost: ¥480,000)
Keywords燃料電池材料 / カソード / 混合伝導性 / SOFC / 固体酸化物形燃料電池 / ペロブスカイト構造 / 電子伝導
Research Abstract

We have investigated the cathodic performance of (Sr_<1-x>Ce_x)MnO_<3±>. (X=0.1~0.4, SCM), both with and without Ce_<0.8>Sm_<0.2>O_<1.9> (SDC) as an additive, for solid oxide fuel cells. The current density (IR-free) at overpotential of 0.2V in 800℃ showed maximum value of 200mA cm^<-2> (x=0.3), which was larger than that of La_<0.8>Sr_<0.2>Co_<0.3>Fe_<0.2>O_3 (LSCF) in the same measurement condition. The overpotential of SCM cathode in applying the 0.2A cm^<-2> at 800℃ kept constant value over 1000 hours. The current density of SCM (X=0.3) with SDC additive was higher than that of SCM (X=0.3), which is due to an improvement of the effective three-phase boundary area and oxide ion conductivity of the cathode. We concluded that the SCM is one of the candidate cathode materials for SOFC.

Report

(4 results)
  • 2010 Annual Research Report   Final Research Report ( PDF )
  • 2009 Annual Research Report
  • 2008 Annual Research Report
  • Research Products

    (13 results)

All 2011 2010 2009 Other

All Journal Article (6 results) (of which Peer Reviewed: 5 results) Presentation (4 results) Book (1 results) Remarks (2 results)

  • [Journal Article] Synthesis and Electrochemical Characterization of Pt Catalyst Supported on Sn_<0.96>Sb_<0.04>O_<2-∂>with a Network Structure2011

    • Author(s)
      K.Kakinuma M.Uchida, T.Kamino, H.Uchida, M.Watanabe
    • Journal Title

      Electrochimica Acta 56

      Pages: 2881-2887

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nickel Nanoparticles Supported on Hollow Samaria-DopedCeria Particles via the Solution-Spray Plasma Technique : Anode Catalystsfor SOFCs2010

    • Author(s)
      R.Nishida, et al.
    • Journal Title

      Solid State Ionics

      Volume: 180 Pages: 968-972

    • Related Report
      2010 Annual Research Report
    • Peer Reviewed
  • [Journal Article] Synthesis of Nickel Nanoparticles Supported on Hollow Samaria-DopedCeria Particles via the Solution-Spray Plasma Technique : Anode Catalystsfor SOFCs2009

    • Author(s)
      R.Nishida, K.Kakinuma, H.Nishino, T.Kamino, H.Yamashita, M.Watanabe, H.Uchida
    • Journal Title

      Solid State tonics 180

      Pages: 968-972

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article] Oxide ion conductivity in (Ba_<0.3>Sr_<0.2>La_<0.5>) (In_<1-x>M_x)O_<2.75> (M=Sc and Yb) systems2009

    • Author(s)
      K.Kakinuma, T.Waki, H.Yamamura, T.Atake
    • Journal Title

      J.Ceram.Soc.Jpn. 117

      Pages: 529-533

    • NAID

      10025967321

    • Related Report
      2010 Final Research Report
    • Peer Reviewed
  • [Journal Article]2009

    • Author(s)
      山村博
    • Journal Title

      セラミックスの事典(朝倉書店)

    • Related Report
      2009 Annual Research Report
  • [Journal Article] Oxide ion conductivity in (Ba_<0.3>Sr_<0.2>La_<0.5>)(In_<1-x>M_x)O_<2.75> (M=Sc and Yb) systems2009

    • Author(s)
      Katsuyoshi KAKINUMA, Tetsuaki WAKI, Hiroshi YAMAMURA, Tooru ATAKE
    • Journal Title

      J. Ceram. Soc. Jpn. 117

      Pages: 529-533

    • NAID

      10025967321

    • Related Report
      2008 Annual Research Report
    • Peer Reviewed
  • [Presentation] Ce_<0.8>Sm_<0.2>O_<1.9>を添加したn型電子伝導体(Sr_<1-x>Ce_x)MnO_<3±δ>のSOFCカソードへの応用2010

    • Author(s)
      植松佑太, 柿沼克良, 西野華子, 内田裕之, 渡辺政廣
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ
    • Year and Date
      2010-11-25
    • Related Report
      2010 Final Research Report
  • [Presentation] Ce_0.8Sm_0.2O_1.9を添加したn型電子伝導体(Sr_1-xCe_x)MnO_3±δのSOFCカソードへの応用2010

    • Author(s)
      植松佑太, et al.
    • Organizer
      第36回固体イオニクス討論会
    • Place of Presentation
      仙台市情報・産業プラザ
    • Year and Date
      2010-11-25
    • Related Report
      2010 Annual Research Report
  • [Presentation] n型電子伝導体(Sr_<1-x>Ce_x)MnO_<3-δ>のSOFCカソードへの応用2009

    • Author(s)
      植松佑太, 柿沼克良, 西野華子, 内田裕之, 渡辺政廣
    • Organizer
      第50回電池討論会
    • Place of Presentation
      京都国立京都国際会館
    • Year and Date
      2009-12-01
    • Related Report
      2010 Final Research Report
  • [Presentation] n型電子伝導性(Sr_<1-x>Ce_x)MnO_<3±δ>のSOFCカソードへの応用2009

    • Author(s)
      柿沼克良
    • Organizer
      電池討論会
    • Place of Presentation
      国立京都国際会館
    • Year and Date
      2009-12-01
    • Related Report
      2009 Annual Research Report
  • [Book] セラミックスの事典2009

    • Author(s)
      柿沼克良, 他
    • Publisher
      朝倉書店
    • Related Report
      2010 Final Research Report
  • [Remarks] ホームページ等

    • URL

      http://erdb.yamanashi.ac.jp/rdb/A_DispInfo.Scholar/15/2B3D732A6ABC5AC6.html

    • Related Report
      2010 Final Research Report
  • [Remarks]

    • URL

      http://erdb.yamanashi.acjp/rdb/A_DispInfo.Scholar?ID=2B3D732A6ABC5AC6

    • Related Report
      2010 Annual Research Report

URL: 

Published: 2008-04-01   Modified: 2016-04-21  

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